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1.
The Journal of Supercomputing - In chip multiprocessors, the thermal hot spot prediction is vital to take proactive thermal management decisions for mitigating its impact on the performance of the... 相似文献
2.
This study examined the individual and simultaneous adsorption of SO{in{itx}} (SO{in{it2}}) and NO{in{itx}} (NO-NO{in{it2}})
on activated carbon prepared from waste palm shell. The adsorption process was examined in a fixed bed reactor at low temperatures
(100\2-300\dgC). For individual adsorption without any catalytic activation, SO{in{itx}} showed good adsorption whereas NO{in{itx}}
was very much poor. In the simultaneous adsorption of SO{in{itx}} and NO{in{itx}}, SO{in{itx}} showed greater adsorption affinity
than NO{itx}. For palm shell activated carbon (PSAC) impregnated with metal catalyst (Ni and Ce) the concentration adsorbed
profile showed that the amount of SO{in{itx}} adsorbed decreased regularly, while the amount of the adsorbed NO{in{itx}} increased
irregularly. The properties of the pure and impregnated PSAC were analyzed by BET, SEM and EDX. These investigations indicated
that PSAC impregnated with metal catalyst is the determining factor in the adsorption of SO{in{itx}} and NO{in{itx}} simultaneously.
Supported financially by Yayasan FELDA, Malaysia (Grant No. 6050075) 相似文献
3.
M. S. R. Subrahmanyam H. Sumathi Vedanayagam D. Venkateshwar Rao A. Rajaiah P. Venkatacharyulu 《Journal of the American Oil Chemists' Society》1995,72(12):1537-1540
From the volume expansivity α, a number of thermoacoustic parameters, including the Sharma constant,S
0, are estimated for four fatty acids as a function of temperature. The Sharma constant, which was established to be a constant
with the characteristic value 1.11 ± 0.01 over a number of systems investigated by earlier investigators, is also found to
be a constant with the same value for all fatty acids under investigation. Further, the Sharma constant,S
0, is independent of temperature and dependent only on α. All other parameters estimated are discussed and compared with the
values reported in the literature by earlier workers for different systems. 相似文献
4.
CO2 methanation over Ni and Rh based catalysts: Process optimization at moderate temperature
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Muhammad Younas Sumathi Sethupathi Leong Loong Kong Abdul Rahman Mohamed 《国际能源研究杂志》2018,42(10):3289-3302
H2 was produced from aluminum/water reaction and reacted with CO2 over Ni and Rh based catalysts to optimize the process conditions for CO2 methanation at moderate temperature. Monometallic catalysts were prepared by incorporating Ni and Rh using nickel nitrate hexahydrate (Ni(NO3)2·6H2O) and rhodium(III) chloride trihydrate (RhCl3·3H2O)as a precursor chemical. The preliminary study of the catalysts revealed higher activity and CH4 selectivity for Rh based catalyst compared to that of Ni based catalyst. Further, Rh based catalyst was investigated using response surface methodology (RSM) involving central composite design. The quadratic model was employed to correlate the effects of variable parameters including methanation temperature, %humidity, and catalyst weight with the %CO2 conversion, %CH4 selectivity, and CH4 production capacity. Analysis of variance revealed that methanation temperature and humidity play an important role in CO2 methanation. Higher response values of CO2 conversion (54.4%), CH4 selectivity (73.5%) and CH4 production capacity (8.4 μmol g?1 min?1) were noted at optimum conditions of 206.7°C of methanation temperature, 12.5% humidity and 100 mg of the catalyst. The results demonstrated the ability of Rh catalyst supported on palm shell activated carbon (PSAC) for CO2 methanation at low temperature and atmospheric pressure. 相似文献
5.
R Jayawardena S Swaminathan NM Byrne MJ Soares P Katulanda AP Hills 《Nutrition journal》2012,11(1):63
ABSTRACT: BACKGROUND: Food Frequency Questionnaires (FFQs) are commonly used in epidemiologic studies to assess long-term nutritional exposure. Because of wide variations in dietary habits in different countries, a FFQ must be developed to suit the specific population. Sri Lanka is undergoing nutritional transition and diet-related chronic diseases are emerging as an important health problem. Currently, no FFQ has been developed for Sri Lankan adults. In this study, we developed a FFQ to assess the regular dietary intake of Sri Lankan adults. METHODS: A nationally representative sample of 600 adults was selected by a multi-stage random cluster sampling technique and dietary intake was assessed by random 24-h dietary recall. Nutrient analysis of the FFQ required the selection of foods, development of recipes and application of these to cooked foods to develop a nutrient database. We constructed a comprehensive food list with the units of measurement. A stepwise regression method was used to identify foods contributing to a cumulative 90% of variance to total energy and macronutrients. In addition, a series of photographs were included. RESULTS: We obtained dietary data from 482 participants and 312 different food items were recorded. Nutritionists grouped similar food items which resulted in a total of 178 items. After performing step-wise multiple regression, 93 foods explained 90% of the variance for total energy intake, carbohydrates, protein, total fat and dietary fibre. Finally, 90 food items and 12 photographs were selected. CONCLUSION: We developed a FFQ and the related nutrient composition database for Sri Lankan adults. Culturally specific dietary tools are central to capturing the role of diet in risk for chronic disease in Sri Lanka. The next step will involve the verification of FFQ reproducibility and validity. 相似文献
6.
Two symmetrically nonequivalent silicon carbide (SiC) substrate orientations, (0001) Si-terminated and \((000\overline{1} )\) C-terminated, were used in the physical vapour transport growth of bulk aluminium nitride (AlN) single crystals. The crystals grown on Si-faces always exhibit an Al-polar growth surface. AlN growth on \((000\overline{1} )\) C-terminated surfaces of the SiC substrates was performed to obtain N-polar growth surfaces. An abrupt interface was observed between the AlN crystal and the C-face substrate which is in contrast to the growth on Si-faces where hexagonally shaped SiC hillocks are formed. The growth on C-faces is usually dominated by multi-site nucleation. Applying similar supersaturation conditions that led to step-flow growth on Si-faces to the C-faces resulted in a spiral growth mode, even on highly off-oriented substrates. The obtained broad X-ray diffraction rocking curves of such samples (full-width at half-maximum ≈380 arcsec) indicate the presence of more misfit dislocations and significant misfit stress. In addition, polarity inversion is observed in C-face grown crystals. Though the structural properties of the crystals grown on C-face are inferior to that of the crystals grown on Si-face, the incorporation of unintentional Si impurity was found to be lower (<2 wt%). 相似文献
7.
The aim of our investigation was to compare the rates of dechlorination of DDT using Mg0/Pd4+ system in two different reaction phases, namely, water-acetone and 0.05% biosurfactant in water. Since palladium is expensive and its toxicity effects are not well known we also examined the reuse efficiency of Pd0 immobilized on alumina for dechlorinating DDT. Studies on the dechlorination of DDT in water-acetone (1:1, v/v) and 0.05% biosurfactant phases revealed that the reaction followed second order kinetics and rate of reaction is dependent upon both initial concentrations of the target compound and Mg0/Pd4+. The presence of acid enhanced the rate of reaction by providing protons and preventing passivation of metal that occurs due to deposition of magnesium hydroxide. GC-MS analyses revealed the formation of completely dechlorinated hydrocarbon skeleton of DDT namely, diphenylethane (DPE), as the end product in both reaction phases (water-acetone and 0.05% biosurfactant in water) thereby implying the removal of all five chlorine atoms (three alkyl and two aryl) of DDT. The optimum ratio of water and acetone to facilitate successful dechlorination reaction was found to be 9:1. Results suggested that salt form (K2PdCl6) of palladium had higher potential to dechlorinate DDT as compared to pellet (Pd0-alumina) form (efficiencies of 95 and 36%, respectively, for 100 ppm initial concentration of DDT). We noted that Pd0-alumina pellets could be reused at least four times for successful dechlorination of DDT provided Mg0 granules are present in sufficient quantity. Technical grade DDT (50 ppm) containing significant amounts of DDD was dechlorinated almost completely by the Mg0/Pd4+ (10mg/0.2mg/ml) within 1h in water-biosurfactant phase. Our studies reveal that Mg/Pd system is a promising option due to its high reactivity and its ability to achieve complete dechlorination of DDT. This bimetallic system may be useful for designing indigenous permeable barriers or reactors for the treatment of DDT contaminated water. 相似文献
8.
T. Velmurugan Sibaram Khara S. Nandakumar D. Sumathi 《Radioelectronics and Communications Systems》2017,60(10):431-448
In the global scenario, a variety of wireless access networks are available. Different types of applications such as real time, nonreal time, and high bandwidth availability are used for heterogeneous wireless networks. Therefore, it is necessary for a service provider to make an appropriate connection support. For better performance, connections are to be exchanged among the different networks using seamless vertical handoff (VHO). The proposed algorithm shows the effect of optimization technique, which involves handoff decision process using vertical handoff triggering and selection of the network. The handoff triggering is initiated by using the received signal strength (RSS). In traditional method, handoff triggering is initiated by using RSS only. This method, modified weed optimization (M-WO) algorithm, reduces the unnecessary handoff by considering both RSS and velocity of the mobile node in handoff triggering. The parameters such as battery lifetime, handoff call dropping rate, load, dynamic weights adaptation and so on are to be considered individually or combined to make an effective network selection process. This paper highlights a novel effect ofM-WOalgorithm for decision making during the VHO. Our effort is to essentially optimize the system load, so that it reduces the handoff call dropping rate and the battery power consumption of the mobile node (MN). Weight of each QoS metrics is adjusted along with the networks changing conditions to trace the M-WO. Therefore, the novel VHO decision-making algorithm is superior to the existing SSF and OPTG methods. The simulation results show that the performance ofM-WOalgorithm is far better than SSF andOPTGmethods in terms of load, handoff call dropping rate and battery lifetime of MN. 相似文献
9.
W.P.Cathie Lee Lling-Lling Tan S. Sumathi Siang-Piao Chai 《International Journal of Hydrogen Energy》2018,43(2):748-756
A facile synthesis approach to fabricate Cu-doped MoS2/Bi2S3 (Cu-MoS2/Bi2S3) photocatalysts is reported. The photocatalyst samples with varying amounts of Cu are applied in the photocatalytic splitting of water to produce H2 under the irradiation of simulated solar light. The Cu-MoS2/Bi2S3 photocatalysts with an optimum Cu loading of 20 mol% exhibited high photocatalytic performance, achieving a total H2 yield of 32.4 μmol/h after 6 h of reaction. The photoactivity of the Cu-doped sample was shown to have risen more than 40% than that of pure MoS2/Bi2S3. The improved performance is attributed to the impurity states generated within Cu-doped MoS2, which serve as trapping sites for photogenerated electrons. The effective charge transfer mechanism achieved was evidenced by photoelectrochemical measurements. Based on the experimental results obtained, a plausible mechanism for the photocatalytic process associated with Cu-MoS2/Bi2S3 was proposed. 相似文献
10.
The effects of pH, organic co-solvent, salts such as sodium chloride, sodium sulfate, and co-pollutants, resin and fatty acids (RFAs) on the dechlorination of pentachlorophenol (PCP) by magnesium/silver (Mg/Ag) and magnesium/palladium (Mg/Pd) systems were examined in the present investigations. Such studies provide relevant information about the applicability of bimetallic systems for remediation of raw wastewaters (such as pulp bleaching effluents) or groundwater. Removal efficiencies of 10 mg L(-1) PCP by Mg/Pd and Mg/Ag systems at the end of 1 h reaction were 93% and 78%, respectively, in the presence of acetone (1% v/v). On the other hand, the removal efficiencies were 86% and 70% for reactions conducted in alcoholic solvents (1% v/v) using Mg/Pd and Mg/Ag systems, respectively. The efficiencies of PCP removal by the two bimetallic systems could be correlated to the dipole moments of co-solvents used. The second order reaction rate constant for PCP removal by Mg/Ag system was highest (0.03 L mg(-1) min(-1)) in the absence of any pH-control mechanism. Optimum pH for the dechlorination of PCP by Mg/Pd system was found to be approximately 5.5 and >92% of the compound was removed within 15 min of reaction. Presence of chlorinated and non-chlorinated resin fatty acids (RFAs) resulted in substantial reduction in the rate and extent of PCP removal by Mg/Ag system whereas dechlorination by Mg/Pd remained unaffected. Presence of sodium sulfate or sodium chloride in the reaction phase reduced the rate and extent of PCP removal by Mg/Ag system. PCP dechlorination by Mg/Pd system was adversely impacted by the addition of sodium chloride and unaffected by the presence of sodium sulfate. 相似文献