Influence of Electric Poling on Pb0.9Bi0.1Fe0.55Nb0.45O3 Multiferroic

This paper analyzes the influence of electric poling on structure, magnetism, and ferroelectricity by temperature-dependent Raman scattering (180 K–500 K), magnetic susceptibility, and ferroelectric measurements on Pb_0.9Bi_0.1Fe_0.55Nb_0.45O₃ (PBFNO) multiferroic. X-ray diffraction (XRD) has confirmed the monoclinic structure for PBFNO sample before and after poling. Rietveld refined XRD for poled and unpoled sample shows the influence of electric poling on Fe-O1, Fe-O2, Nb–O, and Bi-O modes with small variation in the lattice parameters. The unpoled PBFNO exhibits broad and overlapping 10 active modes at room temperature (100 to 1300 cm^?1) at 147, 212, 255, 431, 479, 561, 700, 795, 835, and 1112 cm^?1. In case of a poled sample, Pb–O and Nb–O-Nb modes become more active compared to the unpoled sample. Changes observed in the temperature-dependent magnetic measurements, i.e., ZFC/FC and M-H loop, evidence the poling effects on Fe–O and Nb–O active modes. By poling the improvement in ferroelectric domain, ordering occurs, and it is confirmed by P-E loops. The consequences of numerous investigations on electric poling of PBFNO will provide the foundation for future device development and design.

     

Influence of Al doping in LaCoO3 on structural,electrical and magnetic properties

We report investigations on polycrystalline LaCo_1?x Al _x O₃ (x = 0–0.9) bulk samples. The solid state synthesized samples showed a coexistence of rhombohedral and monoclinic phases in the intermediate concentrations (0.2 ≤ x ≤ 0.5) and pure rhombohedral phase otherwise. The observed effect of Al doping on dc transport has been analysed on the basis of small polaron hopping mechanism. The magnetisation results presented give evidence of weak ferromagnetism and anomalous temperature dependence of coercivity which we associate to the canting of the localised high-spin Co(III) and anti-symmetric exchange interactions at low temperatures.     

Pr（Ⅲ） and Nd（Ⅲ） Absorption Spectroscopic Probe to Investigate Interaction with Lysozyme （HEW）

Pr（ Ⅲ ） and Nd（ Ⅲ ） can be utilized as absorption spectroscopic probes to investigate the interaction of biomolecules like Lysozyme （HEW） with Ca（ Ⅱ ） in-vitro ; the most abundant metal ion in the human body system. The spectroscopic techniques involving comparative absorption, absorption difference, and quantitative intensity analysis using 4f-4f transitions are utilized for changes in the inner sphere coordination pattern of Pr（ Ⅲ ） and Nd（Ⅲ ） in solution as well as in solid state. The present study deals with an important biomolecule in human metabolism, that is, Lysozyme （HEW）. The absorption er-Condon the probab spectral parameters such as the oscillator strength （P）, the Judd-Ofelt （Tλ） intensity parameters, and the Slatinter electronic parameters are calculated using chi square methods. The obtained results are used to determine le geometry of the complex in the solution, the nature of the bond between Pr（Ⅲ）/Nd（Ⅲ） with lysozyme, and the inner sphere coordination environment of f-f transitions. The results obtained from various experimental conditions are utilized to investigate the coordination changes in the Pr（Ⅲ）/Nd（Ⅲ） complexes caused by different coordinating sites of lysozyme, normalized bite, denticity, the solvent nature, the coordination number, the nature of bond and other parameters to mimic the interaction of the Ca（ Ⅱ ） ion with such biomolecule.     

Assessing Flood Induced Land-Cover Changes Using Remote Sensing and Fuzzy Approach in Eastern Gujarat (India)

Natural hazards such as flooding can cause changes in land-cover. The present study deals with the changes in land-cover in three worst affected districts (Anand, Vadodara and Kheda) of Gujarat state in India due to severe flood during 2005. The Indian Remote Sensing (IRS) P6 Linear Imaging Self Scanning (LISS) III satellite imageries of pre- and post-flooding periods were used as sources of information for the study area. Three classification approaches (unsupervised ISODATA, supervised Maximum Likelihood Classifier, and fuzzy rule based) were used to extract flood induced land-cover information. Results obtained from the above classification approaches were compared. Soft computing technique such as fuzzy based image classification gave better separability amongst classes as compared to hard classification techniques. The accuracy assessment showed that the fuzzy approach can predict land-cover more accurately than traditional approach and also showed great potential for dealing with mapping of flood induced land-cover. Unsupervised classification results for the period October 2004 to October 2005 revealed decrease in inland water bodies (14.49%) and agricultural area (6.42%) while increase in remaining land-cover. During February 2005 to February 2006, all land-cover classes decreased except agricultural fallow and sparse vegetation. In case of supervised classification, decreasing trend was observed only in case of agricultural area (6.78%) during October 2004 to October 2005. Similarly, during February 2005 to February 2006, increase in coastal water bodies (0.73%) and sparse vegetation (1.7%) was observed where as decreasing trend was noticed in the remaining land-cover classes. In fuzzy based classification, only decrease in agricultural area (7.09%) was observed from October 2004 to October 2005, whereas during February 2005 to February 2006, decrease in area was exhibited in all land-cover classes except coastal water bodies and sparse vegetation. Change detection indicated interchange of areas between inland and coastal water bodies and decrease in agricultural area leading to increase in area of agricultural fallow and sparse vegetation.     

Delineation of Groundwater Potential Zones of Coastal Groundwater Basin Using Multi-Criteria Decision Making Technique

Delineation of groundwater potential zones (GWPZ) has been performed for a coastal groundwater basin of eastern India. The groundwater potential zone index (GWPZI) map is generated by using Analytic Hierarchy Process (AHP) from different influencing features, e.g., Land Use/Land Cover (LU/LC), soil (S), geomorphology (GM), hydrogeology (HG), surface geology (SG), recharge rate (RR), drainage density (DD), rainfall (RF), slope (Sl), surface water bodies (SW), lineament density (LD), and Normalized Difference Vegetative Index (NDVI). Recharge rate values are estimated from hydrological water balance model. Overlay weighted sum method is used to integrate all thematic feature maps to generate GWPZ map of the study area. Four zones have been identified for the coastal groundwater basin [very good: 36.39 % (273.53 km², good: 43.57 % (327.47 km²), moderate: 18.27 % (137.30 km²), and poor: 1.77 % (13.27 km²)]. Areas in north to south-west and south-east direction show very good GWPZ due to the presence of low drainage density. GWPZ map and well yield values show good agreement. Sensitivity analysis reveals that exclusion/absence of rainfall and lineament density increases the poor groundwater potential zones. Omission of hydrogeology, soils, surface geology, and NDVI show maximum increase in good GWPZ. Obtained GWPZ map can be utilized effectively for planning of sustainable agriculture. This analysis demonstrates the potential applicability of the methodology for a general coastal groundwater basin.     

Structural and magnetization studies on nanoparticles of Nd doped α-Fe2O3

It has been observed that, compared to bulk form, the nanocrystalline α-Fe₂O₃ is finding application in various areas. Magnetic properties of α-Fe₂O₃ are found to be influenced by the size of particles and are also sensitive to synthesis method employed for sample preparation. In the present work we have prepared a series of Nd doped α-Fe_2−xO₃ samples (x = 0.0–0.5) by combustion method, without using any fuel. The analysis of room temperature neutron diffraction patterns shows that all the compounds of the series form in the hematite (α-Fe₂O₃) structure, space group R−3c. Magnetization measurements show that there is a broad distribution of particle size in the samples. We find that the increase in the Nd content results in the dilution of magnetism of α-Fe₂O₃. From results we believe that inclusion of Nd in α-Fe₂O₃ drastically modifies the magnetic properties.     

Performance analysis of cooperative spectrum sensing in composite lognormal-Hoyt fading channel

Wireless Networks - The Nakagami-q (or Hoyt) fading model is known as an enriched fading model as it can characterize more severity of fading than Rayleigh fading model. In this paper, the...     

Effect of Particle Size on Magnetic Phase Coexistence in Nanocrystalline La0.4Bi0.3Sr0.3MnO3

Journal of Superconductivity and Novel Magnetism - Magnetic phase coexistence in the substituted perovskite compound, La0.4Bi0.3Sr0.3MnO3, is attributed to the spontaneous moment and a step-like...     

Magnetic and Dielectric Properties of <Emphasis Type="Italic">R</Emphasis><Subscript>2</Subscript>CuTiO<Subscript>6</Subscript> Compounds (<Emphasis Type="Italic">R</Emphasis>=Y,La, Pr and Nd)

Magnetic and dielectric properties of the double perovskite compounds of the type R ₂CuTiO₆ (RCTO, where R=Y, La, Pr and Nd) has been studied. Y₂CuTiO₆ (YCTO) crystallizes in a hexagonal unit cell, whereas the other three compounds form into orthorhombic structure. All four compounds show paramagnetic behavior down to 5 K. The dielectric studies show moderate dielectric constant (ε′) and very small dielectric loss (tan δ) for YCTO. The orthorhombic members of RCTO compounds exhibit moderate values of ε′ and tan δ. The dielectric properties are presented and discussed here in the light of the influence of structure and rare-earth ions on the physical properties of RCTO compounds.