Curing of mixtures of epoxy resins and 4‐methyl‐1,3‐dioxolan‐2‐one with several initiators

Diglycidyl ether of bisphenol A or 3,4‐epoxycyclohexylmethyl 3,4‐epoxycyclohexane carboxylate were mixed with different proportions of 4‐methyl‐1,3‐dioxolan‐2‐one and cured using lanthanide triflates as initiators. In order to compare the materials obtained, conventional initiators such as boron trifluoride complexes and N,N‐dimethylaminopyridine were also tested. The curing process was followed by differential scanning calorimetry (DSC) and Fourier transform IR in attenuated total reflectance mode. This technique proved that the carbonate accelerates the curing process because it helps to form the active initiating species, although it was not chemically incorporated into the network and remained entrapped in the material. The DSC kinetic study was also reported. © 2006 Wiley Periodicals Inc. J Appl Polym Sci 102: 2086–2093, 2006     

New thermosets obtained by cationic copolymerization of DGEBA with γ‐caprolactone with improvement in the shrinkage. II. Time–temperature–transformation (TTT) cure diagram

Mixtures of diglycidylether of bisphenol A (DGEBA) with different proportions of γ‐caprolactone (γ‐CL) were cured with ytterbium triflate as initiator. The curing was studied with differential scanning calorimetry (DSC) and thermo mechanical analysis (TMA). The results are presented in the form of a time–temperature–transformation diagram. The kinetic analysis was performed by means of the isoconversional integral procedure and the kinetic model was also determined using the Coats–Redfern method. Gelation was determined by means of combined experiences of DSC and TMA. The relationship between the glass transition temperature (T_g) and the degree of conversion α was determined by DSC. Using the isoconversional lines and the T_g‐α relationship, the vitrificacion curve was obtained. The methodology developed makes it possible to obtain the TTT diagram using only no‐isothermal experiments with equivalent results to those using classical isothermal procedures. The addition of γ‐CL accelerates the curing and reduces the shrinkage after gelation and consequently the internal stresses in the material. © 2007 Wiley Periodicals, Inc. J Appl Polym Sci, 2007     

Atmospheric correction of optical imagery from MODIS and Reanalysis atmospheric products

In this paper we analyze the differences obtained in the atmospheric correction of optical imagery covering bands located in the Visible and Near Infra-Red (VNIR), Short-Wave Infra-Red (SWIR) and Themal-Infrared (TIR) spectral regions when atmospheric profiles extracted from different sources are used. In particular, three sensors were used, Compact High Resolution Imaging Spectrometer (CHRIS), Advanced Spaceborne Thermal Emission and Reflection radiometer (ASTER) and Landsat5 Thematic Mapper (TM), whereas four atmospheric profiles sources were considered: i) local soundings launched near the sensor overpass time, ii) Moderate Resolution Radiometer (MODIS) atmospheric profiles product (MOD07), iii) Atmospheric Correction Parameter Calculator (ACPC) generated by the National Center for Environmental Prediction (NCEP) and iv) Modified Atmospheric Profiles from Reanalysis Information (MAPRI), which includes data from NCEP and National Center of Atmospheric Research (NCAR) Reanalysis project but interpolated to 34 atmospheric levels and resampled to 0.5° × 0.5°. MODIS aerosol product (MOD04) was also used to extract Aerosol Optical Thickness (AOT) values at 550 nm. Analysis was performed for three test dates (12th July 2003, 18th July 2004 and 13th July 2005) over an agricultural area in Spain. Results showed that air temperature vertical profiles were similar for the four sources, whereas dew point temperature profiles showed significant differences at some particular levels. Atmospheric profiles were used as input to MODTRAN4 radiative transfer code in order to compute atmospheric parameters involved in atmospheric correction, with the aim of retrieving surface reflectances in the case of VNIR and SWIR regions, and Land Surface Temperature (LST) in the case of the TIR region. For the VNIR and SWIR region, significant differences depending on the atmospheric profile used were not found, particularly in the Visible region in which the AOT content is the main parameter involved in the atmospheric correction. In the case of TIR, differences depending on the atmospheric profile used were appreciable, since in this case the main parameter involved in the atmospheric correction is the water vapor content, which depends on the vertical profile. In terms of LST retrieval from ASTER data (2004 test case), all profiles provided satisfactory results compared to the ones obtained when using a local sounding, with errors of 0.3 K for ACPC and MAPRI cases and 0.7 K for MOD07. When retrieving LST from TM data (2005 test case), errors for MOD07 and MAPRI were 0.6 and 0.9 K respectively, whereas ACPC provided an error of 2 K. The results presented in this paper show that the different atmospheric profile sources are useful for accurate atmospheric correction when local soundings are not available. In particular, MOD07 product provides atmospheric information at the highest spatial resolution, 5 km, although its use is limited from 2000 to present, whereas MAPRI provides historical information from 1970 to present, but at lower spatial resolution.     

Mono‐Estolide Synthesis from trans‐8‐Hydroxy‐Fatty Acids by Lipases in Solvent‐Free Media and Their Physical Properties

Pseudomonas aeruginosa 42A2 is known to produce two hydroxy‐fatty acids, 10(S)‐hydroxy‐8(E)‐octadecenoic and 7,10(S,S)‐dihydroxy‐8(E)‐octadecenoic acids, when cultivated in a mineral medium using oleic acid as a single carbon source. These compounds were purified, 91 and 96 % respectively, to produce two new families of estolides: trans‐8‐estolides and saturated estolides from the monohydroxylated monomer. trans‐8‐estolides were produced by three different lipases (Novozym 435, Lipozyme RM IM and Lipozyme TL IM) with reaction yields between 68.4 ± 2.1 and 94.7 ± 2.4 % in a solvent‐free medium at 80 °C in 168 h under vacuum. Novozym 435 was found to be the most efficient biocatalyst for both hydroxy‐fatty acids with reaction yields of 71.7 ± 2.3 and 94.7 ± 2.4 %, respectively. Moreover, saturated estolides were also produced from a saturated 10(S)‐hydroxy‐8(E)‐octadecenoic. These estolides were chemically and enzymatically synthesized with Novozym 435, under the previous described reaction conditions with yields of 60.7 ± 2.1 and 71.2 ± 2.3 % respectively. Finally, viscosity, glass transition temperature, decomposition temperatures and enthalpies were determined to characterize both types of estolides. Thermal applications for both types of polyesters were improved since glass transition temperatures were lowered and decomposition temperatures were increased, with respect to their corresponding substrates.     

Improvement of epoxy thermosets using a thiol‐ene based polyester hyperbranched polymer as modifier

The anionic curing initiated by 1‐methyl imidazole of diglycidyl ether of bisphenol A with a hyperbranched polymer (HBP) containing long aliphatic chains in the structure were studied. The hydroxyl groups present as chain ends in the HBP structure played an important role in the curing kinetics, as demonstrated by differential scanning calorimetry, Fourier transform infrared spectroscopy and rheological studies. Properties such as shrinkage on curing and thermomechanical characteristics were also investigated. The structure of the HBP, which contains long aliphatic chains and reactive hydroxyl groups as chain ends, flexibilizes the network significantly, improving the impact resistance without notably affecting either the glass transition temperature or the microhardness of the modified thermosets. Copyright © 2012 Society of Chemical Industry     

Evaluation of the surface urban heat island effect in the city of Madrid by thermal remote sensing

The surface urban heat island (SUHI) effect is defined as the increased surface temperatures in urban areas in contrast to cooler surrounding rural areas. In this article, the evaluation of the SUHI effect in the city of Madrid (Spain) from thermal infrared (TIR) remote-sensing data is presented. The data were obtained from the framework of the Dual-use European Security IR Experiment (DESIREX) campaign that was carried out during June and July 2008 in Madrid. The campaign combined the collection of airborne hyperspectral and in situ measurements. Thirty spectral and spatial high-resolution images were acquired with the Airborne Hyperspectral Scanner (AHS) sensor in a 11, 21, and 4 h UTC scheme. The imagery was used to retrieve the SUHI effect by applying the temperature and emissivity separation (TES) algorithm. The results show a nocturnal SUHI effect with a highest value of 5 K. This maximum value agrees within 1 K with the highest value of the urban heat island (UHI) observed using air temperature data (AT). During the daytime, this situation is reversed and the city becomes a negative heat island.     

A 4-Mb low-temperature DRAM

The authors present the characterization of the first dynamic RAM (DRAM) fabricated in a technology specifically optimized for cryogenic operation. With the power supply adjusted to assure hot-electron reliability, the 25-ns 4-Mb low-temperature (LT) chips operated 3 times faster than conventional chips. The LT-optimized chips functioned properly with cycle times as fast as 45 ns, and with a toggle-mode data rate of 667 Mb/s. Wide operating margins and a very large process window for data retention were demonstrated. At a temperature of 85 K the storage retention time of the trench-capacitor memory cells exceeded 8 h. This study shows that the performance leverage offered by low temperature applies equally well to DRAM and to logic. There is no limitation inherent to memory     

Synthesis of asymmetric diglycidyl ester compounds. Reaction with aromatic diamines

New diglycidyl esters coming from the corresponding diacids and epichlorohydrin were synthetized using a quaternary ammonium salt as a catalyst. The new asymmetric compounds were characterized by spectroscopic methods and employed as starting monomers in a crosslinking process. The course of the reactions was followed by IR spectroscopy. Some intermediate species were identified in the onset of the reactions by recording ¹³C-NMR spectra until the products became insoluble in the usual deuterated solvents. The thermal behaviour of these cured epoxy resins was also studied.