离子液体中α,β-不饱和化合物的绿色合成

芳香醛和活泼亚甲基化合物为原料,在离子液体中进行Knoevenagel缩合反应。本工艺避开了传统方法中在加入催化剂的有机溶剂中进行Knoevenagel缩合反应的步骤,采用离子液体为反应提供环境和催化,具有操作简单、成本低、对设备无特殊要求和环境友好的优点。     

Numerical Investigation of the Capture of Polydisperse Particles by Charged Droplets

The capture of particles by charged droplets was simulated by considering the electrostatic interactions of droplet-droplet and droplet-particle. The results indicate that the electrostatic repulsion between droplets leads to a dynamic accumulation mode of particles. However, the droplet spacing has an insignificant effect on the capture efficiency when the electrostatic deposition predominates. The increase of droplet charge remarkably improves the capture efficiency, in which the capture of fine particles accounts for the largest proportion. Compared to the droplet charge, the droplet size shows a limited improvement in the capture efficiency. Reducing the droplet velocity prolongs the capture time instead of enhancing the capture capacity per unit time, thereby improving capture efficiency.     

Structural,morphological, dielectric and magnetic properties of Zn-Zr co-doping yttrium iron garnet

In this study, yttrium iron garnet co-doped with Zn and Zr atoms with a chemical formula Y₃Zn_xZr_xFe_(5−2x)O₁₂ (x = 0.0-0.3) has been successfully prepared by the solid-state reaction method. The effects of doping concentration on the microstructure, crystal structure, magnetic properties, and dielectric properties of Y₃Zn_xZr_xFe_(5−2x)O₁₂ were investigated. The microstructure analysis indicates that co-doping of YIG with Zn and Zr can effectively reduce the grain size of the ceramic. The crystal structure results reveal that the doping concentration of Zn–Zr has substantial influence on the lattice parameters of YIG, such as, increases the lattice constant, crystal cell size, and interplanar spacing. However, the second phase of ZrO₂ appears once x ≥ 0.15. Additionally, the dielectric properties of YIG ferrite can be regulated using this Zn–Zr co-doping method. Zn–Zr co-doping can improve the dielectric stability and reduce the dielectric loss at high temperature. The magnetization measurement shows that the saturation magnetization is stabilized at x < 0.15, and the magnetic loss is decreased with the increase in the doping concentration. Overall, the findings show that the ceramic with x = 0.1 exhibits better properties included high saturation magnetization (24.607 emu/g), low magnetic loss (0.0025 @ 1 MHz), and relatively low dielectric loss (496 @ 400°C).     

Effect of Biochar as Reductant on Magnetizing-roasting Behavior of Pyrite Cinder

The effect of biochar substituted for anthracite as reductant on magnetizing-roasting pyrite cinder was investigated.The key of magnetizing-roasting is the gasification reaction between reductants and CO2.Since biochar could react with CO2 more rapidly at lower temperature,the reactivity of biochar is better than that of anthracite.The gasification of biochar could produce reducing condition ofφCO/(φCO+φCO2)about 10%-20% between 700-800 ℃,which is in accord with the atmosphere and temperature of Fe2O3 reduction.So it is beneficial to the reduction of iron mineral of pyrite cinder.Compared with anthracite,biochar could decrease the roasting temperature from825 to 750 ℃ and roasting time from 20 to 15min,which shows that a better effect of magnetization could be obtained in the condition of lower temperature and shorter time.Using biochar as reductant,iron concentrate extracted from pyrite cinder as about 64%iron grade could be produced,and the recovery is over 90% under the condition of above 90% grinding particle less than 0.045 mm and magnetic intensity of 0.124-0.194 T.     

CDMA 1x EV-DO覆盖模型的分析与仿真

结合经过校正后的适合于本地无线环境的OKUMURA-HATA传播模型，建立起一种新的本地化基于1x EV—DO系统数据业务吞吐量分析的覆盖预测仿真模型，可应用于1xEV—DO系统的网络规划及系统性能分析。     

低渗低温低压水敏性储气层压裂改造技术研究与应用

低渗低温低压水敏性储气层因压裂液快速破胶困难、黏土膨胀水敏伤害严重和压后压裂液返排动力不足等因素，使得压裂增产面临诸多难题。针对上述难题进行了技术攻关，形成了弱交联、低温活化剂与超量破胶剂的低温储层快速破胶技术、有机盐与无机盐双元体系复合防膨技术以及高比例液氮全程助排的排液技术。该压裂增产改造技术使牛101井头屯河组首次获得工业油气流，扩展了三塘湖盆地勘探空间。     

克拉2气田水处理装置设计浅析

介绍了克拉2气田中央处理厂一期气田水处理装置的处理工艺特点和流程。针对气田水的最终去向，分析气田水的水质特点，提出合理的处理方案，既符合环保要求，达到保护环境的目的，又简化了工艺，节约了投资。     

玻璃碳电极的激光改性处理

玻璃碳电极（ＧＣＥ）用激光脉冲照射处理后，电化学反应行为发生很大变化。背景电流减小，Ｆｅ３＋／Ｆｅ２＋氧化还原电对的电极反应速率显著提高，抗坏血酸（ＡＡ）在电极上呈现明显的吸附作用。