Preparation and electrochemical characterization of Ti-based amorphous metallic glass with high strength

Ti-based amorphous metallic glasses have excellent mechanical, physical, and chemical properties, which is an important development direction and research hotspot of metal composite reinforcement. As a stable, simple, efficient, and large-scale preparation technology of metallic powders, the gas atomization process provides an effective way of preparing amorphous metallic glasses. In this study, the controllable fabrication of a Ti-based amorphous powder, with high efficiency, has been realized by using gas atomization. The scanning electron microscope, energy-dispersive spectrometer, and X-ray diffraction are used to analyze surface morphology, element distribution, and phase structure, respectively. A microhardness tester is used to measure the mechanical property. An electrochemical workstation is used to characterize corrosion behavior. The results show that as-prepared microparticles are more uniform and exhibit good amorphous characteristics. The mechanical test shows that the hardness of amorphous powder is significantly increased as compared with that before preparation, which has the prospect of being an important part of engineering reinforced materials. Further electrochemical measurement shows that the corrosion resistance of the as-prepared sample is also significantly improved. This study has laid a solid foundation for expanding applications of Ti-based metallic glasses, especially in heavy-duty and corrosive domains.     

伊拉克米桑油田水平井钻井关键技术

针对伊拉克米桑油田盐膏层巨厚、钻井液密度窗口窄、存在高压盐水层,储层段漏塌同层导致复杂时效高等问题,通过对比分析国内外盐膏层和窄压力窗口地层钻井技术,总结了米桑油田钻井面临的主要技术难点,从井身结构优化、钻井提速和复杂预防等方面入手,研究形成了适合米桑油田的钻井关键技术,并进行了现场试验应用,取得了显著的效果.伊拉克米桑油田钻井关键技术对该地区钻井技术方案设计和钻井提速提效具有较强的借鉴和指导作用.     

Crystallization,structure, and enhanced mechanical property of ethylene-octene elastomer crosslinked with dicumyl peroxide

Crosslinking of polyolefin elastomer (POE, ENGAGE™ 8480) with Dicumyl Peroxide (DCP) can have effects on its crystallization dynamics, crystal structure, and properties. The POE crosslinked uniformly has significantly lower crystalline ability than the one with only amorphous phase crosslinked, which, in turn, has weaker crystalline ability than neat POE. The crystallinity and melting point depend on how the POE is crosslinked. The neat POE and POE crosslinked in amorphous phase only, are investigated with DSC and in-situ tensile/synchrotron radiation (WAXD/SAXS). In situ tensile/synchrotron X-ray during a uniaxial stretching process indicates that severe crystal fragmentation is observed at a strain around 45%, and with further increase in strain. The stress in the crosslinked POE is significantly larger than neat POE. For both samples, crystal orientation increases sharply within the strain range up to 88% where orientation-induced new crystals aligned in stretching direction are observed. The long period increases more in stretching direction for the crosslinked POE, consistent with larger stress in this sample, and the stress difference is more pronounced at large strains (27.3 vs. 10.9 MPa at a strain 435%). Permanent set of the crosslinked POE is smaller, consistent with less oriented crystals observed after the test for permanent set.     

Simultaneous fractionation of multiple classes of polyphenols from honeybush tea using solid-phase extraction

The structural diversity of polyphenols and the inherent limitations of current extraction techniques pose a challenge to extract polyphenols using a simple and green method. Hence, in this study, a method was developed to simultaneously fractionate multiple classes of polyphenols by only varying ethanol-water solutions. Honeybush tea, which is rich in polyphenols, was selected as a model for this study. Solvent extraction followed by solid-phase extraction (SPE) was developed to obtain a polyphenol-rich fraction from six honeybush samples. Based on a gradient elution programme (10%, 30%, 50%, 70% and 90% (v/v) ethanol-water solution) of SPE, the Strata X cartridge showed a better recovery of most targeted polyphenols under 0.9 mL of the drying volume and 1 mL min⁻¹ of the dispensing speed. The elution programme for fractionating most polyphenols was as follows: single elution with 50% ethanol, followed by twice elution with 70% ethanol. The antioxidant capacity was used to analyse the differences among the polyphenol-rich fractions from six honeybush samples. Principal component analysis (PCA) revealed that unfermented C. genistoides (GG) has the greatest antioxidant capacity among the honeybush species studied. Additionally, mangiferin, isomangiferin and vicenin-2 were the main contributors to the antioxidant capacity in six honeybush fractions according to the correlation study.     

有机二氟化硼配合物的合成及压致变色性能表征

以阿伏苯宗和三氟化硼为原料,经过一步反应,合成阿伏苯宗二氟化硼(BF2AVB),产物的结构经1HNMR谱确证.基于荧光光谱与X射线粉末衍射测试,对BF2AVB的压致发光性能和机理进行研究.本实验原料易得,反应条件温和,实验操作简单,反应收率高.BF2AVB的压致变色现象明显,通过探讨压致变色机理,加深同学对压致变色材料的了解.同时,该实验可以拓展学科知识,激发学生的专业热情和科研兴趣.     

低分子量聚丙烯酸钾的合成及其应用

采用水溶液聚合法制备了低分子量聚丙烯酸钾（PAAK），并作为新型消焰剂加入单基发射药中。通过火焰原子吸收光谱法测试了PAAK中钾的含量；用乌氏黏度计测定了特性黏度；采用DSC法研究不同pH值的PAAK与硝化棉（NC）的相容性；利用充氮氧弹法对添加PAAK、硝酸钾KNO₃、硫酸钾K₂SO₄的单基发射药的燃烧残渣进行了对比研究。结果表明，合成的PAAK中，钾的质量分数为15.21%，相对分子量在3 000左右，有利于和NC均匀混合，且在中性或微碱性（pH＝7.0~7.5）的情况与NC相容性良好。与传统的KNO₃、K₂SO₄消焰剂相比，PAAK能够和NC均匀混合，制备均质透明的单基发射药；PAAK发射药的燃烧残渣最少，占发射药质量的0.18%。     

岳城煤矿复杂地质条件下工作面设计优化

为了提高煤炭资源回收率,对岳城煤矿3号煤三盘区最后两个小工作面回采区域的回收布置进行了研究,利用巷道外错布置工艺,对该区域进行整体布置,优化工作面设计,既回采了两个小工作面,又回收了与1308工作面之间的煤柱和原南河滩煤矿的部分大巷煤柱,增加了资源回收,简化了生产系统,实现了科学高效回采。