Wavelength and Waveband Assignment for Ring Networks Based on Parallel Multi‐granularity Hierarchical OADMs

In this paper we study the optimization issues of ring networks employing novel parallel multi‐granularity hierarchical optical add‐drop multiplexers (OADMs). In particular, we attempt to minimize the number of control elements for the off‐line case. We present an integer linear programming formulation to obtain the lower bound in optimization, and propose an efficient heuristic algorithm called global bandwidth resource assignment that is suitable for the design of large‐scale OADM networks.     

菱镁制品低温早强促凝剂作用机理分析

菱镁胶凝材料在20℃以上的生产环境具有快硬的特点,但在环境温度低于15℃时,1d的硬化强度只有28d的10%,低于5℃时存在无法脱模的问题。为使菱镁制品能在较低温度下正常生产,试验研制出一种菱镁制品低温早强促凝剂。介绍该早强促凝剂的作用机理、技术性能、掺量特点及在低温生产环境下促进菱镁制品强度发展的作用。     

国产MB-86催化剂使用情况分析

抚顺引进的５００００ｔ／ｙ丙烯腈装置要改造到７００００ｔ／ｙ的生产能力，其中更换国产催化剂ＭＢ－８６是较为关键的一步，文章对此进行了总结与分析。     

Diffusion and sorption of benzene vapor through polybutadiene‐, polybutadiene/styrene‐, and polybutadiene/acrylonitrile‐based polyurethanes

A series of polyurethane (PU) films made from toluene diisocyanate (TDI), 1,4‐butanediol (BDO), and hydroxyl‐terminated polybutadiene (HTPB), hydroxyl terminated polybutadiene/styrene (HTBS), or hydroxyl terminated polybutadiene/acrylonitrile (HTBN) was synthesized by solution polymerization. The absorption of benzene vapor was found mainly in the soft phase. The equilibrium adsorption (M_∞) was reduced with increasing hard segment content for all the PUs. The values of M_∞ were in the sequence of HTBN‐PUs > HTBS‐PUs > HTPB‐PUs, which could be explained by the different interaction parameters between soft segments and benzene. The HTBN‐PU film showed the lowest degree of phase segregation and had more hard segments intermixed in the soft phase, restricting the movement of soft segments, and therefore resulted to non‐Fickian behavior, while the HTPB‐PU is antithetical. FTIR and atomic force microscopy were utilized to identify the hydrogen bonding behavior and morphology change of the PU films before and after the absorption of benzene vapor. The tensile strength of the HTBN‐PUs showed a greater decrease than that of HTBS‐PUs and HTPB‐PUs after absorbing benzene vapor. © 2004 Wiley Periodicals, Inc. J Appl Polym Sci 91: 2984–2991, 2004     

Preparation and characterization of multi-walled carbon nanotubes supported PtRu catalysts for proton exchange membrane fuel cells

A series of PtRu nanocomposites supported on H₂O₂-oxidized multi-walled carbon nanotubes (MWCNTs) were synthesized via two chemical reduction methods—one used aqueous formaldehyde (HCHO method) and the other used ethylene glycol (EG method) as the reducing agents. The effects of the solvents (water and ethylene glycol) and the surface composition of the MWCNTs on the deposition and the dispersion of the metal particles were investigated using N₂ adsorption, TEM, ICP-AES, FTIR and TPD. The wetting heats of the MWCNTs in corresponding solvents were also measured. The characterizations suggest that combination of the surface chemistry of the MWCNTs with the solvents decides the deposition and the dispersion of the metal nanoparticles. These nanocomposites were evaluated as proton exchange membrane fuel cell anode catalysts for oxidation of 50 ppm CO contaminated hydrogen and compared with a commercial PtRu/C catalyst. The data reveal superior performances for the nanocomposites prepared by the EG method to those by the HCHO method and even to that for the commercial analogue. Structure–performance relationship of the nanocomposites was also studied.     

混合溶剂在高分子膜中的传递模型

以单溶剂在高分子膜中的蠕变传递模型为基础,通过考虑溶剂间的耦合作用对溶剂在高分子膜中传递过程的影响,建立了混合溶剂在高分子膜中传递的蠕变模型.对模型参数进行了数值模拟研究,并使用该模型关联了吸收实验曲线.计算结果显示模型具有一定的预测功能.     

镀镍渗硼层的抗热震及抗高温氧化性能

研究了４５钢镀镍渗硼层的抗热震能力及抗高温氧化性能。研究结果表明，镀镍渗硼层的硼化物齿间存在γ－（Ｆｅ，Ｎｉ）固溶体，渗层表面含镍量较高，渗层致密、光滑、可明显改善单一渗硼层的抗热震及高温氧化性能。     

Quantification model of proper curvature for large‐sized curved TVs

We present a feasible modeling method to estimate the proper curvature for large‐sized curved TVs. We especially focused on two factors – preference and perceived distortion – to be considered to determine the proper curvature. The preference includes a number of advantages that people expect to fulfill the possibilities of a more immersive image and sense of realism from curved display. On the other hand, the perceived distortion means the side effects that people can notice uncomfortable feeling caused by the shape of a curved one. In order to find out how two factors would be different as a number of conditions like curvature, size, and viewing angle change, a series of subjective assessments were conducted. The evaluation results show that both the preference and perceived distortion vary with the conditions considerably. We performed the statistical analysis based on the results and proposed the quantification model of proper curvature, which has higher preference and less perceived distortion, for various‐sized curved TVs.     

博斯腾湖矿化度影响因子的敏感度分析

水位,吞吐流,风场从不同机理不同程度影响着博斯腾湖的矿化度分布。本文在定性分析博斯腾湖矿化度分布的影响因子的基础上,建立水流-盐度数学模型,通过采用单因子影响的分析的方法,进行矿化度分布对各影响因子的敏感度分析。研究表明:风场对博湖矿化度分布的影响最为明显,水位和吞吐流对博湖矿化度分布的影响均不明显。该研究对博湖的水环境综合治理有一定的指导意义。     

米力农互变异构的理论计算

采用B3LYP/6-311G(d,P)法,分析米力农分子的酮式与烯醇式构型的构象.再采用相同方法,在气相和水相中计算并考察烯醇式与酬式结构互变时,质子迁移的两种可能途径:(a)分子内质子迁移,(b)水助质子迁移.结果表明,后者所需的活化能较小,氢键在降低反应活化能方面起重要作用,PCM溶剂化对分子几何结构参数和反应活化能的影响较小.