Economic geology value of oil shale deposits: Ethiopia (Tigray) and Jordan

Oil shale is an organic-rich, fine-grained sedimentary rock, containing kerogen, from which liquid hydrocarbons (called shale oil) can be produced. The oil shale deposits in the Tigray region are found in the northern parts of Ethiopia, Eastern Africa. They are of Upper Paleozoic in age, existing as remnants of the Cretaceous erosion period, underlain by tillites and overlain by sandstones. They were formed during the glacial retreat followed by marine deposition of shales in a basin created by the enormous load of the glaciers. The Ethiopian-Tigray oil shale deposits cover an area extending over approximately 30 km², with an average mineable bed-thickness of 55 m, showing on the upper part inter-beds and laminations of shaley limestones. The oil shale resources in this region are estimated to be approximately 4 billion tonnes. The exploitation of the Ethiopian-Tigray oil shale deposits is an excellent alternative to fulfill the fuel and other petroleum products’ demand of Ethiopia. This study sheds light on the oil shale resources in the Ethiopian region of Tigray, as they are fairly investigated, regarding their geological characterization, and future strategies for their exploration and exploitation potential. In addition, the oil shale deposits in Jordan are also moderately investigated, as Jordan is considered a promising country for shale oil, taking into account that Jordan has no other hydrocarbon resources (such as crude oil and natural gas), unlike many other countries in the MENA (Middle East and North Africa) region, as MENA sets on “seas” of oil and natural gas. Furthermore, oil shale in the USA is also briefly investigated, as the USA is being the world’s largest country of oil shale resources and reserves. Also, some other issues related to the oil shale industry are investigated, such as economics, extraction technologies of shale oil, and the environmental impacts.     

Microbial stability evaluation of cement-based waste forms at different waste to cement ratio

An evaluation of the effect of differences in chromium nitrate to cement ratio on the microbial stability of a chromium nitrate/cement waste form, as reflected in the leaching of chromium, calcium, magnesium and aluminum; was carried out in this study. An increase in the proportion of chromium in the waste form from 4.8 to 8.7% had no noticeable effect on microbial stability, with the total chromium leached essentially unchanged. Further increases in the proportion of chromium in the waste form from 8.7 to 10.7%, and from 10.7 to 15.9% resulted in a substantial decrease in microbial stability, with 3-fold and 1.3-fold increase in the total chromium leached, respectively, observed. For calcium, increases in the chromium proportion were accompanied with increases in the total calcium leached even though the increases were not in direct proportion to the increases in chromium proportion. For magnesium and aluminum, increases in the proportion of chromium within the range 4.8-10.7% were accompanied with increases in the total respective metals leached, with minor variation for each metal. On the whole, the maximum percentage chromium leached from the different waste forms was substantially lower than those of the other metals.     

Numerical analysis of density-induced segregation during die filling

In this study, segregation behaviour of binary granular mixtures with the same particle size but different densities during die filling in the presence of air was investigated using a combined discrete element method (DEM) and computational fluid dynamics (CFD) approach, in which the kinematics of particles was modelled using DEM, the motion of air was analysed using CFD and a two-way coupling of the particles and the air was incorporated. The depositions of powder from stationary and moving shoes into the die cavities of different geometries were simulated and the corresponding segregation behaviours were analysed. It has been found that, for die filling from a stationary shoe, the concentration distributions of the heavy and light particles along the die width mainly depend on the initial spatial distribution of the granular mixture in the shoe. For die filling from a moving shoe, a low concentration of light particles on the leading side of the die (referring to the direction of the shoe motion) is observed for die filling with a square die, in which the process is dominated by nose flow. The density difference can cause segregation along the die depth with a low concentration of light particles at the bottom. The presence of air enhances this segregation tendency by resisting the flow of light particles into the bottom of the die and causes a higher concentration of the light particles at the top. Finally, the segregation index, defined as the volume weighted root-mean-square deviation in the content of light particles, was introduced to quantify the degree of segregation in the horizontal and vertical directions. It has been found that the degree of segregation is determined by the presence of air and also the powder flow pattern.     

Effects of Material Properties on Granular Flow in a Silo Using DEM Simulation

In order to test the effect of material properties on flowability of particulate materials, discharge procedures of spherical particles within a flat-bottomed model silo with three sets of material properties, i.e., soft and hard without adhesion and adhesive hard, were simulated using the Discrete Element Method. For each system, three particles on the center line were selected and their instant vertical velocity components were traced. In addition, both discharge and the rate were recorded throughout the procedure. The predicted results show that, for both the systems without adhesion, though the soft has a material modulus only 1/1000 of the hard, there are no significant differences in f low pattern and discharge rate. This suggests that a soft system can be used to predict the behavior of a hard one to save CPU time in a gravity-driven granular flow. On the other hand, comparison between both hard systems shows that adhesion can significantly reduce the flowability in granular flow. By analyzing the velocity plot for the traced particles, free fall was clearly detected above the decompression zone, indicating the motion of a particle in a granular flow can be resolved as free fall together with the movement due to particle collision. In addition, select dynamic behavior related to the kinetic fluctuations affecting flow was observed.

discrete element method silo granule flow particulate material     

Development of a Drinkable,Peanut‐Based Dietary Supplement and Comparison of Its Nutritional and Microbiological Qualities with Commercial Products

This study was undertaken to formulate, using peanuts as a major ingredient, a beverage which will benefit older adults who are at a high risk of protein‐energy malnutrition and other health complications, and to compare its nutritional and microbiological qualities to commercial products. Peanuts, rice flour, and flaxseed meal in a ratio of 48.0:49.8:2.2 were mixed with water (20% solids) and cooked into gruel which was sequentially treated with BAN^®, (480 KNU‐B/g, 75 °C 1 h), Alcalase^® (2.4 AU‐A/g, 60 °C 1 h), and Flavourzyme^® (1000 LAPU/g, 55 °C 1 h) to predigest starch and protein, respectively. The degree of hydrolysis and product viscosity during hydrolysis was measured. The nutritional and microbiological qualities of the product were compared to 10 commercial products. Results indicate that 60% of starch was hydrolyzed while a total of 1.62% protein hydrolysis was observed. Product viscosity reduced from 228.55 to 3.60 cP at the end of hydrolysis. The formulation had no cholesterol and low sodium which was a functional property that was absent in the commercial products. Results of this study suggest that the formulation can be further optimized into a unique product that could cater for the protein needs and other nutritional requirements of older adults.     

Survival of Lactobacillus rhamnosus GG as Influenced by Storage Conditions and Product Matrixes

Abstract: Mortality resulting from diarrhea especially that occurs in children younger than 5 y of age ranks 3rd among all deaths caused by infectious diseases worldwide. Probiotics such as Lactobacillus rhamnosus GG are clinically shown to effectively reduce the incidence of diarrhea in children. A food substrate is one of the major factors regulating the colonization of microorganisms in human gastrointestinal tracts. Peanut butter is a nutritious, low‐moisture food that could be a carrier for probiotics. In this study, we observed the influence of storage conditions and product matrixes on the survival of L. rhamnosus GG. Cells of L. rhamnosus GG were inoculated into full fat or reduced fat peanut butter at 10⁷ CFU/g. Inoculated peanut butter was stored at 4, 25, or 37 °C for 48 wk. Samples were drawn periodically to determine the populations of L. rhamnosus GG. Results showed that there was no significant decrease in the viable counts of L. rhamnosus GG in products stored 4 °C. The survivability of L. rhamnosus GG decreased with increasing storage temperature and time. Product matrixes did not significantly affect the survival of L. rhamnosus GG except at 37 °C. Populations of L. rhamnosus GG were preserved at >6 logs in products stored at 4 °C for 48 wk and at 25 °C for 23 to 27 wk. At 37 °C, the 6‐log level could not be maintained for even 6 wk. The results suggest that peanut butter stored at 4 and 25 °C could serve as vehicles to deliver probiotics. Practical Application: Lactobacillus rhamnosus GG is clinically shown to effectively reduce the incidence of diarrhea in children. A food substrate is one of the major factors regulating the colonization of microorganisms in human gastrointestinal tracts. Peanut butter is a nutritious, low‐moisture food that could be a carrier for probiotics. In this study, we demonstrated the influence of storage conditions and product matrixes on the survival of L. rhamnosus GG. Results suggest that peanut butters could be effective delivery systems for probiotics and that probitic peanut butter could be used as one of the strategies to control diarrhea and malnutrition in developing countries.     

Controlling SO2 emissions in the roasting of gold concentrate

Acid pressure oxidation is generally believed to be the most effective pretreatment for refractory sulfide gold ores and concentrates, although it is ineffective for some ores. For such ores and concentrates (usually those containing both carbonaceous and sulfide materials), roasting remains the most effective pretreatment before cyanidation. However, the serious environmental damage that could result from the emission of SO₂ and As₂O₃ makes roasting an unattractive pretreatment step. In an effort to develop a technique having lower SO₂ emissions, a lime agglomeration roast (LAR) pretreatment process was investigated. The technique involves the agglomeration of calcium-based SO₂ sorbent with the refractory ore or concentrate before roasting. The results of the LAR pretreatment followed by cyanidation indicate that up to 95 percent of the sulfur dioxide can be captured and more than 90 percent gold extraction can be achieved.     

Analysis of self-assembled monolayers on gold surfaces using direct analysis in real time mass spectrometry

Mass spectrometry was performed on self-assembled monolayers (SAMs) of dodecanethiol on gold using the new direct analysis in real time (DART) ionization technique. Observed peaks for the SAMs included monomers, dimers, and trimers of the SAM molecules, with the dimer and trimer relative peak heights enhanced as compared to the spectra for neat dodecanethiol. The possibility that the observed peaks were due to residual (noncovalently bonded) material on the surface was tested by attempting to observe residual dodecanol. No peaks corresponding to dodecanol were observed. These results indicate that DART is an excellent ionization method for the direct and unambiguous mass analysis of chemical species in self-assembled monolayers.     

Survival of Probiotics in Hypromellose Capsules with Rice or Potato Maltodextrin Excipient

There is currently no authorized or established therapeutic level/dose of probiotics for proposed health benefits; however, a daily probiotic consumption of 10⁸ to 10¹⁰ CFU has been recommended. This study determined the survival of 5 individual probiotic strains, Lactobacillus rhamnosus, Lactobacillus paracasei, Lactobacillus plantarum, Lactobacillus acidophilus, and Bifidobacterium lactis, along with a mixture of the 5 strains in hypromellose capsules with rice or potato maltodextrin at 4, 25, and 37 °C for 12 mo. Samples were collected monthly and plated on deMan‐Rogosa Sharpe agar with 0.05% l ‐cysteine hydrochloride. Results showed that samples stored at 4 °C had an average count of 10⁸ to 10¹¹ CFU/g of probiotic cells during the 12 mo period, whereas at 25 °C, L. rhamnosus and L. paracasei had an average counts below 10⁸ CFU/g during the storage period. L. rhamnosus was the most vulnerable strain used in this study, having the least viable counts at all 3 storage temperatures. Probiotics stored in rice maltodextrin, on average, had higher probiotic counts compared to those stored in potato maltodextrin. Study suggests that to provide consumers with 10⁸ to 10¹⁰ CFU/d of probiotic cells, robust bacterial strains, suitable carriers, and a storage temperature of 4 °C are required.