Compressive properties of pristine and SiC-Te-added MgB2 powders,green compacts and spark-plasma-sintered bulks

Pristine and (SiC+Te)-added MgB₂ powders, green and spark plasma sintered (SPS) compacts were investigated from the viewpoint of quasi-static and dynamic (Split-Hopkinson Pressure Bar, SHPB) compressive mechanical properties The amount of the additive (SiC+Te) was selected to be the optimum one for maximization of the superconducting functional parameters. Pristine and added MgB₂ show very similar compressive parameters (tan δ, fracture strength, Vickers hardness, others) and fragment size in the SHPB test. However, for the bulk SPSed samples the ratio of intergranular to transgranular fracturing changes, the first one being stronger in the added sample. This is reflected in the quasi-static K_IC that is higher for the added sample. Despite this result, sintered samples are brittle and have roughly similar fragmentation behavior as for brittle engineering ceramics. In the fragmentation process, the composite nature of our samples should be considered with a special focus on MgB₂ blocks (colonies) that show the major contribution to fracturing. The Glenn-Chudnovsky model of fracturing under dynamic load provides the closest values to our experimental fragment size data.     

Compatibility of polysaccharide/maleic copolymer blends. IV. Thermal behavior of hydroxypropyl cellulose‐containing blends

The compatibility of the hydroxypropyl cellulose (HPC) with maleic acid–vinyl acetate copolymer in the solid state was studied by thermogravimetry, thermo‐optical analysis, differential scanning calorimetry (DSC), Fourier transform infrared spectroscopy (FTIR), and optical microscopy. It was established that physical interactions are prevalent in blends with a high content of HPC, whereas chemical interactions predominate in blends with a medium and low content of HPC. By increasing the temperature, the thermochemical reactions are favored. Thermal properties are dependent on the mixing ratio of the components. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 88: 2585–2597, 2003     

Modeling of conductive particle behavior in insulating fluidsaffected by DC electric fields

Several electrostatic technologies, such as separation of granular mixtures, flocking, printing, or biological cell manipulation, are based on the accurate control of conductive particle motion in insulating gases or liquids by means of relatively high DC electric fields. This paper is aimed at characterizing the behavior of such particles by numerical modeling of two aspects: (1) particle motion under the action of electric field forces and (2) insulation breakdown triggered by mobile particles. The equations of particle motion were written by taking into account both gravitational and drag forces, as well as the rebound at particle impact with the electrodes. If the particles move in ionized air, their charge varies in time. In that case, the equation of particle charge should be added to the mathematical model. The output data of the programs for numerical simulation of particle behavior are in good agreement with the available experimental results. Particle movements were shown to be influenced by the intensity of the electric field, by the density of the space charge, by size and mass density of the particles, as well as by their coefficient of restitution at impact with the electrodes. The conclusions regarding the behavior of conductive particles in insulating fluids are useful for the development of improved electrostatic separation technologies; they are of particular interest to all manufacturers of high-voltage equipment     

Unipolar charging of insulating spheres in rectified AC electricfields

Nonfiltered rectifiers and pulsed power supplies are often used for the energization of the high-voltage electrodes in various electrostatic installations. The aim of this paper is to investigate the ionic charging of insulating particles in the pulsatory electric fields specific to such applications. In a first set of numerical simulations, the space charge was considered constant in time, which means that the ion generation is not related to the voltage drop between the electrodes. A second set of simulations was carried out using the assumption that the space charge is generated by the pulsed corona from one of the electrodes. The computed results, which were found in good agreement with the experimental data, show that the amount of charge acquired by a particle depends on the following factors: (1) particle transit time through the electric field zone; (2) space charge density; and (3) ratio between the corona onset voltage and the amplitude of the variable voltage applied to the electrodes. These factors are discussed in correlation with the operating parameters of roll-type corona-electrostatic separators, but the conclusions are valid for a wider group of industry applications     

Complexes With Biologically Active Ligands. Part 6 Ni(II) Coordination Compounds of Hydrazine and Heterocyclic Sulfonamides as Inhibitors of the Zinc Enzyme Carbonic Anhydrase

Ternary Ni(II) complexes of hydrazine and eight heterocyclic sulfonamides possessing carbonic anhydrase (CA) inhibitory properties, were prepared and characterized by elemental analysis, spectroscopic, magnetic, thermogravimetric, and conductimetric measurements. The complexes behave as strong inhibitors for two isozymes (I and II) of carbonic anhydrase.     

Pulsed laser deposition of silicon nitride thin films by laser ablation of a Si target in low pressure ammonia

We report the deposition of Si-N films by multipulse excimer laser ( = 308 nm, _FWHM = 30 ns) ablation of Si wafers placed in a slow flow of NH₃ in the pressure range (1 bar-1 mbar). The films are deposited on to a Si collector placed parallel to the Si target. We succeeded in depositing pure amorphous Si₃N₄ films at a pressure of 1 mbar of NH₃. The deposition rate reached a maximum value of 0.2–0.3 nm per pulse. At lower pressures, the deposited films consist of a fine mixture of three amorphous phases (amorphous stoichiometric silicon nitride, amorphous non-stoichiometric silicon nitride and amorphous silicon). The amorphous silicon is prevalent in films deposited at a pressure of several to several tens of bars. Droplets of polycrystalline -Si are sometimes visible on the film surface. The experimental evidence, is analysed with a view to elucidating the participation in the chemical synthesis of the three main stages of the process: the substance expulsion from the target by laser ablation, the transition through the gas of the expulsed substance and it's final impact on the collector. We conclude that silicon nitride is mostly synthesized during the impact on the collector of the flow of the ablated substance.     

Educational recommender systems and their application in lifelong learning

The almost unlimited access to educational information plethora came with a drawback: finding meaningful material is not a straightforward task anymore. Recommender algorithms can be used to make smart decisions in complex information systems and help the users decide upon useful materials; therefore, they become a promising area in academia and industry. The current paper presents a survey on educational recommender systems (RS): a set of analysis criteria are exposed and the technological specifications and challenges of each analysed system are provided, in the context of the main trends in the development of RS. Also, an ontology-based educational recommendation mechanism is proposed and its application to lifelong learning is highlighted, proving that RS can successfully support new learning paradigms.     

InSAR validation based on GNSS measurements in Bucharest

This research aims to complex validate radar displacement products over Bucharest based on Global Navigation Satellite System or GNSS. Validation was represented by the comparison of the recent TerraSAR-X (TSX) displacement results with field GNSS data. For this purpose, 24 and 27 high-resolution images acquired from the TSX satellite between 2011 and 2014 were processed by Permanent Scatterer Inteferometry (PSI) and Small BASeline Subset (SBAS) – interferometric techniques using synthetic aperture radar (SAR) images. The images were selected from a larger pool of SAR images, after consulting weather databases, which helped eliminate the images acquired under adverse weather conditions. GNSS locations were cross-checked on high-resolution optical images and 21 ground points (including three permanent stations) were selected. All these points were (1) characterized by high coherence on radar images; (2) were on the ground; (3) were situated in large vacant spaces; and (4) far away from radar obstacles such as trees. A major challenge in achieving the research goal was to overcome the lack of permanent stations at the ground level within the area of Bucharest. Instead of permanent stations, our team designed and installed forced centring systems that remained stable over time, eliminating the instalment errors of GNSS receivers. The line-of-site (LOS) components derived from GNSS data have been compared with those of the SAR scatterers closest to the GNSS markers (never coinciding). For each location, the vertical reading was projected in the LOS of the SAR sensor. These readings were compared with the displacement values determined at the locations of permanent scatterers (PSs) within 100 m from the GNSS nodes, by eliminating all scatterers on buildings. The comparison has shown a good agreement.     

AGAPIA v0.1: A Programming Language for Interactive Systems and Its Typing System

A model (consisting of rv-systems), a core programming language (for developing rv-programs), several specification and analysis techniques appropriate for modeling, programming and reasoning about interactive computing systems have been recently introduced by Stefanescu using register machines and space-time duality, see [Stefanescu, G. Interactive systems with registers and voices. Fundamenta Informaticae 73 (2006), 285–306. (Early draft, School of Computing, National University of Singapore, July 2004.)]. After that, Dragoi and Stefanescu have developed structured programming techniques for rv-systems and their verification, see, e.g., [Dragoi, C., and G. Stefanescu. Structured programming for interactive rv-systems. Institute of Mathematics of the Romanian Academy, IMAR Preprint 9/2006, Bucharest 2006. Dragoi, C., and G. Stefanescu. Towards a Hoare-like logic for structured rv-programs. Institute of Mathematics of the Romanian Academy, IMAR Preprint 10/2006, Bucharest, 2006. Dragoi, C., and G. Stefanescu. Implementation and verification of ring termination detection protocols using structured rv-programs. Annals of University of Bucharest, Mathematics-Informatics Series, 55 (2006), 129–138. Dragoi, C., and G. Stefanescu. Structured interactive programs with registers and voices and their verification. Draft, Bucharest, January 2007. Dragoi, C., and G. Stefanescu. On compiling structured interactive programs with registers and voices. In: “Proc. SOFSEM 2008,” 259–270. LNCS 4910, Springer, 2008.].In the present paper a kernel programming language AGAPIA v0.1 for interactive systems is introduced. The language contains definitions for complex spatial and temporal data, arithmetic and boolean expressions, modules, and while-programming statements with their temporal, spatial, and spatio-temporal versions. In AGAPIA v0.1 one can write programs for open processes located at various sites and having their temporal windows of adequate reaction to the environment. The main technical part of the paper describes a typing system for AGAPIA v0.1 programs.