Simulation study of eutrophication in Hiroshima Bay: Simulation of particulate and dissolved organic matter using cyclic transformation of carbon

A phytoplankton model, which includes a carbon cycle combined with a constant current obtained by the computation of tidal currents, was applied to the coastal region (Hiroshima Bay, Japan). The transformation rate constants for the carbon cycle were experimentally evaluated.The seasonal variations of particulate and dissolved organic matter by the simulation model were reasonably consistent with the field data. Carbon concentration increased by primary production in the upper layer was approx. 10 times that augmented by loading of carbon from land at the shore in summer. Sinking plays an important role in the elimination of particulate organic matter. On the other hand, horizontal advection and turbulent diffusion are important factors for the diminution of dissolved organic matter.     

Organic–silicate hybrid catalysts based on various defined structures for Knoevenagel condensation

Two types of organic–inorganic hybrid base catalysts are prepared. Organic-functionalized molecular sieves (OFMSs), particularly “amine-immobilized porous silicates”, are designed based on common idea to immobilize catalytic active sites on silicate surface. Silicate–organic composite materials (SOCMs), such as “ordered porous silicate–quaternary ammonium composite materials”, are the precursors of ordered porous silicates obtained during the synthesis. Both the OFMS and the SOCM are used as the catalysts for Knoevenagel condensation. Among the OFMSs, there is clear tendency that the use of molecular sieve with larger pore volume and/or surface area gives the product in higher yield. Aminopropylsilyl (AP)-functionalized mesoporous silicates such as AP-MCM-41 gives the product in high yield under mild conditions. No loss of activity is observed after repeated use for three times. The SOCMs are also active for the same reaction. The precursors of the mesoporous silicates are more active than those of microporous silicates. This material can be repeatedly used without significant loss of activity. High activity is not due to the leached species. The active sites of the SOCM catalysts are considered to be SiO⁻ moieties located on the pore-mouth. Activity of the SOCM increases when the reaction is carried out without solvent, whereas decrease in activity of the OFMS is observed in the solvent-free system.     

Crossover from 3D to 2D metallic conduction in Sr2RuO4

We have investigated the normal-state conduction of superconducting Sr₂RuO₄ (T_c 1K), which is isostructural to La_2–xSr_xCuO₄. The resistivity of single crystals shows a crossover at T_M130K from 3D metallic conduction at lower temperatures to 2D one at higher temperatures. Concerning the temperature dependence of the out-of-plane resistivity, we present a systematic interpretation based on competition between the life time of the quasiparticles and the time for the quasiparticles to travel between the adjacent RuO₂ planes.     

Investigation for Necessity of Dispersivity and Tortuosity in the Dusty Gas Model for a Binary Gas System in Soil

Diffusion, dispersion, and advection are important processes in multi-gas systems in soils. To date, both Fick's model and the Dusty Gas (DG) model have been used to model the movement of gases in these systems. Dispersion is included in the dispersion-advection equation with Fick's Model for the movement of gases in gas-phase of soil, yet the movement of gases in multi-component gas-soil systems is considered to be expressed more accurately by the DG model than by Fick's model. However to date, no study has investigated the necessity of considering dispersion in the Dusty Gas (DG) model. We carried out column experiments for nitrogen-methane, nitrogen-carbon dioxide, and carbon dioxide-methane binary gas systems in sandy soil, and also did simulations on the same systems using both Fick's model and the DG model. A comparison of the results of the column experiments with our simulations confirmed that there was no need to consider the dispersion in the advection-diffusion equations with the DG model when the velocity of gas was 0.05-0.4 cm/s in Toyoura sand. Furthermore, our experiments and simulations with the DG model showed that, rather than dispersion, tortuosity should be taken into account in application of the DG model to the above condition.     

ATP-regulated K+ channel and cytosolic Ca2+ mobilization in cultured rat spinal neurons

ATP activated the K+ channel responsible for outwardly rectifying currents via a P2Y purinoceptor linked to a pertussis toxin-insensitive G-protein in cultured rat spinal neurons. The evoked currents were inhibited by a selective protein kinase C inhibitor, GF109203X, whereas a phospholipase C inhibitor, neomycin had no effect. These indicate that the currents are regulated by phospholipase C-independent protein kinase C activation. In addition, ATP enhanced intracellular free Ca2+ concentration. The increase in intracellular free Ca2+ concentration was inhibited by a broad G-protein inhibitor, GDP beta S, but not affected by neomycin or an inositol 1,4,5-triphosphate receptor antagonist, heparin, suggesting that the cytosolic Ca2+ mobilization is regulated by a mechanism independent of a phospholipase C-mediated phosphatidylinositol signaling. These results, thus, demonstrate that ATP has dual actions on the coupled K+ channel and cytosolic Ca2+ release.     

Effect of Impurities on the Electronic Structure of Vortex Core Investigated by Microwave Surface Impedance Measurement

We investigated the microwave surface impedance in Zn doped YBa₂Cu₃O _y . For low Zn concentrations, crossover frequency _p and viscosity of vortex do not change significantly (at maximum, factor of 2). This is in sharp contrast to the dramatic change in the zero-field quasiparticle scattering time. The robust nature of viscosity on the impurity doping suggests that the quasiparticle scattering time in the vortex core is determined by a different mechanism from that outside the core.     

COMPUTATIONAL METHODS THROUGH GENETIC ALGORITHMS FOR OBTAINING STACKELBERG SOLUTIONS TO TWO-LEVEL MIXED ZERO-ONE PROGRAMMING PROBLEMS

In this paper, we develop computational methods for obtaining Stackelberg solutions to two-level mixed zero-one programming problems in which the decision maker at the upper level controls zero-one variables and the decision maker at the lower level controls real variables. To illustrate two-level mixed zero-one programming problems, we formulate a facility location and transportation problem as a two-level mixed zero-one programming problem. We develop computational methods through genetic algorithms for obtaining Stackelberg solutions. To demonstrate the feasibility and efficiency of the proposed methods, computational experiments are carried out and comparisons between the methods based on the branch-and-bound techniques and the proposed methods are provided.     

Increased QTc dispersion predicts lethal ventricular arrhythmias complicating coronary angioplasty

This study found that increased QT dispersion just before angioplasty is an useful marker to predict the risk for lethal ventricular arrhythmias during angioplasty. The fact that successful coronary revascularization decreased QT dispersion suggested that a part of increased QT dispersion is related to myocardial ischemia.