One step method of structure engineering porous graphitic carbon nitride for efficient visible-light photocatalytic reduction of Cr(Ⅵ)

Porous g-C3N4 nanosheets (PCN) were prepared by the nickel-assisted one-step thermal polymerization method.Hydrogen (H2) which was produced by the reaction between nickel (Ni) foam and ammonia (NH3) defined the structure and properties of PCN.During the formation of PCN,the participation of H2 not only enhanced the spacing between layers but also boosted the specific surface area that more active sites were exposed.Additionally,H2 promoted pores formation in the nanosheets,which was beneficial to the transfer of photons through lamellar structure and improved the absorption efficiency of visible light.Remarkably,the obtained PCN possessed better Cr(Ⅵ) photocatalytic reduction efficiency than pure g-C3N4.The reaction rate constant (k) of PCN (0.013 min-1) was approximately twice that of bare g-C3N4 (0.007 min-1).Furthermore,the effects of original pH and concentration of Cr(Ⅵ)-containing solution on removal efficiency of Cr(Ⅵ) were explored.A possible photocatalytic mechanism was proposed based on the experiments of radical scavengers and photoelectrochemical characterizations.     

北非1942

<正>前言本情景的制作缘起于编辑部送给我的一盒威龙北非兵人。怎奈因诸事扰之,期间停工半年有余,致使整个制作周期长达一年两个月。停工虽打乱了制作的节奏,但却使我有机会沉淀下来总结自己这几年模型制作的心得。所以,本情景可以说是我为了求证自己这些感悟对与错的一个实验性作品。我将本情景的背景设定在1942年北非的突尼斯,德军北非军团501重型坦克营一辆三号N型坦克和一辆82侦察车相聚于某一小镇,装甲兵和侦察车成员正在相互交流情报,而一些装甲掷弹兵则在休整补充物资。     

Covalent triazine framework with efficient photocatalytic activity in aqueous and solid media

Covalent triazine frameworks (CTFs) have been recently employed for visible light-driven photocatalysis due to their unique optical and electronic properties. However, the usually highly hydrophobic nature of CTFs, which originates from their overall aromatic backbone, leads to limitations of CTFs for applications in aqueous media. In this study, we aim to extend the range of the application media of CTFs and design hybrid material of a CTF and mesoporous silica (SBA-15) for efficient photocatalysis in aqueous medium. A thiophene-containing CTF was directly synthesized in mesopores of SBA-15. Due to the high surface area and the added hydrophilic properties by silica, the hybrid material demonstrated excellent adsorption of organic molecules in water. This leads not only to high photocatalytic performance of the hybrid material for the degradation of organic dyes in water, but also for efficient photocatalysis in solvent-free and solid state. Furthermore, the reusability, stability and easy recovery of the hybrid material offers promising metal-free heterogeneous photocatalyst for broader applications in different reaction media.     

浅谈SCR脱硝技术控制方案及主要仪表选型

针对目前炼油厂应用效果较好的SCR(选择性催化还原法)脱硝技术,分析了SCR技术主要的控制方式及主要仪表选型,为更好实现经济效益与环保效益奠定了基础。     

“电子封装和PCB组装的材料、工艺和可靠性”学术讲座

前言：电子产品日益小型化、高功耗和环保要求对电子封装和PCB组装以及材料供应商提出了许多挑战。在这次讲座中我们将详细讲解电子元件封装和PCB组装技术以及工艺，并了解组装材料和工艺对最终产品质量和可靠性的影响。例举并讨论组装材料，例如焊料合金、焊膏、助焊剂和芯片粘接材料的主要特性，及评估认证这些材料和工艺优化的方法。对HoHS和无铅加工技术和可靠性进行深入的探讨。进一步，我们将回顾发生在电子元器件和PCB组装中的主要失效机理。我们将以实际案例来讲解产品可靠性评估，寿命预测，HALT／ESS试验方法。     

Nucleation Mechanism for Bainite

Based on the experimental results that solute-depleted zone was observed in Cu-28Zn-4AI (mass fraction) at 523 K, AG is calculated as a positive according to the thermodynamic criteria for the spinodal decomposition of a ternary systems. So, the solute-depleted zone cannot be formed by spinodal decomposition. Dislocation density required by the formation of solute-depleted zone is estimated greater than 7.89×109 cm-2, according to the segregation of solute atoms around dislocations, which is not consistent with the practical situation for the alloy at 523 K. Associated with the internal friction experimental fact that internal friction peaks appear within the incubation for bainitic transformation in Cu-Zn-AI alloy, the equilibrium temperature, TO, is evaluated as 433 K for solute-depleted Cu-25Zn-3.4AI, which is lower than the experimental temperature 523 K. Thus, nucleation by shear mechanism is impossible in this circumstance. Therefore, it is concluded that, like bainite in steels and Ag-Cd, bainite in     

"大学城"建设的冷思考

基于大学校园建设实践,分析目前新校园建设中存在的共性问题,并为校园建设发展提出若干建议。     

应该补上的一课

~~呆伯特连载漫画@史考特·亚当斯~~     

家有天使——宣士通FMVFA50电脑一体机

未来的家用电脑该是怎样的？学习过电脑的人都知道，电脑是由主机和显示器两大部分组成的，那么未来的家用电脑还是这样一成不变的吗？虽然我们现在不知道未来的家用电脑是怎么一个模样，但有一点我们可以肯定的是未来的家用电脑与家居的融合将越来越紧密，就像我们现在看到的富士通FMVFA50电脑一体机一样。