Enrichment of piezoelectric properties in Nb5+doped (0.94) (Na0.5Bi0.5)TiO3–(0.06) BaTiO3 ceramics across morphotropic phase boundary region

Lead-free piezoelectric compounds (0.94)(Na_0.5Bi_0.5)TiO₃–(0.06) BaTiO₃ [NBBT (94/06)]?+?x wt.% Nb⁵⁺ (x?=?0%, 1%, 1.5%, 2%, and 2.5%) were synthesized by the solid-state reaction route and these powders were pelletized and sintered for dielectric and piezoelectric characterization. The phase coexistence Monoclinic (Cc)?+?Rhombohedral (R3c) was affirmed using X-ray Powder diffraction analysis. The structural properties like cell parameters and space group of the synthesized ceramics were investigated by the Rietveld refinement analysis. The surface morphology and grain size of the fractured ceramics were explored using SEM imaging technique. The dielectric properties for all the ratios of NBBT (94/06) ceramics were examined using LCR meter. The piezoelectric coefficients such as d₃₃ and g₃₃ of Nb-doped NBBT (94/06) ceramics were investigated. The saturation polarization (P_s) and remanent polarization (P_r) were exhibited from the P–E hysteresis loop analysis at room temperature. The appropriate addition of Nb⁵⁺ (x?=?1.5%) in NBBT (94/06) material demonstrates eminent dielectric constant and piezoelectric coefficient d₃₃ than other wt.% of Nb. The replacement of Ti⁴⁺ with higher radius cations Nb⁵⁺ in B-site of ABO₃ composes tilting of polar BO₆ octahedra resulting in rhombohedra distortion (RD) (90° ? α), in addition, the polarizability of ions and various valance states of B-site cations could be responsible for RD (90° ? α) ensuing relatively high dielectric constant and piezoelectricity.

     

Hydrated metal salt and Y3Fe5O12–Na0.5K0.5NbO3-incorporated P(VDF-HFP) films: a promising combination of materials with multiferroic and energy harvesting properties

Journal of Materials Science - The composite approach is very effective in developing multiferroic systems with remarkable magnetoelectric coupling coefficients. In this work, P(VDF-HFP)-based...     

Flower shaped frequency coded chipless RFID tag for low cost item tracking

A Flower Shaped Frequency Coded Chip-less RFID Tag with a fully printable and polarization-independent tag is discussed in this paper. The tag encodes a data capacity of 12 bits. The data is encoded and transmitted using the RF encoding particle technique in the spectral domain as a frequency signature of the resonators. The proposed 12-bit tag covers the spectral range from 8 to 11.5 GHz. The tag is designed and simulated using CST Microwave Studio software. The low-cost FR-4 substrate is used for simulation with the dielectric constant of 4.3 and tangent loss of 0.018. This compact tag occupies only 13 mm?×?13 mm area, hence can be printed cheaply on one side substrates.