Characterization and methanol adsorption of walnut-shell activated carbon prepared by KOH activation

Walnut-shellactivated carbons(WSACs)were prepared by the KOH chemicalactivation.The effects of carbonization temperature,activation temperature,and ratio of KOH to chars on the pore development of WSACs were investigated.Fourier transform infrared spectroscopy(FTIR),X-ray powder diffraction(XRD),and scanning electron microscopy(SEM)were employed to characterize the microstructure and morphology of WSACs.Methanoladsorption performance onto the optimalWSAC and the coal-based AC were also investigated.The results show that the optimalpreparation conditions are a carbonization temperature of 700 ℃,an activation temperature of 700 ℃,and a mass ratio of 3.The BET surface area,the micropore volume,and the micropore volume percentage of the optimalWASC are 1636 m~2/g,0.641 cm~3/g and 81.97%,respectively.There are a lot of micropores and a certain amount of meso-and macropores.The characteristics of the amorphous state are identified.The results show that the optimalWSAC is favorable for methanoladsorption.The equilibrium adsorption capacity of the optimalWSAC is 248.02mg/g.It is shown that the equilibrium adsorption capacity of the optimalWSAC is almost equivalent to that of the common activated carbon.Therefore the optimalWSAC could be a potentialadsorbent for the solar energy adsorption refrigeration cycle.     

免费翻译工具中的全能王——谷歌金山词霸合作版

●金山词霸有史以来第一个完全免费的版本今年五月,金山软件与全球最大的搜索引擎公司谷歌(Google)联合推出品牌产品"谷歌金山词霸","谷歌金山词霸"于是就成了金山词霸十二年发展历程中     

“平头型”掏挖基础在输电线路工程中的应用

笔者就输电线路工程设计中有关掏挖基础应用时常遇到的几个问题作特别提出,并通过对相关规范、资料等的分析理解,结合国网公司"两型三新"输电线路的设计导则,提出与常规设计相反的思路,即原状土掏挖基础宜采用"不露头"的个人观点,供各位同行作参考。     

基带池技术在航天测控和数传系统的应用

本文针对传统航天测控与数传系统业务中基带设备套量繁多、专用性强、互替换性差^[1]、设备备份链路复杂、系统扩容升级改造不便等缺点,研究了基带池技术的设计理念和关键技术要求,并提出了一种基于基带池技术的设计架构和方案,基本的基带处理资源和颗粒可按需进行动态分配和部署,从而有效提高卫星地面测控和数传通信资源的利用率,且便于维护和扩容。     

Effect of rare earth addition on Cu-Fe/AC adsorbents for phosphine adsorption from yellow phosphorous tail gas

Phosphine(PH3) is a highly toxic air pollutant,commonly produced in phosphorous chemical industry.But it has received less research attention due to its handling difficultly.CO is the main content of the phosphorous chemical industry tail gas,the concentration of which is always more than 80 vol.%,and it can be the feed gas to produce various valuable products such as formate,oxalate,and methanol and so on.But,PH3 is one of the important barriers,which is harmful to the following chemical process.In order to make use of the tail gas,PH3 should be removed firstly,and CO should be covered in the whole purified procedure at the same time.In this work,the modified activated carbon(MAC) was used as the adsorbent to separate PH3 from the mixture tail gas.Series of MAC adsorbents were prepared for the adsorption of PH3,which loaded Cu-Fe and Ce(La),or separately.The PH3 adsorption capacities,chemical and physical properties of MAC were all investigated.The results showed that over 99% PH3 adsorption efficiency was achieved when used MAC adsorbents.The removal efficiency and PH3 adsorption capacity of the Cu-Fe-Ce/AC(20:1:0.4) were both much higher than those modified activated carbons.The maximum PH3 adsorption capacity was 71 mg of PH3/g of MAC on the Cu-Fe-Ce/AC,which were much higher than literature data using CuO only for adsorbing hydride gases.     

基于VB的变压器故障可视化模糊诊断

为克服传统变压器绝缘故障诊断的局限性,以得到准确全面的诊断结果,将可视化技术与模糊数学相结合,用于变压器故障诊断专家系统。该系统采用VB(Visual Basic)程序设计语言和TeeChart图表图形控件工具来实现变压器故障诊断的二维/三维可视化输出,并利用模糊数学方法构造编码隶属度函数来刻画边界点的模糊区间。实例分析结果表明,用该法有效解决了单一变压器故障诊断法的误诊断或诊断结果不全面等问题,更准确全面地反映变压器故障信息,具有实际意义。     

基于SOM网络的服装号型设置

以MATLAB平台为基础,利用神经网络工具箱构建了自组织神经网络,对测量的1860组样本数据进行SOM聚类,并用轮廓系数对聚类结果进行评价.指出在无监督聚类分析中,SOM聚类方法操作过程简便易行,具有残缺自动识别能力,分类结果唯一,可以在服装号型设置中应用.     

水力喷射压裂工艺在水平井的应用

水力喷射压裂工艺包括水力喷砂射孔、水力喷射压裂、停泵裂缝闭合、压裂液返排4个阶段。该工艺首先在老井选层压裂施工中应用取得了成功,避免了下桥塞、下顶封、验串等繁琐工序,工艺简单、成本低廉,安全可靠。多级水力喷射压裂工艺在水平井中的成功应用,实现一趟管柱多级水力喷砂射孔,不仅具有以上优势,还节省射孔费用。此技术在二连地区的广泛应用,取得了理想的压裂成果。     

石油人也能建核电

在市场萎缩、竞争十分激烈的形势下,中油一建敢揽"瓷器活儿",首次进入核电建设领域,参建世界最先进AP1000核电主泵试验台,使核电技术国产化进程又向前迈进了一步。7月29日,从中国石油工程建设公司一建公司石化设备厂传来消息,这个"中国石油装备"背书品牌授权单位奋战一年零三个月,圆满实现我国AP1000核电主泵试验台管道项目中交,标志着世界最先进的核电技术的国产化进程又向前迈进了一步。     

颗粒级配提高球形银粉振实密度的研究

以链烷醇胺为分散剂,用对苯二酚C6H4(OH)2还原硝酸银,通过调节硝酸银浓度、还原剂配比以及分散剂添加量等工艺参数实现对银粉粒径的控制。用扫描电镜(SEM)表征银粉的形貌、球形度和分散性;用激光粒度分布仪测试不同粒径银粉的粒度分布;参照GB 5162-85测试不同粒径粉体和级配后粉体的振实密度。结果表明:制备的银粉表面粗糙度低、球形度和密实度高,其流动性随粒径的减小变差,振实密度随之减小。合适的颗粒级配能有效提高粉体的振实密度,其最大值达到4.75 g/cm^3。