Experimental investigation of Co and Fe-Doped CuO nanostructured electrode material for remarkable electrochemical performance

The current research work presents a facile and cost–effective co-precipitation method to prepare doped (Co & Fe) CuO and undoped CuO nanostructures without usage of any type of surfactant or capping agents. The structural analysis reveals monoclinic crystal structure of synthesized pure CuO and doped-CuO nanostructures. The effect of different morphologies on the performance of supercapacitors has been found in CV (cyclic voltammetry) and GCD (galvanic charge discharge) investigations. The specific capacitances have been obtained 156 (±5) Fg^?1, 168(±5) Fg^?1 and 186 (±5) Fg^?1 for CuO, Co-doped CuO and Fe-doped CuO electrodes, respectively at scan rate of 5 mVs^?1, while it is found to be 114 (±5) Fg^?1, 136 (±5) Fg^?1 and 170 (±5) Fg^?1 for CuO, Co–CuO and Fe–CuO, respectively at 0.5 Ag^-1 as calculated from the GCD. The super capacitive performance of the Fe–CuO nanorods is mainly attributed to the synergism that evolves between CuO and Fe metal ion. The Fe-doped CuO with its nanorods like morphology provides superior specific capacitance value and excellent cyclic stability among all studied nanostructured electrodes. Consequently, it motivates to the use of Fe-doped CuO nanostructures as electrode material in the next generation energy storage devices.     

EFFECT OF CHILLING AND FREEZING ON SURVIVAL OF VIBRIO PARAHAEMOLYTICUS ON FISH FILLETS1

Vibrio parahaemolyticus is a foodborne pathogen isolated from coastal waters of the United States, and from seafoods including fish. No information is available on the viability of V. parahaemolyticus on raw, chilled and frozen fish. A three‐strain mixture of V. parahaemolyticus was inoculated on fish fillets (pH 6.4) to obtain a bacterial load of 10⁴ (high) or 10³ (low) CFU/fillet, and stored at 4C or 8C for 9 days or at – 18C for seven weeks. At 4C and 8C, and at both levels of inoculation, V. parahaemolyticus survived on the fillets for the entire duration of the study. However, there was a significant reduction (P < 0.01) in V. parahaemolyticus population on the fillets by 9 days of storage. In the frozen fillets, there was a sharp decline (P < 0.01) in the population of V. parahaemolyticus by day 5 of storage. Although chilling and freezing significantly (P < 0.01) inactivated high numbers of V. parahaemolyticus on fish, they cannot be relied upon as a method to reduce V. parahaemolyticus on fish, since the time and magnitude of reduction depends on the initial load of the pathogen and the storage temperature.     

Effect of Oxide Defect Structure on the Electrical Properties of ZrO2

The defect structure of monoclinic ZrO₂ was studied by measuring the transfer numbers and electrical conductivity as functions of O₂ pressure and temperature. The data suggest a defect structure of doubly ionized oxygen vacancies at low pressures, i.e. <10⁻¹⁹ atm, and singly ionized oxygen interstitials at pressures >10⁻⁹ atm. Zirconia is primarily an ionic conductor below #700°C and an electronic conductor at 700° to 1000°C for 10⁻²²≤P_o2≤1 atm.     

Synthesis and characterization of stable aqueous dispersions of graphene

A stable aqueous dispersion (5 mg ml^?1) of graphene was synthesized by a simple protocol based on three-step reduction of graphene oxide (GO) dispersion synthesized using the modified version of Hummers and Offeman method. Reduction of GO was carried out using sodium borohydride, hydrazine hydrate and dimethyl hydrazine as reducing agents. The chemically synthesized graphene was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), UV–visible absorption spectroscopy, Fourier transform infrared (FTIR) and Raman spectroscopy, thermogravimetric analysis (TGA), optical microscopy. The stability of aqueous dispersions of graphene was confirmed through zeta potential measurements and the negative zeta potentials of 55–60 mV were obtained indicating the high stability of aqueous graphene dispersions.     

Preparation and characterization of PAN–KI complexed gel polymer electrolytes for solid-state battery applications

The free standing and dimensionally stable gel polymer electrolyte films of polyacrylonitrile (PAN): potassium iodide (KI) of different compositions, using ethylene carbonate as a plasticizer and dimethyl formamide as solvent, are prepared by adopting ‘solution casting technique’ and these films are examined for their conductivities. The structural, miscibility and the chemical rapport between PAN and KI are investigated using X-ray diffraction, Fourier transform infrared spectroscopy and differential scanning calorimetry methods. The conductivity is enhanced with the increase in KI concentration and temperature. The maximum conductivity at 30°C is found to be 2.089 × 10^?5 S cm^?1 for PAN:KI (70:30) wt%, which is nine orders greater than that of pure PAN (< 10^?14 S cm^?1). The conductivity-temperature dependence of these polymer electrolyte films obeys Arrhenius behaviour with activation energy ranging from 0.358 to 0.478 eV. The conducting carriers of charge transport in these polymer electrolyte films are identified by Wagner’s polarization technique and it is found that the charge transport is predominantly due to ions. The better conducting sample is used to fabricate the battery with configuration K/PAN + KI/I₂+ C + electrolyte and good discharge characteristics of battery are observed.     

Effect of near-critical swirl on the Burke-Schumann reaction sheet

The influence of swirl on the shape of the Burke-Schumann reaction sheet in a straight cylindrical pipe is investigated by asymptotic and numerical means. Attention is confined to swirl levels that are near the critical value at which vortex breakdown occurs. A high-Reynolds-number, laminar, isothermal, low-Mach-number reacting flow is considered. An asymptotic analysis is developed to study the nonlinear interaction between near-critical swirl and mixture fraction distribution within the flow. It is first shown that leading-order perturbation of the velocity field from the columnar state, generated by the interaction of near-critical swirl and low viscosity, can be described by a nonlinear reduced-order model. This flow perturbation is computed, and then employed to determine the correction to the classical Burke-Schumann solution. Under lean conditions of reaction the reaction sheet becomes shorter and more compact as swirl is increased. For rich conditions of reaction, increasing swirl first causes the reaction-sheet length to decrease, and then increase after vortex breakdown has appeared. Numerical simulations of the flow and reaction-zone shape are substantiated by, and supplement, the asymptotic results.     

Quasi-cleavage fracture planes in spheroidized A533B steel

Electron backscattered diffraction (EBSD) has been used to acquire crystal orientation information around unusual microcracks induced by tensile deformation of notched specimens of spheroidized A533B steel. This unusual fracture mode has been called quasi‐cleavage and occurs at relatively low temperatures with fracture energies below that of the upper shelf. EBSD measurements on sectioned samples showed that the quasi‐cleavage cracks were intragranular. A two‐dimensional analysis technique was used in which EBSD measured crystal orientations were combined with secondary electron imaging to obtain the trace of the crack facet on the section plane. The measurements revealed that the observed crack facets were consistent with crack propagation along the {001} and {011} planes.     

Assessment of Metal Contamination in the Mine Water of the West Bokaro Coalfield,India

This study was carried out in the West Bokaro coalfield area of the Jharkhand state of India to assess water quality for drinking and domestic purposes. Thirty mine water samples were collected from opencast and underground mines, and concentrations of Al, As, Ba, Cr, Cu, Fe, Mn, Ni, Se, and Zn were determined using ICP-MS. Spatial distribution maps were prepared using GIS software so that the quality of the mine water could be easily understood. Metal concentrations were higher in the pre-monsoon season than in the post-monsoon season, irrespective of location, but there were more significant seasonal variations in the opencast mine water than in the underground mine water. The concentrations of Al, Ba, Fe, Mn, and Ni exceeded the desirable as well as the permissible drinking water limits in both seasons. The quality of the surface water as well as the groundwater in the region may be adversely affected by the high metal concentrations in this mine water.     

Generalized probability model for estimating the proportion of the female population at different levels of fertility based on census sampling from a mixed population

The present exercise is an attempt to generalize a probability model referring to the waiting time distribution for conception in a mixed group of fecund females with two varying levels of fecundity, based on a census sample truncated at time T =t from the date of resumption of fecundity following an earlier conception (Biswas, 1975, Sankhya, Series B, 37, Part III). The generalization is made in two aspects, viz. instead of fixed conception rates, time-dependent rates decreasing with the age of the woman have been used. Additionally, unlike the model of Biswas (1975) consisting of two different fecund groups, three different levels of fecundity have been taken into consideration in this paper. Estimates of the proportion of fecund females over time, viz. π_i(t) (i = 1, 2, 3) are attempted by the method of maximum likelihood on the basis of a census sample truncated at time T = t under the generalized set up.