Erratum to: Charge transfer in graphene/polymer interfaces for CO2 detection

Nano Research - The order of the authors in the original version of this article was unfortunately incorrect on the first page and the first page of the ESM. Instead of Myungwoo Son1, Yusin Pak1,...     

Synthesis of exfoliated graphite and its use as an electrode in supercapacitors

In this work, the effect of the synthesis conditions on exfoliated graphite and its properties was investigated. Exfoliated graphite was obtained via thermal reduction of graphite oxide at temperatures of 250–350°C. The influence of the synthesis conditions (temperature and heating rate) on the properties of exfoliated graphite (product yield, bulk density, specific surface area, specific capacitance and others) was determined via direct experimental design method. The ability to use exfoliated graphite in supercapacitors was determined on the basis of the specific capacitance data. The highest specific capacitance of exfoliated graphite was found to be 129 F/g.     

An optimization model for the container pre-marshalling problem

In most container yards around the world, containers are stacked high to utilize yard space more efficiently. In these yards, one major factor that affects their operational efficiency is the need to re-shuffle containers when accessing a container that is buried beneath other containers. One way to achieve higher loading efficiency is to pre-marshal the containers in such a way that it fits the loading sequence. In this research, we present a mathematical model for the container pre-marshalling problem. With respect to a given yard layout and a given sequence that containers are loaded onto a ship, the model yields a plan to re-position the export containers within the yard, so that no extra re-handles will be needed during the loading operation. The optimization goal is to minimize the number of container movements during pre-marshalling. The resulting model is an integer programming model composed of a multi-commodity flow problem and a set of side constraints. Several possible variations of the model as well as a solution heuristic are also discussed. Computation results are provided.     

Simultaneous fabrication of line defects-embedded periodic lattice by topographically assisted holographic lithography

We have demonstrated simultaneous fabrication of designed defects within a periodic structure. For rapid fabrication of periodic structures incorporating nanoscale line-defects at large area, topographically assisted holographic lithography (TAHL) technique, combining the strength of hologram lithography and phase-shift interference, was proposed. Hot-embossing method generated the photoresist patterns with vertical side walls which enabled phase-shift mask effect at the edge of patterns. Embossing temperature and relief height were crucial parameters for the successful TAHL process. Periodic holes with a diameter of 600 nm at a 1 μm-pitch incorporating 250 nm wide line-defects were obtained simultaneously.     

A packing algorithm for three-dimensional convex particles

Simulation of granular particles is an important tool in many fields. However, simulation of particles of complex shapes remains largely out of reach even in two-dimension. One of the major hurdles is the difficulty in representing particles in an efficient, flexible, and accurate manner. By representing particles as convex polyhedrons which are themselves the intersection of a set of half spaces, we develop a method that allows one to efficiently carry out key operations, including particle–particle and particle–container wall overlapping detection, precise identification of the overlapping region, particle shifting, particle rotation, and others. The simulation of packing 1,000 particles into a container takes only a few minutes with this approach. We further demonstrate the potential of this approach with a simulation that re-generates the “Brazil nut” phenomenon by mixing and shaking particles of two different sizes.     

Template-Free Preparation of a Mesopore-Rich Hierarchically Porous Carbon Monolith from a Thermally Rearrangeable Polyurea Network

A mesopore-rich, hierarchically porous carbon monolith was prepared by carbonizing a polyisocyanurate network derived by thermal rearrangement of a polyurea network. The initial polyurea network was synthesized by the cross-linking polymerization of tetrakis(4-aminophenyl)methane (TAPM) and hexamethylene diisocyanate (HDI) in the sol-forming condition, followed by precipitation into nanoparticulate solids in a nonsolvent. The powder was molded into a shape and then heated at 200–400 °C to obtain the porous carbon precursor composed of the rearranged network. The thermolysis of urea bonds to amine and isocyanate groups, the subsequent cyclization of isocyanates to isocyanurates, and the vaporization of volatiles caused sintering of the nanoparticles into a monolithic network with micro-, meso-, and macropores. The rearranged network was carbonized to obtain a carbon monolith. It was found that the rearranged network, with a high isocyanurate ratio, led to a porous carbon with a high mesopore ratio. The electrical conductivity of the resulting carbon monoliths exhibited a rapid response to carbon dioxide adsorption, indicating efficient gas transport through the hierarchical pore structure.