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排序方式: 共有975条查询结果,搜索用时 15 毫秒
1.
Dhirendra Kumar Mishra Gopal Pugazhenthi Tamal Banerjee 《International Journal of Hydrogen Energy》2021,46(29):15773-15779
The current work explores the usage of novel synthesized Deep Eutectic Solvent (DES) as a catalyst cum solvent media for the thermal dehydrogenation of chemical hydrides, namely Ammonia Borane (AB) and Ethylene diamine bisborane (EDAB). In the first instance, the quantum chemistry based COSMO-SAC (COnductor like Screening MOdel Segment Activity Coefficient) model was used for the selection of the pertinent solvent. 1-Butyl-3-methylimidazolium methanesulfonate: Imidazole ([BMIM][MeSO3]:[Im]) turned out to be an ideal eutectic mixture with the highest predicted solubility with amine boranes. The DES was synthesized by combining the Hydrogen Bond Acceptor (HBA), namely 1-Butyl-3-methylimidazolium methanesulfonate and Imidazole as Hydrogen Bond Donor (HBD) at a molar ratio of 1:2 and T = 70 °C. The formation of DES was confirmed by recording the NMR spectra. Further, the thermal dehydrogenation study was performed at a vacuum of 4 × 10?2 mbar (gauge pressure) of AB/DES and EDAB/DES systems at 105 °C, where a hydrogen equivalent of 1.40 and 2.55 was produced, respectively. The residual samples were further analyzed through 1H NMR analysis for the reaction mechanism and to confirm the role of Ionic Liquid-based DES as catalyst cum solvent media. 相似文献
2.
Environmental concerns continue to pose the challenge to replace petroleum-based products with renewable ones completely or at least partially while maintaining comparable properties. Herein, rigid polyurethane (PU) foams were prepared using soy-based polyol for structural and thermal insulation applications. Cell size, density, thermal resistivity, and compression force deflection (CFD) values were evaluated and compared with that of petroleum-based PU foam Baydur 683. The roles of different additives, that is, catalyst, blowing agent, surfactants, and different functionalities of polyol on the properties of fabricated foam were also investigated. For this study, dibutyltin dilaurate was employed as catalyst and water as environment friendly blowing agent. Their competitive effect on density and cell size of the PU foams were evaluated. Five different silicone-based surfactants were employed to study the effect of surface tension on cell size of foam. It was also found that 5 g of surfactant per 100 g of polyol produced a foam with minimum surface tension and highest thermal resistivity (R value: 26.11 m2·K/W). However, CFD values were compromised for higher surfactant loading. Additionally, blending of 5 g of higher functionality soy-based polyol improved the CFD values to 328.19 kPa, which was comparable to that of petroleum-based foam Baydur 683. 相似文献
3.
4.
Bose Bimal K. Szczesny Paul M. Steigerwald Robert L. 《Industry Applications, IEEE Transactions on》1985,(5):1182-1191
Microcomputer-based control of a residential photovoltaic power conditioning system is described. The microcomputer is responsible for array current feedback control, maximum power tracking control, array safe zone steering control, phase-locked reference wave synthesis, sequencing control, and some diagnostics. The control functions are implemented using Intel 8751 single-chip microcomputer-based hardware and software. The controller has been tested in the laboratory with the prototype power conditioner and shows excellent performance. 相似文献
5.
Zhiping Lin Xu L. Bose N.K. 《IEEE transactions on circuits and systems. I, Regular papers》2008,55(1):445-461
6.
Properties determining choice of mother wavelet 总被引:3,自引:0,他引:3
Ahuja N. Lertrattanapanich S. Bose N.K. 《Vision, Image and Signal Processing, IEE Proceedings -》2005,152(5):659-664
Properties of wavelets with finite as well as infinite support are summarised to facilitate mother wavelet selection in a chosen application. The quantitative guidelines reduce dependence on trial-and-error schemes resorted to for selection and underscore the importance of such selection in any application of interest. In wavelet-based image sequence superresolution, studied during the last four years, the use of a B-spline mother wavelet is justified. 相似文献
7.
8.
GaTe is a III–VI semiconductor which has layered structure with large anisotropy in electrical properties. Growth of single
crystals by the Bridgman technique permitted the measurement of thermoelectric power in orthogonal directions from which the
anisotropy of hole effective masses were determined for the first time. From resistivity and Hall effect measurements the
carrier activation energies and scattering mechanisms between 10–300°K were found.
Study of the temperature dependence of conductivity revealed a variety of conduction mechanisms including weak localization
below 20°K, hopping conduction between 20–50 K and band conduction in and across the layer planes atT>70 K. Weak localization was confirmed through observation of negative magnetoresistance. TheI–V characteristics showed quantized behaviour due to tunneling across potential barriers, which may be due to stacking faults
between layer planes as observed by TEM studies. 相似文献
9.
Bose B.K. 《Proceedings of the IEEE. Institute of Electrical and Electronics Engineers》1994,82(8):1303-1323
Artificial intelligence (AI) tools, such as expert systems, fuzzy logic, and neural networks are expected to usher a new era in power electronics and motion control in the coming decades. Although these technologies have advanced significantly and have found wide applications, they have hardly touched the power electronics and machine drives area. The paper describes these AI tools and their application in the area of power electronics and motion control. The body of the paper is subdivided into three sections which describe, respectively, the principles and applications of expert systems, fuzzy logic, and neural networks. The theoretical portion of each topic is of direct relevance to the application of power electronics. The example applications in the paper are taken from the published literature 相似文献
10.
Tamal Bose M. -Q. Chen David A. Trautman 《Circuits, Systems, and Signal Processing》1994,13(5):601-614
A special class of complex biquad digital filters called orthogonal filters are investigated for stability under two's complement
quantization. A sufficient condition is derived for the asymptotic stability of the nonlinear filter. Bounds on the possible
limit cycles are also obtained. Using these bounds, any given filter can be tested for stability. The stability triangle is
then scanned using a dense grid, and each point on the grid is tested for stability/limit cycles. By this method, the stability
region given by the sufficient condition is extended. Regions within the linear stability triangle where various types of
limit cycles are possible are also identified. 相似文献