MEA-AMP混合醇胺捕集烟气二氧化碳过程分析

本文根据焦化烟道气实际数据,应用流程模拟软件Aspen Plus模拟分析了MEA吸收剂以及MEA和空间位阻胺AMP混合吸收剂捕集烟道气中CO₂的吸收解吸效果。结果表明,混合胺浓度30 wt%（摩尔比MEA:AMP=1:1）吸收剂的吸收效果较好,为了进一步考察该种配比混合胺吸收剂的吸收、解吸特性,对其进行了灵敏度分析,并选取了25 wt%MEA为基准吸收剂,对比分析了进料温度、解吸塔再沸器热负荷和解吸塔压力对吸收解吸效果的影响,当吸收剂进料温度40℃时,单一MEA吸收剂吸收CO₂效率86.8%,混合胺的吸收率89.6%:2种吸收剂达到55%的解吸率,单一MEA吸收剂工艺再沸器热负荷为4500 kW,混合胺吸收剂工艺再沸器热负荷为3000 kW;当解吸塔压力1.5 bar时,单一MEA吸收剂对CO₂解吸率52.4%,混合胺吸收剂的解吸率55.8%,由对比结果得出混合胺（摩尔比MEA:AMP=1:1）的吸收、解吸效果均优于单一25 wt%MEA吸收剂。     

Cu-Containing Fe-Ni Corrosion-Resistant Alloys Designed by a Cluster-Based Stable Solid Solution Model

Copper is a good corrosion resisting element, but due to its immiscibility with Fe, it is only used as a minor-alloying element in stainless steels. In this work, we introduced a double-cluster structure model [CuNi₁₂][NiFe₁₂] _m for stable solid solutions in Cu-containing Fe-Ni corrosion-resistant invar alloys. Our model takes into account all of the enthalpies between the element pairs by assuming Fe-Ni and Ni-Cu nearest neighbors and by avoiding Fe-Cu ones, so that the ideally stabilized structures are described by mixing two cuboctahedral clusters in the fcc lattice, NiFe₁₂ and CuNi₁₂. Two alloy series were designed by varying the relative proportions of the two clusters and the Cu contents. It was proved that the alloys with Cu contents below those prescribed by this model could easily be solutionized and water-quenched to a monolithic fcc solid solution, and resultant alloys possessed good corrosion-resisting properties in 3.5 wt pct NaCl solution.     

双季戊四醇在3种混合溶剂中的固-液相平衡

采用动态平衡法,在293.15～332.80 K、常压下,测定了双季戊四醇(DPE)在水+(甲醇、乙醇、异丙醇)三种混合溶剂中的溶解度数据。结果表明：DPE在不同质量分数的水+(甲醇、乙醇、异丙醇)混合溶剂中的溶解度随体系温度升高而增大;同一温度下,其在所选取溶剂体系中的溶解度随着甲醇、乙醇或异丙醇质量分数的增大而先增大后减小。λh方程、两参数方程与Apelblat方程均能够对所测定的溶解度数据进行较好的关联;通过修正的van’t Hoff方程计算得到DPE在所选取溶剂体系中Δ_sol H ⁰、Δ_sol S ⁰和Δ_sol G ⁰均大于零,表明DPE在所选取溶剂体系中的溶解过程为吸热、熵增的非自发过程。     

以专业认证为抓手的化工专业人才培养模式研究与实践

为深入落实本科教育和人才培养的相关要求,实现高等教育内涵式发展,郑州大学化工专业以工程教育专业认证为抓手,践行以学生为中心的核心理念,以学生学习成果为导向,建立了“评价—反馈—改进”闭环和与用人单位协同持续改进的培养机制。教学过程中贯穿专业教育和课外教育,激发学生专业兴趣;坚持“以本为本”,培养卓越化工人才。教改在学生就业、竞赛、外部评价及专业建设等方面取得了较好的成效,提升了专业知名度及专业培养质量。     

基于温度场的层压机电加热板优化设计

针对目前太阳能层压机中电加热板存在表面温度分布均匀性差的问题,首先,在基于传热学理论的基础上,对电加热板结构布局进行合理简化,建立其温度分布数学模型;然后,以电加热板面最大温差为优化目标,通过MATLAB优化工具箱对数学模型求解,得到电加热板的结构优化参数;最后,在ANSYSWorkbench中,对优化后结构的温度分布进行模拟仿真。本文所研究的解决问题的思路为电加热板的结构设计奠定了理论基础,也为改善电加热板温度分布的均匀性提供了参考依据。     

充液箱位置对航天器耦合特性影响分析

分析了液体非线性晃动时充液箱位置对带弹性帆板充液航天器刚-液-弹之间耦合特性的影响.假设耦合系统绕系统质心做俯仰运动,首先采用已推导的刚-液-弹耦合系统俯仰运动非线性动力学方程组,得到系统固有频率,给出固有频率简单近似解析表达式,分析充液箱位置对系统各阶固有频率的影响.随后应用多尺度法对耦合系统液体一阶主共振进行解析分析,发现充液箱位置是决定幅频曲线软、硬特性转换点的重要参数.给定外激励力矩时,不同充液箱位置稳态解对应多解现象,并随着激励频率改变,稳态解幅值随充液箱位置的变化曲线发生分岔.     

Properties of wurtzite GaN MESFETs studied by two-dimensional full band Monte Carlo approach

The properties of a GaN Metal-Semiconductor Field Effect Transistor were studied based on two-dimensional full band Monte Carlo simulations. The dependences of the distributions of the electric potential, electron concentration, electric field, drift velocity, and average electron energy on the gate-source voltage (V_GS) and drain-source voltage (V_DS) were obtained, then the characteristics of the drain current (I_DS) versus the drain-source voltage (V_DS) and the transconductance (G_m) versus V_GS characteristics were determined. At and I_DS is 5.03 A/cm, which is higher value. The G_m−V_GS curve shows bell shaped and the maximum G_m is 112 ms/mm at and The current gain cutoff frequency (f_T) is 98 GHz at and      

抗噪声和工艺参数浮动的高性能多输入多米诺或门设计

A novel technique using a keeper with a simultaneous low supply voltage and low body voltage is proposed to improve the overall performance of high fan-in OR gates without modifying the physical dimensions of the keeper.Simulation results of a 16-input domino OR gate using 45 nm CMOS technology show that the proposed technique could trade off between a high power/speed efficient operation and the robustness to noise effectively.Also,a Monte Carlo analysis indicates that the proposed domino OR gate is more robust to parameter variation compared to a conventional domino OR gate.     

ZnO材料的电子输运特性

用全带Monte Carlo方法模拟了纤锌矿Zn O材料电子的稳态和瞬态输运特性.稳态输运特性包括稳态平均漂移速度-电场特性、电子平均能量-电场特性和在不同电场下电子按能量的分布.在平均漂移速度-电场特性中发现了微分负阻效应.Zn O的瞬态输运特性包括平均漂移速度-位移关系曲线、渡越时间-位移关系曲线等.在平均漂移速度-位移关系曲线中发现了过冲现象,这种现象是电子从低能谷到高能谷跃迁过程中的弛豫时间产生的.     

温度和工艺参数浮动下双阈值footed多米诺电路的漏电流特性

考虑到温度和工艺参数浮动的影响,对休眠双阈值footed多米诺电路的漏电流特性进行了系统的量化研究和比较,得到了不同温度下的最佳休眠状态.基于65和45nm BSIM4模型的HSPICE仿真表明：与业已提出的CHIL（时钟为高,输入均为低电平）状态和CHIH（时钟和输入均为高电平）状态相比,本文提出的CLIL（时钟和输入均为低电平）状态更有利于减小低温下电路的漏电流和高温下的多扇入电路的漏电流.而且,分析了工艺参数的浮动对双阈值footed多米诺电路的漏电流特性的影响,并给出了温度和工艺参数浮动下,双阈值footed多米诺电路漏电流最小的休眠状态.