Thermal images generated by a line-scanning technique: statistical properties

The analysis of statistical parameters of computer-generated therfial images by a line-scanning technique indicates an approach to efficient image transmission.     

Selective Al-Ti reactivity in laser-processed Al/Ti multilayers

Multilayers consisting of five (Al/Ti) bilayers were deposited on (100) silicon wafers. On top was deposited the Ti layer, aimed at preventing Al from diffusing to the surface upon laser treatment. The total thickness of the thin-film structure was 200?nm. Laser irradiations with Nd:YAG picoseconds laser pulses in the defocused regime were performed in air. Laser beam energy was 4?mJ and laser spot diameter on the sample surface was 3?mm (fluence 0.057?J?cm^?2). The samples were treated with different numbers of laser pulses. Structural characterizations were performed by different analytical methods and nano-hardness was also measured. Laser processing induced layer intermixing, formation of titanium aluminides, oxidation of the surface titanium layer and enhanced surface roughness. Aluminum appears at the sample surface only for the highest density of laser irradiation. Laser processing induces increment of nano-hardness by approximately 20% and decrease of residual Young’s modulus for a few percentages from the starting value of the untreated samples. These results can be interesting toward achieving structures with a selective extent of Al-Ti reactivity in this multilayered system, within the development of biocompatible materials.     

Two-way D algorithm for path planning and replanning

Inspired by the Witkowski’s algorithm, we introduce a novel path planning and replanning algorithm — the two-way D^∗ (TWD^∗) algorithm — based on a two-dimensional occupancy grid map of the environment. Unlike the Witkowski’s algorithm, which finds optimal paths only in binary occupancy grid maps, the TWD^∗ algorithm can find optimal paths in weighted occupancy grid maps. The optimal path found by the TWD^∗ algorithm is the shortest possible path for a given occupancy grid map of the environment. This path is more natural than the path found by the standard D^∗ algorithm as it consists of straight line segments with continuous headings. The TWD^∗ algorithm is tested and compared to the D^∗ and Witkowski’s algorithms by extensive simulations and experimentally on a Pioneer 3DX mobile robot equipped with a laser range finder.     

Definition of the optimal freezing rate-2. Investigation of the physico-chemical properties of beef M. longissimus dorsi frozen at different freezing rates

The influence of freezing rate on weight loss during the freezing, thawing and cooking, on water-binding capacity, on sensory and other physico-chemical properties of beef M. longissimus dorsi was investigated. The changes in myofibrillar proteins in muscle samples frozen at different freezing rates were also investigated.

The greatest weight losses during the freezing, thawing and cooking were registered at slow freezing procedures (freezing rate of 0·22 cm/h and 0·29 cm/h), when the meat was tougher and less soft. The solubility of myofibrillar proteins was least from those muscles frozen at such freezing rates.

The freezing of samples at freezing rates of 3·33 cm/h and 3·95 cm/h had less influence on their physico-chemical characteristics. The solubility of the myofibrillar proteins from such samples was greatest, and the cooked samples were the most tender.

From analysis of the results it was concluded that optimal conditions for meat freezing seem to be those when the average freezing rate is 2–5 cm/h.     

High value polyurethane resins from rubber seed oil

Rubber seed oil having high free fatty acid content and high unsaturation was used to obtain high quality polyurethane resins through epoxidation and ring opening with methanol and free fatty acids. Two polyols prepared with free fatty acids and without were cured with modified methylene diphenyl diisocyanate to obtain strong, high modulus glassy polyurethanes. The effect of structure on thermal and mechanical properties was analyzed. This showed that the polyol with free fatty acid utilized to obtain a branched structure gave superior crosslinking density and mechanical properties. © 2016 Society of Chemical Industry     

The dependence of the photocatalytic activity of TiO2/carbon nanotubes nanocomposites on the modification of the carbon nanotubes

Nanostructural TiO₂/modified multi-wall carbon nanotubes photocatalysts were prepared by hydrolysis of Ti(iso-OC₃H₇)₄ providing chemical bonding of anatase TiO₂ nanoparticles onto oxidized- or amino-functionalized multi-wall carbon nanotubes (MWCNT). The processes of functionalization of the MWCNT and the deposition of TiO₂ influence the photocatalytic activity of the synthesized nanocomposites. The phase composition, crystallite size, and the structural and surface properties of the obtained TiO₂/modified-MWCNT nanocomposite were analyzed from XRD, FEG-SEM, TEM/HRTEM and FTIR data, as well low temperature N₂ adsorption. In the photocatalytic study, the TiO₂/oxidized-MWCNT catalyst showed the highest and the TiO₂/amino functionalized-MWCNT catalysts somewhat lower degradation rates, indicating that the enhancement of photocatalysis was supported by the more effective electron transfer properties of the oxygen- than amino-containing functional groups, which support the efficient charge transportation and separation of the photogenerated electron-hole pairs.