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1.
制备了一种工作温度约1 173 K的C/C复合材料抗氧化复合涂层,它由磷酸盐过渡层和陶瓷相阻挡层构成,通过与单一陶瓷相涂层的对比试验研究了它的抗氧化机理。涂覆有该复合涂层的C/C复合材料试样,在空气中1 173 K时氧化10 h的失重率为11.25%,氧化失重率为9.84×10~(-5)g/(cm~2·min),而且其氧化失重率随氧化时间延长而降低;4 h内经过30次从1 173 K至室温急冷急热循环后,失重率为6.38%,涂层基本完好,说明涂层在温度不超过1 173 K时具有良好的抗氧化性和抗热震性。该种涂层适合于中温下C/C复合材料的抗氧化保护。 相似文献
2.
将3组不同纤维体积分数的整体毡采用等温CVD进行沉积热解炭增密,结合CVD沉积过程中整体毡内气体传质数学模型,研究了整体毡的纤维体积分数对CVD增密过程的影响,研究结果表明:纤维体积低的整体毡沉积时增重率高;纤维体积分数高的整体毡容易获得较高密度的C/C复合材料;纤维体积分数超过35%的整体毡经过300 h的化学气相沉积,坯体的体积密度能达到1.52 g/cm~3。 相似文献
3.
By use of X-ray diffractometry and scanning electron microscope(SEM),the friction and wear results obtained from MM-1000 dynamometer tests of CVI pitch/resin C/C composites were analyzed.By investigating the factors that affected the friction and wear properties,such as matrix carbon,applcation environment,graphitization degree and brake pressure,etc,friction and wear mechanism of carbon materials were probed.The results indicate that pitch densified CVI initially treated composite is more graphitizable with its graphitization degree up 59 62%,and which results in uniform small debris easier to generate,more smooth friction curves with the coefficient of 0.3-0.4 and relatively higher wear and mass loss,compared with CVI/resin C/C composites.It was further proved by SEM observation that tribological behavior of C/C composite was system dependent.Factors determining the friction and wear properties such as the size of debris and its influence on friction and wear,brake pressure,graphization degree and debris bilm formation interacted and affected each other.The friction and wear mechanism of C/C composites under different high temperature treatments needs further research. 相似文献
4.
采用炭纤维和陶瓷粉末混编技术将HfC粉引入到炭纤维预制体中,制备了含有HfC超高温陶瓷粉末的炭纤维预制体;随后采用化学气相渗透(CVI)和先驱体浸渍裂解工艺(PIP)制备了密度高达1.94 g/cm^(3)的C/C-SiC-HfC复合材料,分析了复合材料的微观结构及力学性能。结果表明,制备的复合材料主要由C、SiC及HfC等物相组成,复合材料的平均弯曲强度达到了78.3 MPa,平均压缩强度为127.9 MPa;断裂过程中,断口处出现明显的裂纹扩展、纤维拔出及脱粘现象,从而使得材料呈现出一定的假塑性断裂特征。 相似文献
5.
Carbon spheres with size of 50–300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform
as reactants in a sealed autoclave. The morphologies and microstructures of carbon spheres before and after high temperature
treatment (HTT) were characterized by X-ray diffractometry (XRD), scanning electronic microscopy (SEM), energy diffraction
spectroscopy (EDS), and transmission electron microscopy (TEM). The formation mechanism of carbon spheres was discussed. The
results indicate that the carbon spheres convert to hollow polyhedron through HTT. Carbon spheres are composed of entangled
and curve graphitic layers with short range order similar to cotton structure, and carbon polyhedron with dimension of 50–250
nm and shell thickness of 15–30 nm. The change of solid spheres to hollow polyhedron with branches gives a new evidence for
formation mechanism of hollow carbon spheres. 相似文献
6.
C/C-SiC composites with SiC island distribution were prepared via a new processing route. The fabrication process mainly included
silicon infiltration by ultrasonic vibration, chemical vapor deposition (CVD), siliconizing, liquid phase impregnation and
carbonization. The wear and friction properties were tested by an MM-1000 wet friction machine. The results show that SiC
phases are mainly distributed between carbon fibers and pyrocarbons as well as among the pryocarbons. The dynamic friction
coefficient of the composites decreases gradually from 0.126 to 0.088 with the increase of the surface pressure from 0.5 to
2.5 MPa at the same rotary speed. Furthermore, under the constant surface pressure, the dynamic friction coefficient increases
from 0.114 to 0.126 with the increase of the rotary speed from 1 500 to 2 500 r/min. However, the coefficient decreases to
0.104 when the rotary speed exceeds 4 500 r/min. During the friction process, the friction coefficient of C/C-SiC composite
is between 0.088 and 0.126, and the wear value is zero after 300 times brake testing.
Foundation item: Project(2006CB600901) supported by the Major State Basic Research and Development Program of China; Project(0991015) supported
by Guangxi Science Found, China; Project(200808MS083) supported by Guangxi Education Department Found 相似文献
7.
8.
本文研究了烧结助剂Ni对C-B_4C-SiC复合材料显微结构与性能的影响.X射线衍射表明Ni在烧结温度下与SiC,B_4C人发生反应在晶界生成Ni_(4.6)Si_2B,并产生液相,有效地促进了C-B_4C-SiC复合材料的烧结,抑制了晶粒的长大,使复合材料密度与强度大幅度地增加,电阻率下降;同时Ni_(4.6)Si_2B在氧化时生成致密的2NiO·B_2O_3,包裹了易氧化的B_4C和C,有效地防止了复合材料的氧化,从而大大提高了制品的抗氧化性能. 相似文献
9.
Mixture of green petroleum coke, B4 C and SiC together with short carbon fiber were employed as starting materials, the mixture was press formed without any binder after grinding, dense and homogeneous binderless SiC-B4 C-C(carbon/ceramic) composites were then obtained after sintering. Composites thus prepared possess excellent anti-oxidation property, that is, mass loss less than IG within the temperature range from 900 to 1 100 ℃ for 10 h. Anti-oxidation mechanism was also discussed from the viewpoint of thermodynamics, excellent anti-oxidation property of materials thus prepared can be discribed to 1) solid SiO2 formed from SiC, which restrains the filtering of oxygen and simultaneously, its volume expansion brought about by the reaction takes roles both walling up the original pores and making the material more compact; 2) liquid B2O3 from the reaction of B4C not only makes the combination with C, B4 C and SiC tighter through forming solid solution, but also effect of reaction SiC(s)+2CO(g) =SiO2 (s)+3C(s) is an expansive process, which improves the microstructure of the material. 相似文献
10.
利用浸渍炉内残留或废弃的呋喃树脂,采用温压成形技术制备高电阻率炭材料。研究了粘结剂质量分数对材料性能(密度、电阻率、石墨化度)的影响,用扫描电镜观察了材料断口的微观形貌。结果表明,采用30%的酚醛树脂做粘结剂时,材料的综合性能最优,其平均密度为1.47g.cm-3,电阻率为224μΩ.m;制品中加入粘结剂时,石墨化度明显增加,为37.5%;试样断口扫描电镜照片表明粘结剂的质量分数为30%时,材料致密,孔隙细小且分布均匀,没有明显裂纹。 相似文献