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排序方式: 共有197条查询结果,搜索用时 312 毫秒
1.
Mani Balamurugan Hui‐Yun Jeong Venkata Surya Kumar Choutipalli Jung Sug Hong Hongmin Seo Natarajan Saravanan Jun Ho Jang Kang‐Gyu Lee Yoon Ho Lee Sang Won Im Venkatesan Subramanian Sun Hee Kim Ki Tae Nam 《Small (Weinheim an der Bergstrasse, Germany)》2020,16(25)
The electrochemical reduction of carbon dioxide (CO2) to hydrocarbons is a challenging task because of the issues in controlling the efficiency and selectivity of the products. Among the various transition metals, copper has attracted attention as it yields more reduced and C2 products even while using mononuclear copper center as catalysts. In addition, it is found that reversible formation of copper nanoparticle acts as the real catalytically active site for the conversion of CO2 to reduced products. Here, it is demonstrated that the dinuclear molecular copper complex immobilized over graphitized mesoporous carbon can act as catalysts for the conversion of CO2 to hydrocarbons (methane and ethylene) up to 60%. Interestingly, high selectivity toward C2 product (40% faradaic efficiency) is achieved by a molecular complex based hybrid material from CO2 in 0.1 m KCl. In addition, the role of local pH, porous structure, and carbon support in limiting the mass transport to achieve the highly reduced products is demonstrated. Although the spectroscopic analysis of the catalysts exhibits molecular nature of the complex after 2 h bulk electrolysis, morphological study reveals that the newly generated copper cluster is the real active site during the catalytic reactions. 相似文献
2.
Silicon - The promising capability of Triple Material Surrounding Gate Junctionless Tunnel FET (TMSG – JL – TFET) based 6 T SRAM structure is demonstrated by employing... 相似文献
3.
Treated glass fibers (RICS, 3 and 6 mm in length) were added at a concentrations of 10, 20, and 30 phr in natural rubber (NR), nitrile rubber (NBR), and ethylene–propylene–diene comonomer (EPDM) formulations, in both plain and carbon black mixes. The compounds were mixed in two‐roll mill and were evaluated for their resistance to hot‐air aging, abrasion, compression set, Goodrich heat buildup, De Mattia fatigue, and for NR mixes, adhesion in the tensile mode. The vulcanizates of the three rubbers showed resistance to hot‐air aging. Abrasion resistance was poor for NR, and it improved with carbon black addition in the presence of treated glass fiber in NBR. In carbon‐black‐added EPDM vulcanizates, the abrasion resistance and fatigue resistance were better. © 2003 Wiley Periodicals, Inc. J Appl Polym Sci 91: 1124–1135, 2004 相似文献
4.
S. Appavu alias Balamurugan Ramasamy Rajaram 《Expert systems with applications》2009,36(10):12113-12119
This paper deals with some improvements to rule induction algorithms in order to resolve the tie that appear in special cases during the rule generation procedure for specific training data sets. These improvements are demonstrated by experimental results on various data sets. The tie occurs in decision tree induction algorithm when the class prediction at a leaf node cannot be determined by majority voting. When there is a conflict in the leaf node, we need to find the source and the solution to the problem. In this paper, we propose to calculate the Influence factor for each attribute and an update procedure to the decision tree has been suggested to deal with the problem and provide subsequent rectification steps. 相似文献
5.
Tolerance specification is an important part of mechanical design. Design tolerances strongly influence the functional performance and manufacturing cost of a mechanical product. Tighter tolerances normally produce superior components, better performing mechanical systems and good assemblability with assured exchangeability at the assembly line. However, unnecessarily tight tolerances lead to excessive manufacturing costs for a given application. The balancing of performance and manufacturing cost through identification of optimal design tolerances is a major concern in modern design. Traditionally, design tolerances are specified based on the designer’s experience. Computer-aided (or software-based) tolerance synthesis and alternative manufacturing process selection programs allow a designer to verify the relations between all design tolerances to produce a consistent and feasible design. In this paper, a general new methodology using intelligent algorithms viz., Elitist Non-dominated Sorting Genetic Algorithm (NSGA-II) and Multi Objective Particle Swarm Optimization (MOPSO) for simultaneous optimal selection of design and manufacturing tolerances with alternative manufacturing process selection is presented. The problem has a multi-criterion character in which 3 objective functions, 3 constraints and 5 variables are considered. The average fitness factor method and normalized weighted objective functions method are separately used to select the best optimal solution from Pareto optimal fronts. Two multi-objective performance measures namely solution spread measure and ratio of non-dominated individuals are used to evaluate the strength of Pareto optimal fronts. Two more multi-objective performance measures namely optimiser overhead and algorithm effort are used to find the computational effort of NSGA-II and MOPSO algorithms. The Pareto optimal fronts and results obtained from various techniques are compared and analysed. 相似文献
6.
Balamurugan A Benhayoune H Kannan S Laquerriere P Michel J Balossier G Ferreira JM 《Microscopy research and technique》2008,71(9):684-688
The present study deals with the short-term physicochemical reactions at the interface between bioactive glass particles [55SiO(2)-20CaO-9P(2)O(5)-12Na(2)O-4MgO. mol%] and biological fluid (Dulbecco Modified Eagle's Medium (DMEM)). The physicochemical reactions within the interface are characterized by scanning transmission electron microscopy (TEM) (STEM) associated with Energy-dispersive X-ray spectroscopy (EDXS). Microanalysis of diffusible ions such as sodium, potassium, or oxygen requires a special care. In the present investigation the cryo-technique was adopted as a suitable tool for the specimen preparation and characterization. Cryosectioning is essential for preserving the native distribution of ions so that meaningful information about the local concentrations can be obtained by elemental microanalysis. The bioglass particles immersed in biological fluid for 24 h revealed five reaction stages: (i) dealkalization of the surface by cationic exchange (Na(+), Ca(2+) with H(+) or H(3)O(+)); (ii) loss of soluble silica in the form of Si(OH)(4) to the solution resulting from the breakdown of Si--O--Si bonds (iii); repolymerization of Si(OH)(4) leading to condensation of SiO(2)); (iv) migration of Ca(2+) and PO(4) (3-) to the surface through the SiO(2)-rich layer to form CaO-P(2)O(5) film; (v) crystallization of the amorphous CaO-P(2)O(5) by incorporating OH-- or CO(3) (2-) anions with the formation of three different surface layers on the bioactive glass periphery. The thickness of each layer is approximately 300 nm and from the inner part to the periphery they consist of Si--OH, which permits the diffusion of Ca(2+) and PO(4) (3-) ions and the formation of the middle Ca--P layer, and finally the outer layer composed of Na--O, which acts as an ion exchange layer between Na(+) ions and H(+) or H(3)O(+) from the solution. 相似文献
7.
Efficient Total Chemical Synthesis of 13C=18O Isotopomers of Human Insulin for Isotope‐Edited FTIR
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Dr. Balamurugan Dhayalan Dr. Ann Fitzpatrick Dr. Kalyaneswar Mandal Dr. Jonathan Whittaker Prof. Dr. Michael A. Weiss Prof. Dr. Andrei Tokmakoff Prof. Dr. Stephen B. H. Kent 《Chembiochem : a European journal of chemical biology》2016,17(5):415-420
Isotope‐edited two‐dimensional Fourier transform infrared spectroscopy (2 D FTIR) can potentially provide a unique probe of protein structure and dynamics. However, general methods for the site‐specific incorporation of stable 13C=18O labels into the polypeptide backbone of the protein molecule have not yet been established. Here we describe, as a prototype for the incorporation of specific arrays of isotope labels, the total chemical synthesis—via a key ester insulin intermediate—of 97 % enriched [(1‐13C=18O)PheB24] human insulin: stable‐isotope labeled at a single backbone amide carbonyl. The amino acid sequence as well as the positions of the disulfide bonds and the correctly folded structure were unambiguously confirmed by the X‐ray crystal structure of the synthetic protein molecule. In vitro assays of the isotope labeled [(1‐13C=18O)PheB24] human insulin showed that it had full insulin receptor binding activity. Linear and 2 D IR spectra revealed a distinct red‐shifted amide I carbonyl band peak at 1595 cm?1 resulting from the (1‐13C=18O)PheB24 backbone label. This work illustrates the utility of chemical synthesis to enable the application of advanced physical methods for the elucidation of the molecular basis of protein function. 相似文献
8.
A series of polymethacrylates containing triazole ring linked chalcone were designed and synthesized. These conjugated chalcone polymers are modulate under the light depending on the pendant substituents (–N(CH3)2, CH3, OCH3, Br, H & NO2). The steady-state absorption and emission spectroscopic techniques have been used to investigate intramolecular charge transfer (ICT) behaviour of the polymers. Absorption spectra in different organic solvents demonstrate the presence of ICT in polymer 5a. On the other hand, its excited singlet state exhibits high ICT characters as manifested by polarity of solvents. Interestingly, ICT emission maximum is strongly red shifted (53 nm). The emission intensities of fluorophore are compared with those measured after crosslinking, suggesting that the statically quenched fluorophores are entirely non-emissive. The emission decay of polymer 5a displays bi-exponentially with life time of 0.52 and 1.62 ns ascribed to presence of locally excited ICT state. Cyclic voltammogram demonstrates irreversible oxidation potential at 0.9 V indicates formation mono-radical cation. 相似文献
9.
Silicon - In this study, we present an ambipolar conduction and RF stability performance for a Germanium Source Dual Halo Dual Dielectric Triple Material Surrounding Gate Tunnel FET... 相似文献
10.
Babu N. Sujatha S. Narayanan S. Balamurugan V. 《Journal of Mechanical Science and Technology》2018,32(3):1357-1365
Journal of Mechanical Science and Technology - Achieving stability of unmanned, heavy tracked vehicles is challenging, especially under conditions of teleoperation because the remote operator... 相似文献