有机-无机压电材料TMCM-MnCl3的研究

有机-无机压电材料是一种分子铁电体，具有柔性、结构灵活、易成膜、全液相合成及环保节能等优点，可满足新一代薄膜器件及可穿戴设备的需求。该文以三甲基卤代甲基铵(TMXM, X=F, Cl, Br)为有机部分，MnCl₂为无机部分，通过溶液蒸发法制备了具有钙钛矿分子结构的有机-无机压电材料三甲基氯三氯化锰(TMCM-MnCl₃)，并对其分子结构组成、压电、热学、声学及铁电性进行表征。结果表明，TMCM-MnCl₃的压电常数为106 pC/N，居里温度为130 ℃，声阻抗值约为16.5 MRayl，低于压电陶瓷PZT-4(大于33 MRayl)，具有广阔的应用前景。     

Synergistic effect of bulk phase doping and layered-spinel structure formation on improving electrochemical performance of Li-Rich cathode material

In this study, La was doped into the lithium layer of Li-rich cathode material and formed a layered-spinel hetero-structure. The morphology, crystal structure, element valence and kinetics of lithium ion migration were studied by field emission scanning electron microscope (FESEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS) and electrochemical impedance spectroscopy (EIS). The La doped lithium-rich cathode material exhibited similar initial discharge capacity of 262.8 mAh g^?1 at 0.1 C compared with the undoped material, but the discharge capacity retention rate can be obviously improved to 90% after 50 cycles at 1.0 C. Besides that, much better rate capability and Li⁺ diffusion coefficient were observed. The results revealed that La doping not only stabilized the material structure and reduced the Li/Ni mixing degree, but also induced the generation of spinel phase to provide three-dimensional diffusion channels for lithium ion migration. Moreover, the porous structure of the doped samples also contributed to the remarkable excellent electrochemical performance. All of these factors combined to significantly improve the electrochemical performance of the material.     

Study on wax precipitation characteristics of wax deposit in pipes

Wax deposit properties are a significant concern in pipeline pigging during waxy crude oil transportation. In the present work, the impacts of flow conditions and oil properties on the wax precipitation characteristics of wax deposits are investigated. A flow loop apparatus was developed to conduct wax deposition experiments using four crude oils collected from different field pipes. The differential scanning calorimetry (DSC) technique was employed to observe the wax precipitation characteristics of crude oil and wax deposit. The results show that the wax content and the wax appearance temperature (WAT) of the deposits increase with shear stress and radial temperature gradient, and decrease with radial wax molecule concentration gradient near the pipe wall. The DSC tests on the wax deposits revealed that the deposit wax content is strongly correlated to the oil wax content. Furthermore, an empirical correlation was developed to predict the wax content and the WAT of the wax deposit. Verification of the empirical correlation using the different oils indicated that the average relative error of the wax content prediction and average absolute error of WAT prediction were 13.2% and 3.6°C, respectively.     

县区电网电压无功控制系统设计

针对目前地区电网电压无功控制的现状,提出了电网电压无功监控系统的设计方案。说明优化控制系统应该实现的功能,选用线性规划(LP)算法为核心程序,正常状态下以有功网损最小为目标函数。依据分离原理提出两层分级控制的系统结构,分析优化控制系统的工作流程及特点。     

活化疏松剂用于过磷酸钙生产的性能研究

介绍了在过磷酸钙中添加活化疏松剂的试验情况及运用效果。试验结果表明 :添加活化疏松剂后鲜肥转化率提高 4.0 % ,产品物性得到改善 ,结块倾向明显降低。     

低差错平底特性的非规则LDPC码的设计

介绍了非规则LDPC码的发展并给出了其优势及缺点，重点论述用ACE算法来构造非规则LDPC码从而降低其差错平底特性。对降低非规则LDPC码的差错平底特性的其它方法提出了展望。     

乡镇供水工程设计中应注意的若干问题

乡镇供水作为水利开发建设中的一个新领域，设计工作是龙头，有许多技术问题需要研究和探索，阐述了乡镇供水工程设计应注意的若干问题，并对设计中存在的一些具体问题进行了分析和探讨。     

940nm高功率激光二极管及线阵

设计并制作出了940 nm无铝有源区高功率激光二极管和激光条.通过MOCVD法生长出应变量子阱材料,器件显示出极好的性能,100μm条宽的激光二极管最大输出功率达800mW(室温),填充因子为17%的激光二极管条发射功率达32 W.     

伊朗德黑兰地铁轨道施工方法

依托伊朗德黑兰地铁一、二号线工程 ,针对地铁单洞单线采用的轨道施工轨排法存在的不足 ,根据单洞双线隧道的特点 ,提出了利用组装好的轨排直接铺设在隧道结构底板上作为轨道平板车临时轨道的施工新方法