Purification,structural data and biological properties of polysaccharide from Prunus amygdalus gum

This work demonstrates the efficiency of almond gum polysaccharides (AGPs) as bioactive compounds. AGPs were first extracted using H₂O₂, in the presence of NaOH, at different times and temperatures. The optimal extraction conditions were 4% H₂O₂ and 2 N NaOH, for 7 h at 50 °C, leading to an extraction yield of 58.2% (w/w). After a purification step, the retained AGPs were characterised using high‐performance liquid chromatography showing a molecular weight of 99.3 kDa. The monosaccharide composition of AGPs were assessed using gas chromatography–mass spectrometry. AGPs were found to be a complex heteropolysaccharide with a repeating unit mainly composed of galactose, arabinose, xylose, mannose, rhamnose, and glucuronic acid with the respective ratios: 45:26:7:10:1:11. The acidic nature of the polysaccharide is due to the presence of glucuronic acid. Total antioxidant activity, free radical‐scavenging activity and reducing power assay of AGPs were investigated. The obtained results showed high antioxidant activities of AGPs. Furthermore, beyond 60 mg mL^?1, AGPs exhibited bacterial growth inhibition for five pathogenic strains: Escherichia coli, Staphylococcus aureus, Enterococcus feacalis, Pseudomonas aeruginosa and Salmonella typhimurium.     

Absolute Stability of Nonlinear Systems with Two Additive Time-varying Delay Components

In this paper, we present a new sufficient condition for absolute stability of Lure system with two additive time-varying delay components. This criterion is expressed as a set of linear matrix inequalities (LMIs), which can be readily tested by using standard numerical software. We use this new criterion to stabilize a class of nonlinear time-delay systems. Some numerical examples are given to illustrate the applicability of the results using standard numerical software.     

Absolute stability of nonlinear systems with two additive time-varying delay components

In this paper, we present a new sufficient condition for absolute stability of Lure system with two additive time-varying delay components. This criterion is expressed as a set of linear matrix inequalities (LMIs), which can be readily tested by using standard numerical software. We use this new criterion to stabilize a class of nonlinear time-delay systems. Some numerical examples are given to illustrate the applicability of the results using standard numerical software.     

Robust control of T‐S fuzzy systems with time‐varying delay using new approach

This paper aims to design a controller to robustly stabilize uncertain nonlinear systems with time‐varying delay and norm bounded uncertainties via Takagi–Sugeno (T‐S) fuzzy model. The stabilization conditions are given in the form of linear matrix inequalities using a single Lyapunov–Krasovskii functional (LKF) combining the introduction of some relaxation matrices and only one tuning parameter. In comparison with the existing techniques in the literature, the proposed approach has two major advantages. The first is the reduction of computational complexity when the number of IF‐THEN rules, r, is big. The second concerns the conservatism reduction. Several examples are given to show the effectiveness and the merits of the design procedure. Copyright © 2009 John Wiley & Sons, Ltd.     

Mesoscopic approach for steady‐state free convection in a diamond array

The purpose of the present paper is testing an in‐house efficiency algorithm based on lattice Boltzmann method (LBM) and using it to resolve the obtained coupled nondimensional governing equations to analyze two‐dimensional free convection inside a cold outer cavity subjected to a heated cylindrical diamond array. Steady state or oscillatory results are obtained using the Bhatnagar‐Gross‐Krook collision model associated to the thermal LBM. Both the velocity and temperature fields are solved using the D2Q9 models. With different Rayleigh numbers (Ra), the tested free convection can either achieve to steady state or oscillatory. We extended our in house Fortran 90 code using curved boundary conditions and implemented them into a cavity with a diamond array. The numerical simulations were done using distinct Ra (10⁶ and 10 ⁷) and distances between the four neighboring circular cylinders aligned in a diamond array. The effects of several physical parameters, including Ra and position of the hot body array on flow and heat transfer characteristics are investigated. The obtained results are highlighted in the form of streamlines, isotherms, and velocities plots. We show in this paper the stability and the efficiency of the LBM to deal with a complex geometry and its ability to reach suitable convergence criteria for high Ra (10 ⁶ and 10 ⁷). The numerical results indicate that LBM can simulate numerical problems with a high Ra reaching a steady state where we can depict the change of the flow pattern and enhancement of the heat transfer in the presence of heated diamond array.     

Electrochemical degradation of waters containing O-Toluidine on PbO2 and BDD anodes

Electrochemical oxidation of O-Toluidine (OT) was studied by galvanostatic electrolysis using lead dioxide (PbO₂) and boron-doped diamond (BDD) as anodes. The influence of operating parameters, such as current density, initial concentration of OT and temperature was investigated. Measurements of chemical oxygen demand were used to follow the oxidation. The experimental data indicated that on PbO₂ and BDD anodes, OT oxidation takes place by reaction with electrogenerated hydroxyl radicals and is favoured by low current density and high temperature. Furthermore, BDD anodes offer significant advantages over PbO₂ in terms of current efficiency and oxidation rate.     

Optimising operating conditions in ultrafiltration fouling of pomegranate juice by response surface methodology

The resistance‐in‐series model was used to analyse flux behaviour, which involved the resistances of membrane itself, the fouling and solute concentration polarisation. Response surface methodology was used to establish the relationships between operating parameters and ultrafiltration (UF) efficiency and thus to determine optimal conditions. Experiments were performed according to Box–Behnken design by changing the levels of three parameters, namely transmembrane pressure, feed flow rate and temperature. The fitted mathematical models allowed us to plot isoresponse curves. It was shown that the resistance due to solute concentration polarisation (R_cp) dominated the flux decline (40–74%). The fouling resistance (R_f) varied from 12 to 46%. To optimise simultaneously the three responses studied (R_f, R_cp and permeate limit flux), we applied the desirability function approach which allowed us to determine the best acceptable compromise. The selected UF conditions of the compromise were as follows: three bars, 0.95 L min^?1 and 30 °C. Optimal values of R_f, R_cp and permeate limit flux were equal to 18%, 72% and 19 L h^?1 m^?2, respectively.     

Pyrene-adamantane-β-cyclodextrin: An efficient host–guest system for the biofunctionalization of SWCNT electrodes

The design of nanostructured biological architectures based on host–guest interactions between β-cyclodextrin and adamantane was investigated on SWCNT coatings using glucose oxidase (GOX) as biomolecule model. β-Cyclodextrin tagged GOX was immobilized on adamantane functionalized carbon nanotubes, deposited on platinum electrodes. Different functionalization techniques to attach “pyrene adamantane” on nanotubes were studied and compared in terms of the performances of the subsequently constructed glucose biosensors. The best results were obtained by dipping the nanotube deposit into a pyrene-adamantane solution followed by electropolymerization of the adsorbed pyrene monolayer. The constructed biosensor exhibited a good linear response toward glucose concentrations between 2 × 10⁻⁷ M and 1.6 × 10⁻³ M. The maximum current density and glucose sensitivity were 154.9 μA cm⁻² and 14.4 mA M⁻¹ cm⁻², respectively.