Parametric study on smoothed particle hydrodynamics for accurate determination of drag coefficient for a circular cylinder

Simulations of two-dimensional (2D) flow past a circular cylinder with the smoothed particle hydrodynamics (SPH) method were conducted in order to accurately determine the drag coefficient. The fluid was modeled as a viscous liquid with weak compressibility. Boundary conditions, such as a no-slip solid wall, inflow and outflow, and periodic boundaries, were employed to resemble the physical problem. A sensitivity analysis, which has been rarely addressed in previous studies, was conducted on several SPH parameters. Hence, the effects of distinct parameters, such as the kernel choices and the domain dimensions, were investigated with the goal of obtaining highly accurate results. A range of Reynolds numbers (1–500) was simulated, and the results were compared with existing experimental data. It was observed that the domain dimensions and the resolution of SPH particles, in comparison to the obstacle size, affected the obtained drag coefficient significantly. Other parameters, such as the background pressure, influenced the transient condition, but did not influence the steady state at which the drag coefficient was determined.     

Controller synthesis with guaranteed closed-loop phase constraints

In this paper, we present an analysis and synthesis approach for guaranteeing that the phase of a single-input, single-output closed-loop transfer function is contained in the interval [−α,α] for a given α>0 at all frequencies. Specifically, we first derive a sufficient condition involving a frequency domain inequality for guaranteeing a given phase constraint. Next, we use the Kalman–Yakubovich–Popov theorem to derive an equivalent time domain condition. In the case where , we show that frequency and time domain sufficient conditions specialize to the positivity theorem. Furthermore, using linear matrix inequalities, we develop a controller synthesis approach for guaranteeing a phase constraint on the closed-loop transfer function. Finally, we extend this synthesis approach to address mixed gain and phase constraints on the closed-loop transfer function.     

He’s homotopy perturbation method: A strongly promising method for solving non-linear systems of the mixed Volterra–Fredholm integral equations

In this paper, He’s homotopy perturbation method is applied to solve non-linear systems of mixed Volterra–Fredholm integral equations. Two examples are presented to illustrate the ability of the method. Also comparisons are made between the Adomian decomposition method and the homotopy perturbation method. The results reveal that He’s homotopy perturbation method is very effective and simple and in these examples leads to the exact solutions.     

Facile synthesis of polyoxometalate-based composite with doped ternary NiCoFe cations as electrocatalyst for oxygen evolution reaction

The construction of efficient and low-cost electrocatalysts for oxygen evolution reactions (OER) to replace precious catalysts is a necessity to achieve economic production of hydrogen. Herein, we report an efficient tri-metallic electrocatalysts for the OER that is prepared by incorporate nickel, cobalt and iron cations on Triton X-100/phosphotungstic acid organic-inorganic composite without utilize any binders or energy consumer procedure. Considering to the synergy effect of simultaneous absorption of NiCoFe cations on composite substrate, the as-made tri-metallic catalyst exhibits excellent OER activity with a small overpotential of 210 and 330 mV at a current density of 10 and 100 mA cm^?2, respectively. Moreover, remarkable trends in electrocatalytic activity of mono-, bi- and tri-metallic electrocatalysts at low (10 mA) and high (100 mA) current density are observed. In addition, this new families of non-precious metal catalyst shows long-term durability in 1 M KOH.     

Plasticized poly(vinyl chloride) composites: Influence of different nanofillers as antimigration agents

In this study, plasticized poly(vinyl chloride) (PVC) composites with different nanofillers, including single‐walled carbon nanotubes (SWCNTs), organoclay, TiO₂, and ZnO nanoparticles, were prepared, and their effects on plasticizer migration were investigated. Scanning electron micrographs revealed the dispersion quality of the nanofillers in the polymer matrix. It had a significant influence on the performance of the nanofillers in the process of plasticizer migration. Migration and exudation tests showed that the nanofillers could efficiently hinder plasticizer migration. On the basis of these results, we concluded that carbon nanotubes were the best antimigration agent in the plasticized system. This was ascribed to the high aspect ratio of the SWCNTs and the good interactions between them and the plasticizer. Also, TiO₂ nanoparticles showed a better performance compared to the ZnO nanoparticles. This was due to the more homogeneous dispersion of the TiO₂ in the polymer matrix and the higher surface area of the particles. The differential scanning calorimetry thermograms were in good agreement with the migration tests. The lowest change in the glass‐transition temperature was observed for the composite filled with SWCNTs. This indicated that a lower amount of the plasticizer migrated from PVC. The thermogravimetric analysis curves showed that the incorporation of the nanofillers improved the thermal stability of the PVC. The results could be useful for determining the efficiency of plasticized PVC in applications. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132, 42559.     

Direct synthesis of bi-modal porous structure MCM-41 and its application in CO2 capturing through amine-grafting

A bi-modal porous structure MCM-41 (BPS-MCM-41) was synthesized and functionalized by 3-[2-(2-Aminoethylamino)ethylamino]propyltrimethoxysilane (TRI); also, its performance in amine grafting and CO₂ capturing was compared with that of pore-expanded MCM-41 [1]. To create larger pores beside the mesoporous structure of MCM-41, carbon black nanoparticles were used as the solid template. Characterizing the BPS-MCM-41 using the BET and BJH techniques resulted in the surface reduction of 29.3 percent and volume increase of 68.46 percent. The pore size distribution showed two peaks: a narrow peak at 2.24 nm diameter, which belonged to micelles, and a wide one at about 50 nm due to the presence of used nanoparticles. The functionalization confirmed that BPS-MCM-41 is capable of accommodating a large quantity of amine groups. The CO₂ adsorption measurement indicated that internal volume of the adsorbent was a critical factor affecting the adsorption capacity of the amine grafted adsorbents.     

Oxidation Behavior of Nanostructured Ni-5Al Coating. A case Study on Monophase Coatings

Protection of Metals and Physical Chemistry of Surfaces - Oxidation behavior of nanostructured Ni-5Al HVOF coatings was studied. For this purpose, isothermal oxidation of the free standing coatings...     

An alternative measure of the ICT-Opportunity Index

We developed an alternative approach for measuring information and communication technology (ICT), applying Data Envelopment Analysis (DEA) using data from the International Telecommunications Union as a sample of 183 economies. We compared the ICT-Opportunity Index (ICT-OI) with our DEA-Opportunity Index (DEA-OI) and found a high correlation between the two. Our findings suggest that both indices are consistent in their measurement of digital opportunity, though differences still exist in different regions. Our new DEA-OI offers much more than the ICT-OI. Using our model, the target and peer groups for each country can be identified.