Preparation, Characterisation and Catalytic Behaviour of a New TeVMoO Crystalline Phase

TeM_xMo_1.7O mixed oxides (M = V and/or Nb; x = 0-1.7) have been prepared by calcination of the corresponding salts at 600 °C in an atmosphere of N₂. A new crystalline phase, with a Te/V/Mo atomic ratio of 1/0.2-1.5/1.7, has been isolated and characterised by XRD and IR spectroscopy. This phase is observed in the TeVMo or TeVNbMo mixed oxide but not in the TeNbMo mixed oxide. The new crystalline phase shows an XRD pattern similar to Sb₄Mo₁₀O₃₁ and probably corresponds to the M1 phase recently proposed by Aouine et al. (Chem. Commun. 1180, 2001) to be present in the active and selective MoVTeNbO catalysts. Although these catalysts present a very low activity in the propane oxidation, they are active and selective in the oxidation of propene to acrolein and/or acrylic acid. However, the product distribution depends on the catalyst composition. Acrolein or acrylic acid can be selectively obtained from propene on Nb-free or Nb-containing TeVMo catalysts, respectively. The presence of both V and Nb, in addition to Mo and Te, appears to be important in the formation of acrylic acid from propene.     

Comparison of supports for the direct synthesis of hydrogen peroxide from H2 and O2 using Au–Pd catalysts

The direct synthesis of hydrogen peroxide from H₂ and O₂ using a range of supported Au–Pd alloy catalysts is compared for different supports using conditions previously identified as being optimal for hydrogen peroxide synthesis, i.e. low temperature (2 °C) using a water–methanol solvent mixture and short reaction time. Five supports are compared and contrasted, namely Al₂O₃, -Fe₂O₃, TiO₂, SiO₂ and carbon. For all catalysts the addition of Pd to the Au only catalyst increases the rate of hydrogen peroxide synthesis as well as the concentration of hydrogen peroxide formed. Of the materials evaluated, the carbon-supported Au–Pd alloy catalysts give the highest reactivity. The results show that the support can have an important influence on the synthesis of hydrogen peroxide from the direct reaction. The effect of the methanol–water solvent is studied in detail for the 2.5 wt% Au–2.5 wt% Pd/TiO₂ catalyst and the ratio of methanol to water is found to have a major effect on the rate of hydrogen peroxide synthesis. The optimum mixture for this solvent system is 80 vol.% methanol with 20 vol.% water. However, the use of water alone is still effective albeit at a decreased rate. The effect of catalyst mass was therefore also investigated for the water and water–methanol solvents and the observed effect on the hydrogen peroxide productivity using water as a solvent is not considered to be due to mass transfer limitations. These results are of importance with respect to the industrial application of these Au–Pd catalysts.     

Mechanical sensorless speed control of permanent-magnet AC motors driving an unknown load

A new sensorless scheme for high-performance speed control of permanent-magnet ac motors (PMACMs) driving an unknown load is proposed. This scheme uses an extended nonlinear reduced-order observer to estimate the induced electromotive force (EMF) and load torque. From the estimated variables, the rotor position, the rotor speed, and the position derivative of flux are calculated and are used to close the control loop. In order to improve the drive performance, the estimated load torque is incorporated as a feedforward signal in the closed control loop. In addition, the proposed sensorless PMACM drive allows the torque-ripple and copper-loss minimization for motors with an arbitrary EMF waveform. Simulation and experimental results to validate the proposal are presented in this paper.     

Feedback linearization via state transformation using estimated states

This paper deals with the exact feedback linearization of nonlinear plants using estimated states. Under appropriate hypotheses, exact linearization can be achieved through transformation of states and feedback. We assume that the states cannot be measured so that a nonlinear observer, with exponential convergence, is included in the loop. We establish sufficient conditions to guarantee that the overall system trajectories asymptotically converge to those obtained with feedback linearization utilizing the true states. We apply our results to control an electrical drive using a permanent-magnet synchronous motor without mechanical and optical sensors. The behaviour of our control scheme is illustrated by simulations.     

Analyzing locality over a P2P computing architecture

A characteristic of Peer-to-Peer (P2P) computing networks is their huge number of different computational resources scattered across the Internet. Gathering peers into markets according to their multi-attribute computational resources makes it easier to manage these environments. This solution is known as market overlay. In this context, the closeness of the markets with similar resources, known as locality, is a key feature for ensuring good P2P resource management. Thus, the locality feature over a market overlay allows a lack of resources in a given market to be compensated quickly by any other market with similar resources, whenever these are close to each other. Consequently, locality becomes an essential challenge.This paper addresses the analysis of the locality of P2P market over-lays. According to this, a new procedure for measuring locality is applied together with an extensive analysis of some well-known structured P2P overlays. Based on this analysis, a new P2P computing architecture, named DisCoP, oriented towards optimizing locality is proposed. Our proposal gathers the peers into markets according to their computational resources. A Hilbert function is used to arrange multi-attribute markets in an ordered and mono-dimensional space and the markets are linked by means of a Bruijn graph. In order to maintain the DisCoP locality whenever the overlay is not completed, a solution based on the virtualization of markets is also proposed. Finally, the DisCoP locality is tested together with the proposed virtualization method for approximate searches over uncompleted overlays. The simulation results show that approximate searches exploit the DisCoP locality efficiently.     

State-based predictions with self-correction on Enterprise Desktop Grid environments

The abundant computing resources in current organizations provide new opportunities for executing parallel scientific applications and using resources. The Enterprise Desktop Grid Computing (EDGC) paradigm addresses the potential for harvesting the idle computing resources of an organization’s desktop PCs to support the execution of the company’s large-scale applications. In these environments, the accuracy of response-time predictions is essential for effective metascheduling that maximizes resource usage without harming the performance of the parallel and local applications. However, this accuracy is a major challenge due to the heterogeneity and non-dedicated nature of EDGC resources. In this paper, two new prediction techniques are presented based on the state of resources. A thorough analysis by linear regression demonstrated that the proposed techniques capture the real behavior of the parallel applications better than other common techniques in the literature. Moreover, it is possible to reduce deviations with a proper modeling of prediction errors, and thus, a Self-adjustable Correction method (SAC) for detecting and correcting the prediction deviations was proposed with the ability to adapt to the changes in load conditions. An extensive evaluation in a real environment was conducted to validate the SAC method. The results show that the use of SAC increases the accuracy of response-time predictions by 35%. The cost of predictions with self-correction and its accuracy in a real environment was analyzed using a combination of the proposed techniques. The results demonstrate that the cost of predictions is negligible and the combined use of the prediction techniques is preferable.     

Effect of Potassium Doping on the Catalytic Behavior of Mo–V–Sb Mixed Oxide Catalysts in the Oxidation of Propane to Acrylic Acid

Small addition of potassium to a Mo–V–Sb mixed oxide catalyst (previously prepared by hydrothermal synthesis) strongly modifies its catalytic behavior. Thus, while acetic acid is mainly observed in the K-free catalysts, acrylic acid is selectively obtained in K-doped catalysts. In this case, a selectivity to acrylic acid of about 30% is achieved at propane conversions of 30%. This catalytic behavior is apparently not due to modification of the crystalline phases in the K-doped catalysts but to the elimination of the acid sites of the undoped Mo–V–Sb mixed oxide catalyst.     

Extravesical involvement in patients with bladder carcinoma in situ: biological and therapy implications

PURPOSE: The biological and therapeutic implications of extravesical involvement in patients with bladder carcinoma in situ were analyzed. MATERIALS AND METHODS: Of 138 patients with bladder carcinoma in situ 87 (63%) had extravesical involvement, including the prostate in 53, the upper urinary tract in 11 and both structures in 23 (pan-urothelial involvement). With survival free of disease as an end point, univariate and multivariate analyses were done. RESULTS: Patients with extravesical involvement had worse survival than those with bladder carcinoma in situ alone (p < 0.001). In multivariate analysis prostate involvement (p = 0.0007) and pan-urothelial involvement (p = 0.0001) were selected as significant variables. When pathological patterns were considered prostatic stromal invasion (p = 0.0002) was the only variable selected. With these data 3 patient groups with disease mortality risk were defined. CONCLUSIONS: Prostate involvement and pan-urothelial involvement behave as independent prognostic factors, with the latter probably reflecting an extremetly diffuse character of carcinoma in situ. However, the upper urinary tract had no influence on survival. In patients with upper urinary tract and/or prostatic involvement limited to the mucosa treatment can be conservative. Patients with ductal or stromal involvement should undergo radical treatment. For upper tract involvement conservative approaches may be considered if there are no radiological signs of invasion or low grade tumor.     

Adrenal gland incidentaloma in the oncologic patient: is its histologic study obligatory?

We evaluated the performance of an automatic polymerase chain reaction (PCR) detection system for identification of Mycobacterium tuberculosis in respiratory specimens. Six hundred and two respiratory specimens, including 557 sputa and 45 bronchial washing samples, were analyzed using the COBAS AMPLICOR Mycobacterium tuberculosis (MTB) test. The results were compared with those obtained from acid-fast microscopy, conventional culture, and clinical history. In cases of discrepancy between the results of the COBAS AMPLICOR MTB test and culture, the medical history of the patient was reviewed, the COBAS AMPLICOR MTB test was repeated, and the gene encoding M. tuberculosis superoxide dismutase was screened using PCR (SOD-PCR). Fourteen samples were excluded because the internal control test result was negative. Of 57 specimens that were culture positive for Mycobacterium species, 40 appeared to have growth of M. tuberculosis and 21 were smear positive for acid-fast bacteria. The sensitivity, specificity, and positive and negative predictive values for the COBAS AMPLICOR MTB test evaluated at our laboratory were 85.0% (34/40), 99.3% (544/548), 89.5% (34/38), and 98.9% (544/550), respectively. Three specimens that were culture positive for M. tuberculosis but negative by COBAS AMPLICOR MTB test were positive when rechecked by both COBAS AMPLICOR MTB test and SOD-PCR. Among the four specimens with positive reactions on both COBAS AMPLICOR MTB test and SOD-PCR that were culture negative, two were from patients who had been receiving antituberculosis treatment, one was from a patient who had been treated for tuberculosis for 1 year, and the other was from a patient who died of sepsis with adult respiratory distress syndrome. In more than 70% of smear-negative and culture-positive specimens and 86.4% of smear-positive specimens, M. tuberculosis was identified by the COBAS AMPLICOR MTB test within 10 hours after receipt of the specimens. Our data show that the COBAS AMPLICOR MTB test provides rapid and accurate detection of M. tuberculosis in respiratory specimens.