Soluble and conductive polypyrrole copolymers containing silicone tegomers

Soluble and processable conductive copolymers of silicone tegomers and pyrrole were developed. This was easily accomplished by the oxidative polymerization of pyrrole monomer by Ce(IV) salt in the presence of silicone tegomers with hydroxyl chain ends. The resulting copolymers were soluble in dimethylformamide. The products were characterized by Fourier transform infrared, ¹H‐NMR, and four‐point probe conductivity, and their surface properties were investigated with contact‐angle measurements. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2896–2901, 2003     

Soft handoff algorithms for CDMA cellular networks

This paper discusses the design of soft handoff algorithms for cellular communication systems. The handoff process is modeled as a hybrid system and handoff design is cast as an optimization problem based on such a model. Performance is evaluated in terms of call quality, average number of active base stations, average number of active set updates, and average amount of interference. A soft handoff algorithm, which achieves a tradeoff between these performance criteria, is obtained using principles of dynamic programming. One key feature of the algorithm is that it incorporates the effects of mobility and shadow fading in the handoff decision. Different diversity combining schemes are considered including selective combining, equal gain combining (EGC), and various optimized combining (OC) methods in the soft handoff mode. For EGC and OC, Wilkinson's and Schwartz and Yeh's methods are used to compute the statistics for the power sum of the signals. Simulation results indicate that the performance of the handoff algorithm is a function of the different combining schemes and of the different methods used to compute the statistics of the power sum. Moreover, it is observed that interference cancellation is important in order for the algorithm to be viable for cellular systems which experience interference due to using nonorthogonal multiple access.     

Automatic detection of learning styles for an e-learning system

A desirable characteristic for an e-learning system is to provide the learner the most appropriate information based on his requirements and preferences. This can be achieved by capturing and utilizing the learner model. Learner models can be extracted based on personality factors like learning styles, behavioral factors like user’s browsing history and knowledge factors like user’s prior knowledge. In this paper, we address the problem of extracting the learner model based on Felder–Silverman learning style model. The target learners in this problem are the ones studying basic science. Using NBTree classification algorithm in conjunction with Binary Relevance classifier, the learners are classified based on their interests. Then, learners’ learning styles are detected using these classification results. Experimental results are also conducted to evaluate the performance of the proposed automated learner modeling approach. The results show that the match ratio between the obtained learner’s learning style using the proposed learner model and those obtained by the questionnaires traditionally used for learning style assessment is consistent for most of the dimensions of Felder–Silverman learning style.     

A variational approach to problems in calibration of multiple cameras

This paper addresses the problem of calibrating camera parameters using variational methods. One problem addressed is the severe lens distortion in low-cost cameras. For many computer vision algorithms aiming at reconstructing reliable representations of 3D scenes, the camera distortion effects will lead to inaccurate 3D reconstructions and geometrical measurements if not accounted for. A second problem is the color calibration problem caused by variations in camera responses that result in different color measurements and affects the algorithms that depend on these measurements. We also address the extrinsic camera calibration that estimates relative poses and orientations of multiple cameras in the system and the intrinsic camera calibration that estimates focal lengths and the skew parameters of the cameras. To address these calibration problems, we present multiview stereo techniques based on variational methods that utilize partial and ordinary differential equations. Our approach can also be considered as a coordinated refinement of camera calibration parameters. To reduce computational complexity of such algorithms, we utilize prior knowledge on the calibration object, making a piecewise smooth surface assumption, and evolve the pose, orientation, and scale parameters of such a 3D model object without requiring a 2D feature extraction from camera views. We derive the evolution equations for the distortion coefficients, the color calibration parameters, the extrinsic and intrinsic parameters of the cameras, and present experimental results.     

Microbial profile and bacterial characterisation of naturally debittered Hurma olives compared to non‐debittered Erkence variety during ripening period

Naturally debittered Hurma olive is grown in a specific area in Karaburun peninsula in Turkey. It is characterised by its sweet taste and it differs from other varieties by losing its bitterness caused by phenolic compounds during its maturation period on the tree. Therefore, Hurma olive does not require any further debittering process to be served as table olive. This study was particularly interested in the comparison of the microbial profile of Hurma olive during its 8 weeks of maturation period in two subsequent harvest years and Erkence (not naturally debittered) olive. In addition, main bacterial profile of both Hurma and Erkence olives were isolated and identified. Aerobic mesophilic microorganism (AMM), lactic acid bacteria (LAB), Enterobacteriaceae, Pseudomonadaceae, Staphylococci, Micrococcaceae, yeasts and moulds (Y&Ms) were detected (counted and isolated) in the olive drupes during the maturation period. Isolated bacteria were identified as different spp. of Bacillaceae, Enterobacteriaceae, Micrococcoceae and Pseudomonadaceae.     

Synthesis and application of phenylcarbamodithioate compound for steel protection

Phenyldithiocarbamate compound has been synthesized and studied as corrosion inhibitor for steel. Dithiocarbamate (DTC) compounds with linear alkyl groups are good inhibitors, but their stability is quite low in acidic solutions. It should be noted that long-term stability is important for practical applications, in order to avoid excess use of chemicals. So, we have synthesized phenyl substituted DTC which offers strong inhibition efficiency and extra stability. This new inhibitor is chemically adsorbed on steel through its DTC group, while the aromatic ring provides extra stability and long-term efficiency. For the assessment of corrosion kinetics, we have utilized potentiodynamic and ac impedance studies; also solution assay analysis was realized with atomic absorption spectroscopy. It was revealed that inhibitor exhibits remarkably high efficiency, even under elevated temperature conditions. At 55 °C temperature conditions, i_corr value decreased from 5050 to 154 μA cm^?2, with the addition of 500 ppm inhibitor. The long-term stability of inhibitor was also tested and 85.93% efficiency was obtained after three days of exposure period for 500 ppm concentration.     

Modification of cyclohexanone-formaldehyde-resin

The reactions of cyclohexanone-formaldehyde-resin via its hydroxy and carbonyl functional groups with a number of different reagents such as acetic anhydride, benzoyl chloride, hydroxylamine, semicarbazide, and phenyl hydrazine were studied. Melting points, IR spectrums, and solubilities in various solvents of the products were determined.     

Usability Problem Reports for Comparative Studies: Consistency and Inspectability

ABSTRACT

This study explores issues of consistency and inspectability in usability test data analysis processes and reports. Problem reports resulting from usability tests performed by three professional usability labs in three different countries are compared. Each of the labs conducted a usability test on the same product, applying an agreed test protocol that was collaboratively developed by the labs. Each lab first analyzed their own findings as they always do in their regular professional practice. A few weeks later, they again analyzed their findings, but then everyone applied the same method (SlimDEVAN: a simplified version of DEVAN, a method developed for facilitating comparison of findings from usability tests in an academic setting). It was found that levels of agreement between labs did not improve when they all used SlimDEVAN, suggesting that there was inherent subjectivity in their analyses. It was found that consistency of single analyst teams varied considerably and that a method like SlimDEVAN can help in making the analysis process and findings more inspectable. Inspectability is helpful in comparative studies based on identified usability problems because it allows for tracing back findings to original observations as well as for laying bare the subjective parts of the data analysis.     

Variations on optimal and suboptimal handoff control for wirelesscommunication systems

The design of handoff algorithms for cellular communication systems based on signal-strength measurements is addressed. The system is modeled using a hybrid framework: a mixture of continuous state and discrete event systems. The handoff problem is formulated as an optimization problem to control the switchings within the discrete event system. Performance is evaluated as a function of the expected number of handoffs, the expected handoff delay, and the expected number of signal degradations. A signal degradation occurs when the signal level falls below a threshold. The cost of handoff delay is explicitly specified, in contrast to prior work. Various optimization problems are posed to trade off between these quantities. Based on the optimal solutions which are obtained through dynamic programming, suboptimal versions are proposed for ease of implementation. The performance of the suboptimal algorithm which trades off between the expected number of handoffs and the expected number of signal degradations is improved through the use of signal averaging; however, this algorithm suffers from excessive handoff delay. Therefore, the tradeoff between handoff delay and number of handoffs is considered. The corresponding suboptimal algorithm provides nearly one handoff and almost no delay, which is ideal if call quality is also good. Finally, an algorithm which is a combination of the two previous algorithms is explored