Al2O3/Al composites produced by directed melt oxidation using Zn containing external dopants

Al₂O₃/Al composites have been produced by the directed melt oxidation of Al with externally applied Zn containing dopants. Zn, ZnO and ZnAl₂O₄ are all shown to be capable of initiating the directed melt oxidation of Al without any Mg being present. The external surfaces of the reaction products were covered with a layer of ZnO overlaying a layer of ZnAl₂O₄, however, no Zn was observed within the composite bodies. Doping with ZnO or ZnAl₂O₄ resulted in a fine, dense ceramic microstructure and the amount of growth increased with increasing firing time and increasing ZnO or ZnAl₂O₄ content. Doping with Zn resulted in significantly less dense composites to those produced using ZnO or ZnAl₂O₄ and thus in the Zn system oxide and spinel dopants offer a significant advantage over using metallic Zn.     

Optimizing natural rubber blends for examination gloves: Vacuum radiation for mechanical strength and solvent barrier

Natural rubber (NR) is emblematic of sustainability compared to synthetic rubber. However, the tradition of adding sulfur as a vulcanization ingredient results in the release of toxic substances and the potential for health issues. In this study, a feasible strategy was proposed to replace sulfur and discover a safe bulk modification process for NR films. The results have shown that the NR particle size was disintegrated to below 10 nm by gamma irradiation. High tension strength up to 24.45 MPa was observed in the vulcanized NR blend film, which could be elongated up to 800% strain after exposure to an optimum dose of 14 kGy. In comparison to commercial NR latex and nitrile gloves, the vulcanized NR/ SIS films exhibited better chemical resistance ability against hexane, methanol, toluene, and acetone, as revealed by the permeation test. The appearance of amorphous regions and highly oriented NR crystallites was observed through transmission electron microscopy. Findings from this study propose the vacuum radiation strategy that can replace conventional vulcanization methods, resulting in NR films with high mechanical and barrier performance. Furthermore, the emission of toxic substances is reduced by this green process, making it practically useful for potential chemical-resistant examination glove applications.     

Temporal changes in the periphytic algal communities in a drowned tropical forest reservoir in Malaysia: Lake Kenyir

Periphytic algal assemblages, comprising bacillariophytes, cyanophytes and chlorophytes of standing dead trees in Lake Kenyir, a tropical drowned forest reservoir, were studied during 1995. A total of 317 algal taxa were identified in this study. The monthly floral mean species richness and cell count data demonstrated significant temporal differences between the months, in one-way anova (P < 0.05). Both redundancy analysis and cluster analysis on monthly blue-green abundance and diatom assemblages exhibited conspicuous groupings among the months, with underpinning seasonal differences. The responses were not similar, however, between the upstream and downstream ends of the lake. The grouping or clustering of months can be generalized as: (i) November, December and January as the monsoonal months; (ii) February, March, April and May as the transitional months; and (iii) June to October as the dry months. Based on stepwise multiple regression with forward selection, alkalinity and dissolved oxygen concentration were significant environmental predictors at the downstream dam sampling site, and reactive silica, electrical conductivity, Secchi depth transparency and sunshine hours were significant predicators at the upstream riverine sampling site, based on Monte Carlo tests. Being a ploymictic, mesotrophic lake, the limnology and temporal changes for Lake Kenyir appears to be complex and driven by monsoons, as evidenced from the temporal changes in its periphytic algae communities, particularly the diatom assemblages. The downstream sampling site (site 1) at the dam, in the main basin and deeper zone of the lake, the seasonal amplitude was likely complex because of thermocline formation and stratification processes. In contrast, the upstream sampling site in the Petang River (site 2) exhibited a clearer distinction between the dry and monsoon months, based on its cyanophyte and diatom floral assemblages. These study results are pertinent for lake management, especially for developing biomonitoring programmes or lake productivity studies, as well as for climate change studies, within the context of tropical lake ecology.     

Potent Antidiabetic Activity and Metabolite Profiling of Melicope Lunu‐ankenda Leaves

Diabetes mellitus is normally characterized by chronic hyperglycemia associated with disturbances in the fat, carbohydrate, and protein metabolism. There is an increasing trend of using natural products instead of synthetic agents as alternative therapy for disorders due to their fewer side effects. In this study, antidiabetic and antioxidant activities of different Melicope lunu‐ankenda (ML) ethanolic extracts were evaluated using inhibition of α‐glucosidase and 2,2‐diphenyl‐l‐picrylhydrazyl (DPPH) radicals scavenging activity, respectively; whereas, proton nuclear magnetic resonance (¹H NMR) and ultra‐high performance liquid chromatography‐tandem mass spectrometric (UHPLC‐MS/MS) techniques were used for metabolite profiling of ML leaf extracts at different concentrations of ethanol and water. Sixty percent of ethanolic ML extract showed highest inhibitory effect against α‐glucosidase enzyme (IC₅₀ of 37 μg/mL) and DPPH scavenging activity (IC₅₀ of 48 μg/mL). Antidiabetic effect of ML extracts was also evaluated in vivo and it was found that the high doses (400 mg/Kg BW) of ML extract exhibited high suppression in fasting blood glucose level by 62.75%. The metabolites responsible for variation among ML samples with variable ethanolic levels have been evaluated successfully using ¹H‐NMR–based metabolomics. The principal component analysis (PCA) and partial least squares(PLS) analysis scores depicted clear and distinct separations into 4 clusters representing the 4 ethanolic concentrations by PC1 and PC2, with an eigenvalue of 69.9%. Various ¹H‐NMR chemical shifts related to the metabolites responsible for sample difference were also ascribed. The main bioactive compounds identified attributing toward the separation included: isorhamnetin, skimmianine, scopoletin, and melicarpinone. Hence, ML may be used as promising medicinal plant for the development of new functional foods, new generation antidiabetic drugs, as a single entity phytomedicine or in combinational therapy.     

Performance investigation of a small Savonius-Darrius counter-rotating vertical-axis wind turbine

This paper describes the study of a small vertical-axis wind turbine (VAWT) with a combined design of Darrius and Savonius counter-rotating rotors. The main purpose of this study is to improve the extraction capabilities of a single-rotor VAWT by using two distinct rotor designs while adopting the counter-rotating technique. Given that the conversion capabilities and operational speed of the existing wind turbines are still limited, the current technique is used to enhance the efficiency and expand the operating wind speed range of the VAWT. The Darrius and Savonius counter-rotating rotors were exposed to a similar upstream wind speed using a centrifugal blower. It was found that the Savonius-Darrius counter-rotating rotor was able to operate effectively, particularly at the low-speed wind. By looking at the individual performance of the rotors, it was observed that the conversion efficiency of the H-type rotor increases as the wind speed increases. However, in the case of the S-type rotor, it is higher at lower wind speed and tends to decrease as the operating speed increases. Thus, the maximum efficiency of the S-type rotor was achieved at low speed, whereas the H-type rotor has achieved its maximum efficiency at the highest operating wind speed. The average efficiency of the present Savonius-Darrius counter-rotating rotor has been improved to reach almost 42% and 30% more efficiency in terms of torque and power, respectively.     

Parametric study for concrete cover separation failure of retrofitted SNSM strengthened RC beams

ABSTRACT

The side near-surface mounted (SNSM) method is a new flexural strengthening method for reinforced concrete (RC) beams which was proposed to allow near-surface mounted (NSM) strengthening to be applied on beams with small width. As a relatively new strengthening method, further studies are needed to determine the effects of strengthening parameters on the flexural performance of RC beams. In response to that, this paper presents a parametric study on the concrete cover separation failure of SNSM strengthened beams using a simulation method based on the moment-rotation (M/θ) approach.     

Fog removal using laser beam penetration,laser intensity,and geometrical features for 3D measurements in fog-filled room

Three dimension (3D) point cloud data in fog-filled environments were measured using light detection and ranging (LIDAR). Disaster response robots cannot easily navigate through such environments because this data contain false data and distance errors caused by fog. We propose a method for recognizing and removing fog based on 3D point cloud features and a distance correction method for reducing measurement errors. Laser intensity and geometrical features are used to recognize false data. However, these features are not sufficient to measure a 3D point cloud in fog-filled environments with 6 and 2 m visibility, as misjudgments occur. To reduce misjudgment, laser beam penetration features were added. Support vector machine (SVM) and K-nearest neighbor (KNN) are used to classify point cloud data into ‘fog’ and ‘objects.’ We evaluated our method in heavy fog (6 and 2 m visibility). SVM has a better F-measure than KNN; it is higher than 90% in heavy fog (6 and 2 m visibility). The distance error correction method reduces distance errors in 3D point cloud data by a maximum of 4.6%. A 3D point cloud was successfully measured using LIDAR in a fog-filled environment. Our method’s recall (90.1%) and F-measure (79.4%) confirmed its robustness.     

UVC dosage effects on the physico-chemical properties of lime (Citrus aurantifolia) juice

A phenyl lipid alkaloid and seven phenolic compounds were isolated from the aerial part of Spergularia marina, a halophyte that grows on salt marshes and tidal flat. These compounds were identified as 2,4-di-tert-butylphenol, N-hexacosanoylanthranilic acid, tryptophan, 4-hydroxybenzyol glucopyranoside, luteolin 6-C-β-D-glucopyranoside 8-C-β-D-(2-O-feruloyl)glucopyranoside, luteolin 6-C-β-D-(2-O-feruloyl)glucopyranoside 8-C-β-D-glucopyranoside, apigenin 6-C-β-D-glucopyranoside 8-C-β-D-(2-O-feruloyl)glucopyranoside, and apigenin 6-C-β-D-(2-O-feruloyl)glucopyranoside 8-C-β-D-glucopyranoside. The structures were determined by nuclear magnetic resonance and electrospray ionization-mass spectroscopy.     

Effect of Particle Size on Direct Compaction of Urea Fertilizer

The effect of particle size on compaction properties and characteristics of urea tablets manufactured from available urea granules (TG tablets) and ground urea powders (TP tablets) was investigated. The compaction properties, namely, plastic work, elastic work, friction work, and maximum ejection pressure were analyzed from the force-displacement profile of the compaction process. Five applied pressures ranging between 37.67 MPa and 188.35 MPa were used to compact the materials using a universal testing machine. Characteristics of the tablets tested were mechanical strength and the release of ammonium ion through dissolution test. The results demonstrated that TG tablets underwent high plastic work and elastic work but low friction work compared to the TP tablets. TG tablets released lower amount of ammonium ion compared to the TP tablets at almost all applied pressures, except at 75.34 MPa. This study provides a valuable data for evaluating the behavior of urea in the form of granules and powders during the compaction process as well as the suitability in choosing the form of raw material for the production of urea tablets.