循环利用变型二浴法铬鞣废液的研究

本文对变型二浴法铬鞣废液的循环利用进行了研究。结果表明，变型二浴法铬鞣废液可以进行封闭式循环利用。     

Electrospinning and rheological behavior of poly (vinyl alcohol)/collagen blended solutions

Poly(vinyl alcohol)/collagen (PVA/COL) micro-nanofibers were successfully prepared by electrospinning process. Water, green, and non-toxic was used as the solvent. The electrospun mats consisted of micro-nanoscale fibers with mean diameter ranging from approximately 363 nm to 179 nm. It was observed that the mean diameters of PVA/COL electrospun fibers decreased with increasing collagen content. The effects of PVA/COL blending ratio on the rheological behavior of PVA/COL blended solutions were investigated by rotate rheometer. It was found that PVA/COL blended solutions behaved as Non-Newtonian fluids. With increasing collagen content, the Non-Newtonian index (n) of PVA/COL blended solutions decreased. Meanwhile, a linear relationship was found between the Non-Newtonian index (n) and the mean diameters of the PVA/COL micronanofibers. The chemical structures of PVA/COL electrospun fibers were also characterized by FTIR.     

Compatibility and Properties of Biodegradable Blend Films with Gelatin and Poly（vinyl alcohol）

The blend films with gelatin and poly（vinyl alcohol） （PVA） were prepared by a solution casting method. The compatibility between gelatin and PVA in the blend films was investigated. The transmittance, Fourier-transform infrared spectroscopy （FTIR）, x-ray diffraction （XRD）, thermogravimetry analysis （TG）, and differential scanning calorimetry （DSC） were employed to characterize the resultant blend films. According to optic result, the opacity of the blend film at the ratio of 20/80 （w/w, Gel to PVA） was the lowest, indicating the best compatibility between Gel and PVA at the ratio. The results oflR, XRD, DSC, and TG revealed an intensive interaction and good compatibility between them in the blend film at the ratio. The mechanical properties and solubility showed that PVA content in the blend films obviously affected the elongation at break and solubility. The mechanical properties and water resistance of gelatin film may be improved by the introduetion of PVA.     

铬的污染源及其危害

本文介绍了铬污染的来源并对其危害进行了分析和讨论，从而说明了治理铬污染的必要性和重要性。     

汗液对皮革耐热稳定性的影响

采用热台显微镜、热重分析等方法研究了未鞣制皮粉、铬鞣皮粉和戊二醛鞣制皮粉的热收缩和热降解行为，探索了这些试样在受到汗液浸泡作用时热收缩和热降解行为方面所发生的变化，讨论了发生这些变化的机理。     

固定化酶及其在化工等领域中的应用

简要介绍了固定化酶技术的概念、制备方法(包括传统固定化技术、传统固定化技术的改进方法、新型固定化技术)及其在化学化工、食品行业、临床医药、生物传感器和环境科学等领域中的应用现状与存在的问题，展望了固定化酶技术在皮革行业中的研究与应用前景。对于皮革工业的酶技术具有一定的借鉴意义和参考价值。     

胶原蛋白酶解产物功能特性研究

本文研究了胶原蛋白经酶水解后所得胶原水解物的功能特性。酶解后胶原蛋白分子量减小，胶原酶解产物的吸水性、保水性、溶解性较酶解前都得到提高，但是吸油性、起泡性和泡沫稳定性都明显下降。对胶原蛋白进行有限水解，使其功能特性发生改变，有利于其在化妆品以及食品添加剂等方面的应用。     

猪鞋面革应力松弛时间谱的研究(Ⅰ)——猪鞋面革应力松弛行为的模拟和应力松弛谱的求解

研究了猪鞋面革的应力松弛模量,采用1～8个Maxwell单元组成的广义Maxwell模型,模拟了其应力松弛行为。结果表明:采用5个或5个以上Maxwell单元组成的广义Maxwell模型,可以较好地模拟猪鞋面革的应力松弛行为。利用模型模拟获得的应力松弛表达式和Schwarzl松弛时间谱二阶近似求解方法求解了松弛时间谱,得到了猪鞋面革的应力松弛谱图。     

有机化合物交联改性明胶的研究进展(续)

综述了有机化合物对明胶的化学交联改性方法,包括醛类、烷烯类、糖类、植物单宁等对明胶的交联改性。     

正丁胺为扩链剂合成水性聚氨酯皮革涂饰剂

采用异佛尔酮二异氰酸酯(IPDI)、二羟甲基丙酸(DMPA)、聚四氢呋喃(PTMG)为原料制备聚氨酯预聚体,分别以乙二醇(EG)、乙二胺(EN)和正丁胺(n-butylamine)为扩链剂制备了水性聚氨酯皮革涂饰剂,研究了该涂饰剂所成膜的力学性能、断裂伸长率和吸水性。结果表明,以正丁胺为扩链剂制备的水性聚氨酯膜的断裂伸长率最好,高达1454%;其玻璃化转变温度可达-82℃,耐水性也比用其它两种扩链剂合成的产品好。