Efficient electrochemomechanical energy conversion in nanochannels grafted with polyelectrolyte layers with pH-dependent charge density

Nanochannels, functionalized by grafting with a layer of charged polyelectrolyte (PE), have been employed for a large number of applications such as flow control, ion sensing, ion manipulation, current rectification and nanoionic diode fabrication. Recently, we established that such PE-grafted nanochannels, often denoted as “soft” nanochannels, can be employed for highly efficient, streaming-current-induced electrochemomechanical energy conversion in the presence of a background pressure-driven transport. In this paper, we extend our calculation for the practically realizable situation when the PE layer demonstrates a pH-dependent charge density. Consideration of such pH dependence necessitates consideration of hydrogen and hydroxyl ions in the electric double layer charge distribution, cubic distribution of the monomer profile, and a PE layer-induced drag force that accounts for this given distribution of the monomer profile. Our results express a hitherto unknown dependence of the streaming electric field (or the streaming potential) and the efficiency of the resultant energy conversion on parameters such as the pH of the surrounding electrolyte and the \(\hbox {pK}_{\mathrm{a}}\) of the ionizable group that ionizes to produce the PE charge—we demonstrate that increase in the pH and the PE layer thickness and decrease in the \(\hbox {pK}_{\mathrm{a}}\) and the ion concentration substantially enhance the energy conversion efficiency.     

Technical appraisal of solar home systems in Bangladesh: A field investigation

Solar Home System (SHS) based rural electrification has experienced a considerable growth in Bangladesh since the start of the Rural Electrification and Renewable Energy Development Project (REREDP) in 2003. The initial target of 50,000 SHS installations in off-grid areas was achieved within 2.5 years, 3 years ahead of schedule. After achieving a revised target of 200,000 SHSs, ahead of schedule in early 2009, a new target of 1 million SHS installations by 2012 was set. The installation of about 0.5 million systems by March 2010 indicates that the current target may well be achieved before the deadline. The size of the SHS market and its impact on the regeneration of the rural economy make it necessary to investigate the quality and reliability of the installed SHSs, if the continued success of the initiative is to be maintained. This paper reports on the findings from a field-based technical appraisal of SHS installations in Bangladesh. Sixty geographically dispersed installation sites were visited. Physical characteristics of the SHSs and their system components were tested to ascertain compliance with and deviations from the approved specifications. Despite the overwhelming success of the REREDP project, the study revealed various shortcomings. Notable among these are: incompatible and sub-optimal component configurations, faulty installations and a lack of effective quality assurance mechanism. The findings are contextualized and the ways to address the identified shortcomings are discussed.     

Adaptive compressive sensing for target tracking within wireless visual sensor networks-based surveillance applications

Wireless Visual Sensor Networks (WVSNs) have gained significant importance in the last few years and have emerged in several distinctive applications. The main aim is to design low power WVSN surveillance application using adaptive Compressive Sensing (CS) which is expected to overcome the WVSN resource constraints such as memory limitation, communication bandwidth and battery constraints. In this paper, an adaptive block CS technique is proposed and implemented to represent the high volume of captured images in a way for energy efficient wireless transmission and minimum storage. Furthermore, to achieve energy-efficient target detection and tracking with high detection reliability and robust tracking, to maximize the lifetime of sensor nodes as they can be left for months without any human interactions. Adaptive CS is expected to dynamically achieve higher compression rates depending on the sparsity nature of different datasets, while only compressing relative blocks in the image that contain the target to be tracked instead of compressing the whole image. Hence, saving power and increasing compression rates. Least mean square adaptive filter is used to predicts target’s next location to investigate the effect of CS on the tracking performance. The tracking is achieved in both indoor and outdoor environments for single/multi targets. Results have shown that with adaptive block CS up to 20 % measurements of data are required to be transmitted while preserving the required performance for target detection and tracking.     

A NOMA-Enabled Cellular Symbiotic Radio for mMTC

Wireless Personal Communications - Non-orthogonal multiple access (NOMA) scheme, potentially enabling high spectral efficiency, is one of the key technological innovations in the 5th generation...     

Polypropylene nanocomposites with oxo‐degradable pro‐oxidant: Mechanical,thermal, rheological,and photo‐degradation performance

The objective of the study was to generate degradable polypropylene nanocomposites by incorporation of pro‐oxidant and different fillers like silica, silicate, and thermally reduced graphene. Graphene‐based composites exhibited higher crystallinity attributed to better dispersion and high aspect ratio platelets. Graphene composites with 2.5% additive content significantly enhanced the peak degradation temperature to 464°C as compared to 448°C for pure polymer. The processing conditions used for the nanocomposite generation were optimum as a uniform distribution of filler particles (or platelets) was observed in the PP matrix. The tensile modulus of the graphene composite with 2.5% additive content was 80% higher than pure PP, as compared to 60 and 30% for silicate and silica composites, respectively. Similarly, the storage modulus of the graphene nanocomposite with 1% additive content had 30% increment at 40°C as compared to pure PP. PP‐additive blends as well as PP nanocomposites with silica and silicate were observed to attain 100% degree of embrittlement within 6 months of UV exposure at 30°C. Graphene composites, though, had delayed photo‐degradation due to UV absorption by the platelets and high aspect ratio platelets acting as oxygen barrier for PP matrix, but the pro‐oxidant was successful in attaining controlled degradation. POLYM. ENG. SCI., 56:1229–1239, 2016. © 2016 Society of Plastics Engineers     

Electrokinetics in nanochannels grafted with poly-zwitterionic brushes

In this paper, we compute the electrokinetic transport in soft nanochannels grafted with poly-zwitterionic (PZI) brushes. The transport is induced by an external pressure gradient, which drives the ionic cloud (in the form of an electric double layer or EDL) at the brush surfaces to induce an electric field that drives an induced electroosmotic transport. We characterize the overall transport by quantifying this electric field, overall flow velocity, and the energy conversion associated with the development of the electric field and a streaming current. We specially focus on how the ability of the PZI to ionize and demonstrate a significant charge at both large and small pH can be efficiently maneuvered to develop a liquid transport, an electric field, and an electrokinetically induced power across a wide range of pH values.     

SMOaaS: a Scalable Matrix Operation as a Service model in Cloud

The Journal of Supercomputing - Matrix operations are fundamental to a wide range of scientific applications such as Graph Theory, Linear Equation System, Image Processing, Geometric Optics, and...     

Analytical framework for adaptive compressive sensing for target detection within wireless visual sensor networks

Multimedia Tools and Applications - Wireless visual sensor networks (WVSNs) are composed of a large number of visual sensor nodes covering a specific geographical region. This paper addresses the...     

Capacity and coverage increase with repeaters in UMTS urban cellular mobile communication environment

In this letter, we propose to use repeaters to increase system information capacity in urban areas, where path loss exponents are higher (as much as 3.4 or more). There is at least a 10% increase in coverage area when repeaters are placed in every cell within the network to increase system capacity. The overall system information capacity is doubled at propagation exponent 3.7-3.9.