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排序方式: 共有253条查询结果,搜索用时 15 毫秒
1.
Katja F. Hellendahl Felix Kaspar Dr. Xinrui Zhou Zhaoyi Yang Prof. Dr. Zhen Huang Prof. Dr. Peter Neubauer Dr. Anke Kurreck 《Chembiochem : a European journal of chemical biology》2021,22(11):2002-2009
Selenium-modified nucleosides are powerful tools to study the structure and function of nucleic acids and their protein interactions. The widespread application of 2-selenopyrimidine nucleosides is currently limited by low yields in established synthetic routes. Herein, we describe the optimization of the synthesis of 2-Se-uridine and 2-Se-thymidine derivatives by thermostable nucleoside phosphorylases in transglycosylation reactions using natural uridine or thymidine as sugar donors. Reactions were performed at 60 or 80 °C and at pH 9 under hypoxic conditions to improve the solubility and stability of the 2-Se-nucleobases in aqueous media. To optimize the conversion, the reaction equilibria in analytical transglycosylation reactions were studied. The equilibrium constants of phosphorolysis of the 2-Se-pyrimidines were between 5 and 10, and therefore differ by an order of magnitude from the equilibrium constants of any other known case. Hence, the thermodynamic properties of the target nucleosides are inherently unfavorable, and this complicates their synthesis significantly. A tenfold excess of sugar donor was needed to achieve 40−48 % conversion to the target nucleoside. Scale-up of the optimized conditions provided four Se-containing nucleosides in 6–40 % isolated yield, which compares favorably to established chemical routes. 相似文献
2.
The phase behavior and volumetric properties of polyethylene (PE) in solutions of n‐pentane and n‐pentane/CO2 were studied in a temperature (T) range of 370–440 K at pressures up to 60 MPa. Measurements were conducted with a variable‐volume view‐cell system equipped with optical sensors to monitor the changes in the transmitted light intensity as the P or the T of the system was changed. Lower‐critical‐solution‐temperature‐type behavior was observed for all of the liquid–liquid (L–L) phase boundaries, which shifted to higher pressures in solutions containing CO2. The solid–fluid (S–F) phase boundaries were investigated over a P range of 8–54 MPa and took place in a narrow T range, from 374 to 378 K in this P interval. The S–F phase boundary showed a unique feature in that the demixing temperatures showed both increasing and decreasing trends with P depending on the P range. This was observed in both the PE/n‐pentane and PE/n‐pentane/CO2 mixtures. The density of these solutions were measured as a function of P at selected temperatures or as a function of T at selected pressures that corresponded to the paths followed in approaching the phase boundaries (S–F or L–L) starting from a homogeneous one‐phase condition. The data showed a smooth variation of the overall mixture density along these paths. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 89: 2201–2209, 2003 相似文献
3.
Direct charging of thin slabs of low carbon steel (0.05%C) was investigated by using laboratory tests on a thin-slab-casting Simulator linked with the hot deformation Simulator (Wumsi). Starting with a different initial thickness of simulated thin slabs (45 down to 25 mm) the total strain ?∑ was varied. Hot deformation schedules (with and without roughing) with different finishing temperatures TF lead to some differences in the hot strip microstructure. Nevertheless, after cold rolling and batch annealing, a rather uniform pancake-structure and a pronounced {111}-texture were achieved in the cold strip without any significant relation to the processing routs. The measurement of final mechanical properties proved that a good deep drawability of cold strip can be achieved with direct charging of thin slabs, well comparable to that after a conventional cold charging of thick slabs. 相似文献
4.
Radko Kaspar 《国际钢铁研究》2003,74(5):318-326
By using a thin slab casting simulator combined with the hot deformation simulator WUMSI, laboratory tests were performed to investigate the microstructure processes and mechanical properties in the process of thin slab direct rolling (TSDR). The paper shows the possibilities to improve the initial as‐cast state of microstructure prior to hot rolling (microvoids, dendritic structure, austenite grain size, state of precipitation). The main part of the study is dedicated to the role of microalloying and sulphur for the austenite grain control and for the precipitation hardening in the final structure. On examples of selected low carbon steel grades the effect of the variation of the process parameters of hot rolling and cooling on the microstructure and mechanical properties is presented. 相似文献
5.
Forrer P Binz HK Stumpp MT Plückthun A 《Chembiochem : a European journal of chemical biology》2004,5(2):183-189
Consensus design is a valuable protein-engineering method that is based on statistical information derived from sequence alignments of homologous proteins. Recently, consensus design was adapted to repeat proteins. We discuss the potential of this novel repeat-based approach for the design of consensus repeat proteins and repeat protein libraries and summarize recent results from such experiments. 相似文献
6.
This study highlights how heuristic evaluation as a usability evaluation method can feed into current building design practice to conform to universal design principles. It provides a definition of universal usability that is applicable to an architectural design context. It takes the seven universal design principles as a set of heuristics and applies an iterative sequence of heuristic evaluation in a shopping mall, aiming to achieve a cost-effective evaluation process. The evaluation was composed of three consecutive sessions. First, five evaluators from different professions were interviewed regarding the construction drawings in terms of universal design principles. Then, each evaluator was asked to perform the predefined task scenarios. In subsequent interviews, the evaluators were asked to re-analyze the construction drawings. The results showed that heuristic evaluation could successfully integrate universal usability into current building design practice in two ways: (i) it promoted an iterative evaluation process combined with multi-sessions rather than relying on one evaluator and on one evaluation session to find the maximum number of usability problems, and (ii) it highlighted the necessity of an interdisciplinary ad hoc committee regarding the heuristic abilities of each profession. A multi-session and interdisciplinary heuristic evaluation method can save both the project budget and the required time, while ensuring a reduced error rate for the universal usage of the built environments. 相似文献
7.
Previous findings suggested that banner ads have little or no impact on perceptual behavior and memory performance in search tasks, but only in browsing paradigms. This assumption is not supported by the present eye-tracking study. It investigates whether task-related selective attention is disrupted depending on the animation intensity of banner ads when users are in a search mode as well as the impact of banner animation on perceptual and memory performance. 相似文献
8.
Graph edit distance is a powerful and flexible method for error-tolerant graph matching. Yet it can only be calculated for small graphs in practice due to its exponential time complexity when considering unconstrained graphs. In this paper we propose a quadratic time approximation of graph edit distance based on Hausdorff matching. In a series of experiments we analyze the performance of the proposed Hausdorff edit distance in the context of graph classification and compare it with a cubic time algorithm based on the assignment problem. Investigated applications include nearest neighbor classification of graphs representing letter drawings, fingerprints, and molecular compounds as well as hidden Markov model classification of vector space embedded graphs representing handwriting. In many cases, a substantial speedup is achieved with only a minor loss in accuracy or, in one case, even with a gain in accuracy. Overall, the proposed Hausdorff edit distance shows a promising potential in terms of flexibility, efficiency, and accuracy. 相似文献
9.
Advanced treatment of biologically treated medium density fiberboard (MDF) wastewater with Fenton and Fenton enhanced hydrodynamic cavitation process
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10.
Hydrogen is a promising alternative for current energy carriers. Compressed gas cylinders are the storage systems closest to the commercialization of hydrogen in vehicles. The safety factors in current standards are seen as restrictive for further growth and competitiveness of hydrogen infrastructure. A probabilistic approach can be employed in order to give a rational background to the safety factors. However, an acceptable probability of failure needs to be estimated before calculating the safety factors. The discussion of determining the acceptable probability must include the mass of hydrogen since this determines the consequences of an accident. It is concluded that an annual probability of failure of 10−7 would be appropriate for small pressure vessels containing a few kilograms of hydrogen. Larger pressure vessels of a few hundred kilograms or more should be designed for an annual probability 10−8. 相似文献