排序方式: 共有34条查询结果,搜索用时 31 毫秒
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Т.А. Sergeyeva L.A. Gorbach О.А. Slinchenko L.A. Goncharova O.V. Piletska О.О. Brovko L.M. Sergeeva G.V. Elska 《Materials science & engineering. C, Materials for biological applications》2010,30(3):431-436
Colorimetric test-system for the express-control of phenols content in water was developed. The system consisted of free-standing molecularly imprinted polymer (MIP) membranes which contained synthetic binding sites capable of phenol binding. The MIP membranes were obtained by co-polymerisation of a functional monomer (e.g. itaconic acid, 2-acrylamido-2-methyl-1-propanesulfonic acid, acrylamide or methacrylic acid) with triethyleneglycoldimethacrylate and oligourethaneacrylate. Rational choice of the functional monomers was based on the results of computational modelling. The phenol-selective MIP membranes were used as a basis for the colorimetric test-system for measuring phenol in aqueous samples. Phenol molecules were selectively adsorbed by the MIP membranes and quantified using color reaction with 4-aminoantipyrine. The intensity of the membranes' staining was proportional to the phenol concentration in the analysed sample. The optimised colorimetric test-system based on MIP membranes demonstrated a low detection limit (50 nM), a wide working range — 50 nM–0.5 mM and an excellent storage stability at room temperature (12 months). As compared to the traditional methods of phenols detection the developed test-system is superior because of simplicity of operation, small size and low cost. 相似文献
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I.A. Anokhina I.E. Animitsa V.I. Voronin V.B. Vykhodets Т.Е. Kurennykh N.G. Molchanova A.I. Vylkov A.E. Dedyukhin Y.P. Zaikov 《Ceramics International》2021,47(2):1949-1961
The lithium-doped phases Gd1.7Li0.3Zr2O6.7 and Gd2Zr1.7Li0.3O6.55 with a pyrochlore structure were prepared by the modified Pechini method using citric acid and glycerol. Monitoring of the lithium content by using a nuclear microanalysis showed that a significant loss of lithium occurred after heat treatment above 1200 °C. Dense ceramics with a stoichiometric lithium content can be prepared by a low temperature microwave sintering (1100 °C). The introduction of lithium in the Gd-sublattice was accompanied by a decrease in the unit cell parameter (a = 10.5208 (1) Å vs 10.5346 (2) Å for Gd2Zr2O7) and during doping at the Zr-sites with lithium, the cell parameter increased (10.5720 (1) Å). The doping in both cases led to an increase in the free cell volume. The impedance spectroscopy results showed that the bulk conductivity can be enhanced by the Li+-doping at the Gd3+-site by almost an order of magnitude. The sample Gd2Zr1.7Li0.3O6.55 had a conductivity lower than that of Gd1.7Li0.3Zr2O6.7 due to the possible trapping of oxygen vacancies by a high-charged acceptor defect LiZr???. The conductivity?pO2 measurements showed that the Li-containing phase was a pure oxide-ion conductor at T < 800 °C. 相似文献
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Korniy S. А. Zin I. М. Тymus M. B. Khlopyk O. P. Danyliak M.-O. М. 《Materials Science》2021,56(5):602-607
Materials Science - It is shown that xanthan gum inhibits corrosion processes in carbon steel placed in chloride-containing media by the mechanism of adsorption. Potassium-sodium tartrate improves... 相似文献
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Fedirko V. М. Voevodin V. М. Velykodnyi О. М. Тykhonovskyi М. А. Kukhar І. S. Mel’nyk Kh. R. 《Materials Science》2020,55(4):529-535
Materials Science - We study the corrosion resistance of high-entropy alloys of the Cr–Fe–Mn–Ni system in lead melts at 480°С in testing for up to 1000 h. It is shown... 相似文献
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