Lignin from Annual Plants as Raw Material Source for Flavors and Basic Chemicals

The enzymatic conversion of lignins, possibly in combination with electrochemical oxidation, makes aromatics such as syringol, guaiacol, vanillin and catechol available in the qualities required by the fragrance industry. The lignins were obtained by soda digestion from wheat straw and Miscanthus, characterized and then converted with laccases. The overall yield amounted up to 9 wt % with a product spectrum confined to four substances. Catechol was the major product, with a fraction of ≈75 %. It can easily be isolated by extraction with acetone.     

Effect of nitrogen and nickel on the stability of an Fe-12Cr-23Mn austenitic steel

The effect of nitrogen and nickel on the austenite stability and the structural changes as a result of cold work of an Fe-12Cr-23Mn alloy steel has been examined by transmission electron microscopy and X-ray analysis. Prestrain was performed either at room temperature or at 200° C. Final strain was carried out at liquid nitrogen temperature. The volume fraction of strain-induced martensite decreased by 40% and 12% due to the addition of 2.43% Ni and 0.11% N, respectively, despite whether prestrain was performed or not. The mechanisms are discussed in terms of the phase, stacking faults, dislocation cells and dislocation tangles induced by prestrain and final strain.     

Stability and work hardening of an Fe-12Cr-23Mn austenitic steel

The effect of pre-strain on the strain-induced martensitic transformation of an Fe-12Cr-23Mn austenitic steel has been investigated through transmission electron microscopy and X-ray analysis. Pre-strain was performed either at room temperature or at 200° C. Final strain was carried out at liquid-nitrogen temperature. The phase was shown to form on {1 1 1} planes of the austenite matrix predominantly by overlapping of stacking faults. The martensite transformation sequence was . Nucleation of the phase mainly occurred at intersections of bands. Austenite stability was shown to increase by pre-strain at 25° C or 200° C. Pre-strain at 200° C has a greater effect on austenite stability than does pre-strain at 25° C. The mechanism was discussed in terms of martensite transformation rate and various substructures introduced during straining. Work hardening was shown to depend on the degree of pre-strain and final strain. The correlation between work hardening and substructures introduced during straining was examined.     

Effect of pre-existing substructures on the fatigue properties of pure aluminium

Pure aluminium was thermomechanically treated (cold rolled to 80% reduction of thickness and annealed at 200° C for various lengths of time) in order to obtain different kinds of substructures. These aluminium specimens were then fatigued with a stress amplitude of 9×10³ psi or 90% of their ultimate tensile strength. The substructures of the specimens before and after fatigue were compared with each other and were then correlated to their fatigue property. The size and shape of substructure introduced by fatigue depend on the pre-existing substructure formed by thermomechanical treatment. The sub-boundaries of the fatigued specimen are not as well-defined as the pre-existing subgrain. The substructure size of the fatigued specimen increases initially with annealing time and then reaches a saturation value (2.32 m) when the annealing time is longer than 2 h. A peak value of fatigue life against the annealing time was found if the stress amplitude of fatigue is 90% of the ultimate tensile strength. The peak value also occurs at an annealing time of 2 h. The reason why the specimen annealed for 2 h possesses the optimum fatigue and property is discussed in terms of the substructures before and after fatigue.     

Smart metal sheets by direct functional integration of piezoceramic fibers in microformed structures

Microassembly of piezoceramic fibers in micro cavities at the surface of sheet metal is a novel approach for high volume production of smart adaptronic structural metal parts. In this paper a technology, manufacturing processes and characterization results of metal sheets with an active piezo-metal substructure based on directly integrated piezoceramic fibers are described. The processes include micro-milling of cavities in sheet metal, precision grinding of piezoceramic fibers, PECVD insulating layers with high dielectric strength, microassembly and force-locked joining by forming. In experiments, measurements of the surface roughness and geometric parameters of the piezoceramic fibers and micro cavities were performed. Further, the electrical properties of the insulation coatings were measured. The sensor function of the piezo-metal substructure was proven by a mechanical excitation resulting in a proportional measured sensor signal.     

Energy dissipation in laser-based free form heading: a numerical approach

Cold forming generally allows the fast generation of parts with very low tolerances. In addition, mechanical properties are improved, if work hardening materials are used. Transferring the cold forming process to micro range leads to a decrease in the maximum achievable upset ratio so that the forming process becomes inefficient. Therefore, a laser-based free form heading process has been developed to generate preforms which can be calibrated in a secondary cold forming step. The achievable upset ratios reach values of several hundreds instead of 2.1 which is common for single step mechanical upsetting. In this article, heat losses arising in the material accumulation process using laser-based free form heading are analyzed and discussed. For this purpose, the process is modeled within the framework of continuum mechanics and simulated by a finite element method. By using a numerical approach, a systematic study on heat losses is performed in order to identify the influence of radiation, heat transfer due to convection and thermal conduction during laser irradiation time. The simulation results, which are validated with experimental data, show that the radiation is the most important mechanism reducing the efficiency of the accumulation process.     

Porous Perovskite Fibers – Preparation by Wet Phase Inversion Spinning and Catalytic Activity

Porous perovskite (LaMnO₃) fibers were prepared by means of wet phase inversion spinning. The influence of different spinning procedures, slurry and coagulation bath composition on fiber shape and pore morphology was studied. The catalytic activity of the prepared fibers was tested for carbon monoxide oxidation as a model reaction in a differential recycle reactor. The results revealed that by suitable choice of process conditions porous catalytically active fibers can be prepared. Catalytic measurements confirmed that the catalytic fibers exhibit an open structure that allows full utilization of the catalytically active surface without intraparticle diffusional limitations.