Unusual W-shaped Galvanic Cell Model of ISCC of α-brass in Neutral Mattsson''''s Solution

Intergranular stress corrosion cracking(ISCC) of α-brass in neutral Mattsson's solutionwas found to be controlled by an unusual"W"-shaped galvanic cell whose cathode is thegrain boundary oxide film (G.B.0. film) andsurface film and the anode is fresh metal atthe cracked tip on both sides of the G.B.0.film. Redox reactions involved in the cellhave been proposed here. According to thismdel, initidtion of ISCC is caused by therupturing of surface film along grain boundaries,thus forming a galvanic cell. Propagation ofISCC resulted from alternate advances of G.B.0.film and dissolution on both sides of G.B.0.film caused by the effect of electrochemicalreaction. This work developed an effective approachto investigate the embrittlement process atthe tip of the crack, by increasing the lengthof the embrittlement region through constantstrain test and distinguishing the morphologyand the nature of the corrosion products byoptical microscopy and scanning electronmicroscopy (SEH).