Electrical and optical properties of fluorine-doped CdO films deposited by ultrasonic spray pyrolysis

The CdO:F samples have been deposited onto microscope glass substrates at 250 °C by ultrasonic spray pyrolysis method. With the incorporation of fluorine into CdO, the direct optical transition has shifted towards the shorter wavelengths, and the transparency of the material has increased at a given wavelength above the fundamental absorption edge. The shift in the absorption edge is explained by means of the Moss–Burstein effect, which is also supported with the results of the current–voltage characteristics. Here, a correlation has been established between the band broadening and the increase in conductivity due to the increase in carrier density.     

Theoretical Investigation of Time Suboptimal Control of Industrial Manipulators Along Specified Paths

A method for the time suboptimal control of an industrial manipulator from an initial position and orientation to a final position and orientation as it moves along a specified path is proposed. Nonlinear system equations that describe the manipulator motion are linearized at each time step along the path. A method which gives the control inputs (joint angular velocities) for time suboptimal control of the manipulator is developed. In the formulation, joint angular velocity and acceleration limitations are also taken into consideration. A six degree of freedom elbow type manipulator is used in numerical examples to verify the method developed.     

A combo technology of autotrophic and heterotrophic denitrification processes for groundwater treatment

In this study,a sequential process (heterotrophic up-flow column and completely mixed membrane bioreactors) was proposed combining advantages of the both processes.The system was operated for 249 days with simulated and real groundwater for nitrate removal at concentrations varying from 25 to 145 mg·L-1 NO3-N.The contribution of heterotrophic process to total nitrate removal in the system was controlled by dozing the ethanol considering the nitrate concentration.By this way,sulfur based autotrophic denitrification rate was decreased and the effluent sulfate concentrations were controlled.The alkalinity requirement in the autotrophic process was produced in the heterotrophic reactor,and the system was operated without alkalinity supplementation.Throughout the study,the chemical oxygen demand in the heterotrophic reactor effluent was (23.7 ± 22) mg·L-1 and it was further decreased to(7.5 ± 7.2) mg·L-1 in the system effluent,corresponding to a 70％ reduction.In the last period of the study,the real groundwater containing 145 mg·L-1 NO3-N was completely removed.Membrane was operated without chemical washing in the first 114 days.Between days 115-249 weekly chemical washing was required.     

纳米MOFs及其衍生物在超级电容器中的研究进展

金属有机框架（MOFs）材料因其大的比表面积、可调控的孔道结构和丰富的活性位点引起了国内外学者们的广泛关注。近年来MOFs基材料广泛应用于能量储存与转化领域,但大多数MOFs基材料的低稳定性和低导电性等缺陷限制了其实际应用。通过对MOFs基材料进行改性,如采用共轭度高的有机配体以增加MOFs材料的稳定性,或MOFs衍生物以提高其氧化还原活性位点和导电性,从而达到提高MOFs基电极材料的电化学性能。主要介绍了原始MOFs及其衍生材料如碳材料、金属氧化物、金属硫化物、金属氢氧化物和金属磷化物等在超级电容器电极材料中的最新研究进展。研究表明,多金属MOFs材料或多金属MOFs衍生物有利于提高电极材料的电化学性能,而导电MOFs材料或MOFs衍生物中的碳材料有利于提高电极材料的导电性。最后对MOFs基电极材料在电化学储能领域中的研究做出了展望,指出MOFs基材料的形貌、组分和导电性是未来研究的发展方向。     

基于灰色关联分析的电网安全事故关键致因分析

探讨和研究电网安全事故的影响因素及控制已成为预防电网安全事故发生的热点问题.为揭示电网安全事故发生的深层机理,基于事故致因理论,采用质性分析和灰色关联分析的方法,分析中国电网安全事故的关键致因.研究发现,电网安全事故的影响因素主要包括主体因素(认知因素、行为因素和身体因素)、过程因素(组织氛围因素和组织过程因素)、对象...     

Evaluation of damage to light structures erected on a fill material rich in expansive soil

The paper reports a study of the cause of defects in light structures and the toppling of a wall constructed on a fill material rich in Ankara clay. Laboratory tests were carried out on vertical and horizontal samples from boreholes and a trial pit was excavated near the damaged structures. The results showed that in the vicinity of the toppled wall, swelling pressures in the horizontal direction were greater than those measured in the vertical direction. The swelling properties of the fill material were higher than those of original Ankara clay as determined previously by other investigators, suggesting that breakdown of the cementing bonds and a change in the fabric are the main factors affecting the swelling pressure of disturbed and compacted expansive soils. The calculations to predict uplift showed a good agreement with the observations in the damaged structures. It is concluded that swelling was the main cause of the damage to the light structures at the study site and resulted from the highly expansive nature of the fill material, poor drainage, the semi-arid climate, poor construction methods and ineffective precautions. Some recommendations for minimizing the effects of swelling at the study site are briefly outlined.     

Thermal Conductivity and Viscosity of Nanofluids Having Nanoencapsulated Phase Change Material

In this study, the thermal conductivity and viscosity of nanofluids, composed of a base fluid and nanoencapsulated phase change material (NEPCM), were investigated experimentally. The NEPCM was prepared by the encapsulation of n-nonadecane as phase change material with diethylenetriamine and toluene-2,4-diisocyanate using interfacial polymerization method. The NEPCM was characterized using scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), and differential scanning calorimetry (DSC) analyses. In the preparation of the nanofluids containing NEPCM, two different base fluids, water and ethylene glycol (EG), were used. The concentration of NEPCM and the working temperature were selected as the main parameters. It was found that the viscosity of the nanofluids decreases with increasing temperature and increases with increasing solid concentration. The viscosity was also expressed as a function of the solid concentration and temperature. The thermal conductivity of the nanofluids was found to increase with increasing temperature. Thermal conductivity exhibited an increasing tendency with increasing solid concentration, but the changes in thermal conductivity according to base fluid are in the range of uncertainty of the measurement for both nanofluids with a solid volumetric fraction lower than 1.68%.     

Stochastic resonance in binary composite hypothesis-testing problems in the Neyman–Pearson framework

Performance of some suboptimal detectors can be enhanced by adding independent noise to their inputs via the stochastic resonance (SR) effect. In this paper, the effects of SR are studied for binary composite hypothesis-testing problems. A Neyman–Pearson framework is considered, and the maximization of detection performance under a constraint on the maximum probability of false-alarm is studied. The detection performance is quantified in terms of the sum, the minimum, and the maximum of the detection probabilities corresponding to possible parameter values under the alternative hypothesis. Sufficient conditions under which detection performance can or cannot be improved are derived for each case. Also, statistical characterization of optimal additive noise is provided, and the resulting false-alarm probabilities and bounds on detection performance are investigated. In addition, optimization theoretic approaches to obtaining the probability distribution of optimal additive noise are discussed. Finally, a detection example is presented to investigate the theoretical results.     

Multi-sink load balanced forwarding with a multi-criteria fuzzy sink selection for video sensor networks

Congestion is a challenging problem in wireless sensor networks, which exacerbates with the high volume of data traffic imposed by video applications such as video surveillance and target tracking. Deployment of multiple sinks is a candidate solution for congestion and is also promising in terms of reliability and energy-efficiency. In order to gain the maximum benefit from multiple sinks, it is essential to distribute the load among them evenly. In this paper, we propose a cross layer geographic forwarding scheme MLBRF (Multi-Sink Load Balanced Reliable Forwarding) which aims to provide reliable and energy efficient video delivery in a multi-sinked sensor network for target tracking. In order to provide load balancing among the sinks, MLBRF proposes a sink selection mechanism based on fuzzy logic for the frame forwarding which evaluates the traffic density in the direction of each sink by combining two dynamic criteria which are the number of contenders and the buffer occupancy levels in the neighborhood with the static distance criterion. The performance of the fuzzy sink selection mechanism is compared using simulation with various sink selection mechanisms. The results show that MLBRF gains the maximum benefit from deploying multiple sinks in terms of reliability, latency and energy efficiency by using the proposed fuzzy sink selection mechanism.