Paper‐Derived Ferroelectric Ceramics: A Feasibility Study

Preceramic paper may serve as a preform to manufacture single sheet as well as multilayer porous ferroelectric ceramic products. In this article, the authors discuss the formation, microstructure, and properties of preceramic papers highly loaded with BaTiO₃ filler ranging from 70 to 80 vol% and their conversion into ceramic materials. In order to increase the density of the single sheets, post calendering is applied. These sheets are used for the fabrication of multilayer ceramics using warm lamination technique. After binder burnout and sintering up to 1300 °C for 2 h in air, porous paper‐derived multilayer BaTiO₃ is obtained. The effect of ceramic filler content and calendering on the residual porosity in sintered samples is studied. Furthermore, the influence of porosity on the microstructure, mechanical, dielectric, and piezoelectric properties of the sintered BaTiO₃ ceramics is investigated.

     

New aspects of transversal1H-NMR relaxation in natural rubber vulcanizates

Summary Structure and dynamics of unfilled and carbon black filled natural rubber vulcanizates were investigated by means of transversal¹H-NMR-relaxation. A simple theoretical model including different motions in polymer network was extended by the discussion of an anisotropy parameter of segmental motion not only for the intercrosslink chains but also for the dangling ends. It makes characterization of the filling state of the network possible to approximate. The effect of increasing correlation times _f of the fast anisotropic local motion with reduction of the molecular mass of intercrosslink chains which was observed, but not cleared up in previous investigation is evidently smaller by using this modified model in accordance with the expectation of a local motion. The determined values of M_c are in good agreement with the results of fits by using the unmodified relaxation function.¹³C-NMR-spectra and stress-strain-experiments are leading in most cases to similar results, especially for M_c.     

Synthesis of structured triglycerides from peanut oil with immobilized lipase

Structured triglycerides (ST) that contain medium- and long-chain fatty acids were synthesized by lipase-catalyzed interesterification between tricaprylin and peanut oil. To select appropriate enzymes, we investigated nine commercial lipase preparations for their ability to hydrolyze pure triglycerides as well as natural oils. Three microbial lipases from Rhizomucor miehei (RML), Candida sp. (CSL), and Chromobacterium viscosum (CVL) gave good results, and immobilized preparations were used in the interesterification. RML gave the highest yields of ST (73%, 40°C), although its hydrolytic activity toward triolein was low. As the temperature was raised to 50°C, the yield of ST increased to 79%. After 120 h reaction time, remaining activities were high for CSL (71%), moderate for CVL (48%), and low for RML (20%). Parts of this paper were presented as a poster at the Biochemical Engineering Conference IX, May 1995, Davos, Switzerland.     

Strahlungspyrometrische Messung der wahren Temperatur und Bestimmung des Emissionsgrades in Stahlschmelzen

Kurze Übersicht über die zur wahren Temperaturmessung von Schmelzen benutzten Thermoelemente, visuellen und unmittelbar anzeigenden Strahldichte- und Farbpyrometer. Meßfehler von Verhältnis-(Farb-) Pyrometern abhängig von benutzten Wellenlängen und vom Emissionsgrad der Schmelzen. Zusammenhang zwischen Verhältnistemperatur, wahrer Temperatur und Emissionsgrad bei Messung mit Verhältnispyrometer und daraus abgeleitete Berichtigungsschaltung. Vergleich möglicher Meßfehler bei Messung mit Strahldichte- und ε-berichtigtem Verhältnispyrometer. Verschiedene Verfahren zur Bestimmung des Emissionsgrades für eine laufende Strahlungsanalyse der Schmelzen.     

Preferences for legume attributes in maize-legume cropping systems in Malawi

Adoption rates of leguminous crops remain low in sub-Saharan Africa despite their potential role in improving nutrition, soil health, and food security. In this study we explored Malawian farmers’ perceptions of various legume attributes and assessed how these perceptions affected allocation of land to legume crops using a logit link model. We found high regional variation in both consumption- and production-related preferences, but relatively consistent preferences across samples. While scientific understanding and farmer perceptions were aligned on some topics and for some legumes, there were discrepancies elsewhere, particularly in terms of soil fertility and nutrition. Understanding why these discrepancies exist and where there were potential biases are critical in explaining the extent of adoption. In many cases perceptions of legume attributes may be influenced by the cultural role of the crop in the household, particularly in terms of food security or market-orientation. The findings also suggest that researchers need to look beyond both the agronomic properties and farmers’ preferences to fully understand the extent of adoption. Socioeconomic factors, biases, and marketing concerns may also influence integration of legumes into maize-based cropping systems.     

Procreation after death or mental incompetence: medical advance or technology gone awry?

PURPOSE: To study the feasibility of using an iodinated particulate contrast agent, iodipamide ethyl ester (IDE), for angiography. MATERIALS AND METHODS: IDE at doses of 40-100 mg of iodine per kilogram was diluted to a total volume of 5-20 mL and used for digital subtraction angiography in nine dogs under general anesthesia. Equivalent images were obtained by using water-soluble contrast medium (WSCM) for comparison (iohexol) in seven animals. All images were reviewed by blinded reviewers and graded subjectively on a five-point scale. RESULTS: Angiographic studies of multiple vascular territories performed with IDE yielded images of slightly lower overall quality compared with images obtained with WSCM (P = .14, Mann-Whitney U test). Arterial phase images were subjectively superior with WSCM when compared with IDE (P < .0001, chi 2.) Depiction of the corresponding veins during the venous phase on the IDE angiograms was superior to that on WSCM angiograms in 12 of 21 cases, although this did not reach statistical significance (P > .05 chi 2). Images of the renal vein and portal vein achieved with IDE were graded as superior to those achieved with WSCM in eight of 10 reviews. CONCLUSION: Angiography is feasible with IDE. Compared with WSCM, IDE produced images of lesser quality during the arterial phase, but of equal or superior quality in the venous phase depending on the vessel studied. Because it is excreted slowly in bile and is isotonic, it may prove useful in patients with renal insufficiency, diabetes, multiple myeloma, or severe coronary disease.     

Novel qualitative structure-activity relationships for the antinociceptive actions of H2 antagonists, H3 antagonists and derivatives

Recent studies have shown that cimetidine, burimamide and improgan (also known as SKF92374, a cimetidine congener lacking H2 antagonist activity) induce antinociception after intracerebroventricular administration in rodents. Because these substances closely resemble the structure of histamine (a known mediator of some endogenous analgesic responses), yet no role for known histamine receptors has been found in the analgesic actions of these agents, the structure-activity relationships for the antinociceptive effects of 21 compounds chemically related to H2 and H3 antagonists were investigated in this study. Antinociceptive activity was assessed on the hot-plate and tail-flick tests after intracerebroventricular administration in rats. Eleven compounds induced time-dependent (10-min peak) and dose-dependent antinociceptive activity with no observable behavioral impairment. ED50 values, estimated by nonlinear regression, were highly correlated across nociceptive assays (r2 = 0.98, n = 11). Antinociceptive potencies varied more than 6-fold (80-464 nmol), but were not correlated with activity on H1, H2 or H3 receptors. Although highly potent H3 antagonists such as thioperamide lacked antinociceptive activity, homologs of burimamide and thioperamide containing N-aromatic substituents retained H3 antagonist activity and also showed potent, effective analgesia. A literature review of the pharmacology of these agents did not find a basis for their antinociceptive effects. Taken with previous findings, the present results suggest: 1) these compounds act on the brain to activate powerful analgesic responses that are independent of known histamine receptors, 2) the structure-activity profile of these agents is novel and 3) brain-penetrating derivatives of these compounds could be clinically useful analgesics.     

Butadiene rubbers: topological constraints and microscopic deformation by mechanical and small angle neutron scattering investigation

Summary Results of stress-strain measurements are reported for butadiene rubbers of varying crosslink density. The fluctuation of the effective tube diameter of the polymer networks was investigated under uniaxial elongation by mechanical measurements as well as by small angle neutron scattering (SANS) which probe the local orientation on a segmental scale. The effect of topological constraints on the microscopic deformation of the butadiene network chains is well described within a tube approach. For the first time, experiments at large deformations and for polydisperse sample are presented. Excellent agreement between the statistical mechanical model and the experimental results is obtained. Received: 20 November 2001 /Revised version: 5 March 2002/ Accepted: 5 March 2002     

Segmental mobility in poly(isoprene) rubber studied by deuterium-carbon NMR correlation spectroscopy

Summary A HMQC based deuterium-carbon correlation method is used for the first time to study the segmental mobility in a fully deuterated poly(isoprene) (PI) rubber network. The isotropic J _CD couplings can be utilized for polarization transfer between ²H and ¹³C spins in a mobile solid polymer. This makes it possible to correlate the ²H resonances with the ¹³C chemical shifts of the attached carbon in a two-dimensional (2D) experiment, and thus allow the extraction of the individual ²H signals. The experimental data obtained from the 2D correlation spectrum indicates differences in the segmental mobility of the C-D vectors in perdeuterated PI. The conclusions are fully consistent with ²H and ¹³C T ₁ relaxation data. The results shown in this paper demonstrate the potential of ²H-¹³C NMR correlation spectroscopy in solid systems which produce overlapped 1D ²H spectra. Received: 11 December 2000/Revised version: 1 March 2001/Accepted: 1 March 2001