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排序方式: 共有96条查询结果,搜索用时 31 毫秒
1.
Tetsuya Ikuta Yuki Miyanami Hayato Iwamoto Takayoshi Shimura Kiyoshi Yasutake 《Science and Technology of Advanced Materials》2007,8(3):142-145
Selective epitaxial Si with a high arsenic concentration of 2.2×1019 atoms/cm3 was deposited at a high growth rate of 3.3 nm/min under atmospheric pressure. It was confirmed that this method had excellent selectivity and produced films having good crystalline quality, abrupt dopant profiles at the interfaces, and smooth surfaces. The growth mechanism is discussed in terms of the relationship between the effects of arsenic surface segregation and etching by hydrogen chloride. 相似文献
2.
Yasushi Takeuchi Kohjiro Yanagisawa Yuhsuke Tanaka Noriyuki Tsuruoka 《Korean Journal of Chemical Engineering》1997,14(5):377-381
Fixation of nitrogen oxides (NOx) in air onto granular activated carbon impregnated with chemicals was attempted to improve removal efficiency of NOx by activated carbon adsorption. Nitric oxide (NO) and nitrogen dioxide (NO2), were tried to remove by a flow test. Fixed-bed adsorption breakthrough curves were obtained when some kinds of carbon were
used. The amount adsorbed of NO2 changed with the amount and kinds of metallic salts impregnated. Chemicals-impregnated carbons were prepared from a commercial
activated carbon. Among obtained carbons, the one which showed the highest selectivity for NOx was chosen, and its performance with the change in humidity was determined. Removal mechanism of NO2 was estimated, and the carbon impregnated with potassium hydroxide was found to be superior to any other carbon tested. The
amount of the adsorbed NO and that produced by the reduction of NO2 were determined from the breakthrough curves. 相似文献
3.
Kazuo Fujiura Yasutake Ohishi Shigeki Sakaguchi Yukio Terunuma 《Journal of the American Ceramic Society》1989,72(8):1368-1372
A technique for synthesizing ultra-high-purity ZrF4 using chemical vapor deposition in a ZrBr4 –HF system is developed and a purification mechanism is clarified. The Fe concentration in ZrF4 is evaluated at less than 10 ppb based on analysis of the transmission loss spectrum of a fiber prepared using synthesized ZrF4 . Purification is achieved mainly in a sublimation process of ZrBr4 , and purification efficiency is determined by sublimation temperature and activity of impurities in ZrBr4 . The concentration of transition-metal impurities in ZrF4 , synthesized by chemical vapor deposition in the ZrBr4 –HF system, is expected to be less than 1 ppb. 相似文献
4.
Formation of Tetravalent Fe Ions in LaFeO3 Perovskite Through Mechanochemical Modification by Ball Milling 下载免费PDF全文
Tomoki Uchiyama Maiko Nishibori Hisahiro Einaga Yasutake Teraoka 《Journal of the American Ceramic Society》2015,98(4):1047-1051
Mechanochemical modification of previously synthesized LaFeO3 perovskite‐type oxide by a high‐energy ball milling was investigated to introduce Fe4+ ions or transform some Fe3+ into Fe4+ in LaFeO3. X‐ray absorption fine structure studies revealed that the formation of Fe4+ ions into LaFeO3 perovskite has been achieved at first time by ball milling at room temperature without any additives or replacement of La3+ ions by some divalent cations. The structural model of Fe4+ containing LaFeO3 could be described as with a modified perovskite having equal amounts of La and Fe vacancies, which is supported by a good correlation between the results of Fe K‐edge XANES spectra and O2‐TPD. The synthesis of Fe4+‐containing LaFeO3 perovskite by ball milling was able to produce the O2 adsorption capacity of nonsubstituted perovskite‐type oxide. 相似文献
5.
A Nanashima H Yamaguchi T Tsuji E Yamaguchi T Sawai T Yasutake T Nakagoe H Ayabe 《Canadian Metallurgical Quarterly》1998,12(12):1381-1385
BACKGROUND: Differences in the physiological stress response to pneumoperitoneal (PP) and gasless abdominal wall-lifting (AWL) procedures used for laparoscopic cholecystectomy have not been properly evaluated. METHODS: We compared leukocyte count, interleukin-6 (IL-6) levels, arterial blood gases, creatinine clearance, plasma renin activity, cardiothoracic ratio, and clinical outcome in 27 patients without systemic complications who underwent laparoscopic cholecystectomy, including 11 by AWL and 16 by PP. RESULTS: Transient leukocytosis and high IL-6 levels were observed at POD 1 (postoperative day) in both groups, but both values returned to baseline by POD 2. IL-6 levels correlated significantly with operation time (p < 0.01). Changes in blood gases, creatinine clearance, plasma renin activity, and cardiothoracic ratio were not different for the two groups. The clinical outcome was similar for both groups. CONCLUSIONS: Our results indicate that both PP and AWL are appropriate for patients without serious complications. 相似文献
6.
H. Kakiuchi H. Ohmi M. Harada H. Watanabe K. Yasutake 《Science and Technology of Advanced Materials》2007,8(3):137-141
The formation of silicon dioxide (SiO2) layers at low temperatures (150-400 °C) by atmospheric pressure plasma oxidation of Si(0 0 1) wafers have been studied using a gas mixture containing He and O2. A 150 MHz very high frequency (VHF) power supply was used to generate high-density atomic oxygen in the atmospheric pressure plasma. Oxidation rate, structure, and thickness and refractive index profiles of the oxidized layers were investigated by ellipsometry and infrared absorption spectroscopy. Atomic force microscopy was also employed to observe atomic-scale morphologies of the layer surface and wafer Si surface, after chemical removal of the oxidized layers. It was found that stoichiometric SiO2 layers were obtained at higher oxidation rates than conventional dry O2 thermal oxidation and radical oxidation processes, even at a very low substrate temperature of 150 °C. Although thickness variations were observed in the plasma region, the refractive index was independent of both substrate temperature and VHF power. In addition, the SiO2 surface and SiO2/Si interface roughnesses were comparable to those obtained in conventional dry oxidation at high temperatures. 相似文献
7.
Dr. Yoshiaki Yasutake Dr. Taiki Nishioka Dr. Noriko Imoto Prof. Tomohiro Tamura 《Chembiochem : a European journal of chemical biology》2013,14(17):2284-2291
Vitamin D3 hydroxylase (Vdh) from Pseudonocardia autotrophica is a cytochrome P450 monooxygenase that catalyzes the two‐step hydroxylation of vitamin D3 (VD3) to produce 25‐hydroxyvitamin D3 (25(OH)VD3) and 1α,25‐dihydroxyvitamin D3 (1α,25(OH)2VD3). These hydroxylated forms of VD3 are useful as pharmaceuticals for the treatment of conditions associated with VD3 deficiency and VD3 metabolic disorder. Herein, we describe the creation of a highly active T107A mutant of Vdh by engineering the putative ferredoxin‐binding site. Crystallographic and kinetic analyses indicate that the T107A mutation results in conformational change from an open to a closed state, thereby increasing the binding affinity with ferredoxin. We also report the efficient biocatalytic synthesis of 25(OH)VD3, a promising intermediate for the synthesis of various hydroxylated VD3 derivatives, by using nisin‐treated Rhodococcus erythropolis cells containing VdhT107A. The gene‐expression cassette encoding Bacillus megaterium glucose dehydrogenase‐IV was inserted into the R. erythropolis chromosome and expressed to avoid exhaustion of NADH in a cytoplasm during bioconversion. As a result, approximately 573 μg mL?1 25(OH)VD3 was successfully produced by a 2 h bioconversion. 相似文献
8.
9.
Masahiro Nagae Yasunori Koyama Seita Yasutake Tetsuo Yoshio Kohei Oda 《Journal of the American Ceramic Society》2006,89(11):3550-3553
The corrosion behavior of sialon ceramics was investigated in supercritical water at 450°C under 45 MPa for 2–50 h. α-sialon exhibited better corrosion resistance than β-sialon and α/β-sialon. Pitting corrosion with the formation of corrosion products was observed in the case of β-sialon and α/β-sialon. By contrast, the corrosion behavior of α-sialon was characterized by uniform corrosion with the formation of corrosion products. The degree of strength deterioration was strongly dependent on the corrosion morphology. The bending strength of α-sialon after corrosion for 30 h was about 90% of its initial strength, while the strength of β-sialon decreased to 65% of its original strength. 相似文献
10.
Yasutake Teraoka Hiroshi Ogawa Hiroshi Furukawa Shuichi Kagawa 《Catalysis Letters》1992,12(4):361-366
The coexistence of alkaline earth (Ca and Sr) and transition metal (Fe, Co and Ni) cations with Cu ions in ZSM-5 zeolite is effective in the promotion of the maximum activity and the expansion of the active temperature range for the reduction of nitric oxide with ethene in the presence of excess oxygen. 相似文献