Thiol-Functionalized Covalent Organic Frameworks as Thermal History Indictor for Temperature and Time History Monitoring

Various products, including foods and pharmaceuticals, are sensitive to temperature fluctuations. Thus, temperature monitoring during production, transportation, and storage is critical. Facile indicators are required to monitor temperature conditions via color changes in real time. This study aimed to prepare and apply thiol-functionalized covalent organic frameworks (COFs) as a novel indicator for monitoring thermal history and temperature abuse. The COFs underwent obvious color changes from bright yellow to purple after exposure to different temperatures for varying durations. The reaction kinetics are analyzed under isothermal conditions, which reveal that the order of reaction rates is k_−20°C < k_4°C < k_20°C < k_35°C < k_55°C. The activation energy (E_a) of the COFs is calculated using the Arrhenius equation as 50.71 kJ moL⁻¹. The COFs are capable of sensitive color changes and offer a broad temperature tracking range, thereby demonstrating their application potential for the monitoring of temperature and time exposure history during production, transportation, and storage. This excellent performance thermal history indicator also shows promise for expanding the application field of COFs.     

Revealing Electrical-Poling-Induced Polarization Potential in Hybrid Perovskite Photodetectors

Despite recent rapid advances in metal halide perovskites for use in optoelectronics, the fundamental understanding of the electrical-poling-induced ion migration, accounting for many unusual attributes and thus performance in perovskite-based devices, remain comparatively elusive. Herein, the electrical-poling-promoted polarization potential is reported for rendering hybrid organic–inorganic perovskite photodetectors with high photocurrent and fast response time, displaying a tenfold enhancement in the photocurrent and a twofold decrease in the response time after an external electric field poling. First, a robust meniscus-assisted solution-printing strategy is employed to facilitate the oriented perovskite crystals over a large area. Subsequently, the electrical poling invokes the ion migration within perovskite crystals, thus inducing a polarization potential, as substantiated by the surface potential change assessed by Kelvin probe force microscopy. Such electrical-poling-induced polarization potential is responsible for the markedly enhanced photocurrent and largely shortened response time. This work presents new insights into the electrical-poling-triggered ion migration and, in turn, polarization potential as well as into the implication of the latter for optoelectronic devices with greater performance. As such, the utilization of ion-migration-produced polarization potential may represent an important endeavor toward a wide range of high-performance perovskite-based photodetectors, solar cells, transistors, scintillators, etc.     

一种大尺度二维直线度精密测量的新方法

本文提出了一种远距离、大范围二维直线度测量的新方法．该方法采用特殊设计的十字线准直激光器及线阵CCD，通过特殊的光学系统结构设计，能在0-20m距离内连续测量，直线度范围可达70mm，精度优于0．1mm，实际测量结果表明，该方法可适应野外作业环境。     

井喷失控预警的远距离自动调焦控制研究

井喷失控是石油及天然气钻井、完井过程可能出现的灾难性事故，给人类生命财产造成严重伤害，污染环境，破坏地下资源以及在城市火灾、森林火灾、环境变化等监测工作中常需要远距离目标监测，为了获得高清晰的实时图像数据，需要实时自动调焦。通过系统分析远距离相机离焦的原因，建立了一个实时调焦数学模型，并以此为基础研制了一种新的对应距离和温度变化的离焦补偿控制系统。该系统采用微型步进电机实现智能控制，通过监测目标距离确定监测相机的初始焦距，以及环境温度变化的实时反馈实现焦距的实时控制，使相机可以在－40～125 ℃范围内获得清晰、稳定的远距离图像。该系统适用于井喷失控石油及天然气火灾、城市火灾、森林火灾、环境变化等远距离目标的实时监测。     

Research on reversible effects and mechanism between the energy-absorbing and energy-reflecting states of chameleon-type building coatings

In the present paper, the reversible effects between energy-absorbing and energy-reflecting states of chameleon-type building coatings were studied through demonstration of the layers’ properties using infrared thermal imaging of the layers when exposed to a sunlamp or temperature measurements of the layers during exposure to sunlight at different ambient temperatures. The reversible transforming mechanism between the energy-absorbing and energy-reflecting states of the chameleon-type building coatings was investigated with IR, Raman and ¹H NMR spectroscopy. The infrared thermal image results showed that when reversibly thermochromic pigments were added to normal white building coatings, the chameleon-type building coatings could absorb energy from the sunlamp below a switching temperature of about 18°C. Absorption of energy from the sunlamp stopped automatically above the switching temperature. The results from exposure to solar radiation showed that when the temperature was below the switching temperature, the chameleon-type building coating could absorb almost the same amount of solar energy as an ordinary coloured coating, and when the temperature was above the switching temperature, the chameleon-type building coating could reflect more solar energy than the ordinary coloured coating. The above results showed that chameleon-type building coatings could contribute to a thermally comfortable building environment. The IR spectroscopy results showed that when the environmental temperature was below the switching temperature of 18°C, the lactone ring of the thermochromic pigment molecule would open and the band of C=O would almost disappear. Raman spectra indicated that the band of C–O in would move to the high wave number range. From ¹H NMR spectra, it could be found that there was some action between the hydrogen of the hydroxyl and the structure of . During the lactone ring opening, the electron in the non-bond orbital would transit to the higher orbital and it could elongate the conjugated bridge, which would produce visible absorption and hence produce an energy-absorbing effect. However, when the environmental temperature was above the switching temperature of 18°C, the lactone ring in the molecule of the thermochromic pigment would close, the transited electron would transit back to the original orbital, hence the visible absorption would disappear, which would make the coating have an energy-reflecting effect.     

亚毫米波系统探测距离分析

本文提出了距离的概率分布函数作为系统的性能指标，提高了系统评价的准确性。     

Use of Fiber Bragg Grating Sensors for Determination of a Simply Supported Rectangular Plane Plate Deformation

A measurement method has been developed to determine the full-field deformation of a simply supported plane plate under transverse load. The method utilizes strain information provided by a set of four fiber Bragg grating sensors mounted on the plate in a way that all sensors measure strains along one certain direction. The sensors were interrogated using a wavelength swept fiber laser. Utilizing the strain information and the first four terms of Navier solution of simply supported rectangular plate, the necessary parameters for determining the deflection could be computed. By substituting the values of x- and -y- coordinates of each position on the rectangle plate, the full-field deformation information can be obtained. Single-point loading tests were experimentally performed to verify the accuracy of the method.     

"信号调制法"研究电子诱导脱附--基本原理及误差分析

电子诱导脱附是近年来在真空科学与表面科学领域内的热门研究课题。它不仅作为研究和探讨原子激发过程以及电子能量传输机制的有效手段,而且已经逐渐成为获取表面和界面结构、状态等信息的有效方法。“信号调制法”是利用脉冲电流能量调制的电子探束取代传统的直流电子探束,并通过测量电子诱导脱附产物引起的压强变化量,来研究电子诱导脱附的新方法。本文系统地介绍了该方法的基本原理,并从理论上对该方法带来的测量误差进行了分析。