Investigation on external stimuli engendered magnetic ordering in polycrystalline CaCu3Ti4O12 quadruple perovskite

The consequences of high energy mechanical milling, microwave-assisted heating and rapid thermal cooling on magnetic ordering in polycrystalline CaCu₃Ti₄O₁₂ cubic perovskite have been investigated by means of X-ray powder diffractometry (300?K), dc magnetization in field – cooled and zero – field cooled modes (H = 100?Oe and 1000?Oe, T?=?5–300?K) (M – T curves) and M – H loop characteristics (T?=?5?K and 300?K, H_max = 70?kOe). The M – T curves of unmilled and 16?h milled samples show pure antiferromagnetic and weak ferromagnetic ordering, respectively, 1?h and 6?h milled samples demonstrate the coexistence of both the phases while microwave-assisted and quenched samples exhibit classic antiferromagnetic transition and a low temperature paramagnetic–like contribution with different weights, well supported by the M – H loop characteristics. The observed transformations in the magnetic ordering are attributed to the ball-milling induced stress which curtails hybridization of empty Ti-3d orbitals with Cu-3d and O-2p orbitals and secondary phase formation. Oxygen vacancies associated with bound magnetic polarons originate ferromagnetism in the milled samples while unpaired electrons inhabited at the empty sites are the cause of paramagnetic centers. The low-temperature Curie – tail in M – T curve for quenched and microwave assisted samples is attributed to Ti³⁺ cations.     

Deep autoencoders for feature learning with embeddings for recommendations: a novel recommender system solution

Neural Computing and Applications - We propose “Deep Autoencoders for Feature Learning in Recommender Systems,” a novel discriminative model based on the incorporation of features from...     

Improved cellulase production by stable Clostridium cellulolyticum mutants

Methods for the production of mutants of the cellulase producer Clostridium cellulolyticum ATCC 35319 were examined using an agar plate screening technique. Spontaneous and UV light-induced mutants were isolated, some of which exhibited a high level of both endoglucanase and exoglucanase activities as assayed using CMC (carboxymethyl cellulose) and PNPCb (paranitrophenyi-β-cellobioside) respectively. The volumetric enzyme activities were up to 2.5 times those of the wild strain.     

Grafting of methyl methacrylate onto guar gum by hydrogen peroxide initiation

Graft copolymerization of methyl methacrylate (MMA) onto guar gum (GG) in aqueous slurry has been carried out using hydrogen peroxide (H₂O₂) as initiator. The copolymers were characterized by infrared spectroscopy. The grafting parameters like percent grafting, grafting efficiency, percent add-on, and the grafting frequency were determined, and the effect of reaction time, concentration of initiator, and [GG]/[MMA] ratios on the grafting parameters have been discussed. The decrease in % add-on at increasing concentration of H₂O₂ indicated enhancement in the rate of homopolymerization of methyl methacrylate.     

Registration techniques for using imperfect and partially calibrated devices in planar multi-projector displays

Multi-projector displays today are automatically registered, both geometrically and photometrically, using cameras. Existing registration techniques assume pre-calibrated projectors and cameras that are devoid of imperfections such as lens distortion. In practice, however, these devices are usually imperfect and uncalibrated. Registration of each of these devices is often more challenging than the multi-projector display registration itself. To make tiled projection-based displays accessible to a layman user we should allow the use of uncalibrated inexpensive devices that are prone to imperfections. In this paper, we make two important advances in this direction. First, we present a new geometric registration technique that can achieve geometric alignment {\em in the presence of severe projector lens distortion} using a relatively inexpensive low-resolution camera. This is achieved via a closed-form model that relates the projectors to cameras, in planar multi-projector displays, using rational Bezier patches. This enables us to geometrically calibrate a 3000 x 2500 resolution planar multi-projector display made of 3 x 3 array of nine severely distorted projectors using a low resolution (640 x 480) VGA camera. Second, we present a photometric self-calibration technique for a projector-camera pair. This allows us to photometrically calibrate the same display made of nine projectors using a photometrically uncalibrated camera. To the best of our knowledge, this is the first work that allows geometrically imperfect projectors and photometrically uncalibrated cameras in calibrating multi-projector displays.     

A Study on Reaction Influencing Factors in Carboxymethylation of Leucaena glauca Seed Gum

Sodiummonochloroacetate and sodiumhydroxide were employed under different conditions to prepare and optimize the carboxymethyl derivative of Leucaena glauca seed gum. The effects of concentration of reactants, reaction temperature and time have been interpreted in terms of degree of carboxymethylation as well as efficiency and rate of carboxymethylation reaction. The formation of the proposed derivative has also been supported by providing infra-red spectral characterization.     

Design and development of a machine vision system using artificial neural network-based algorithm for automated coal characterization

Coal is heterogeneous in nature,and thus the characterization of coal is essential before its use for a specific purpose.Thus,the current study aims to develop ...     

N,N-bis (2-hydroxyethyl) fatty amide as novel environmentally friendly crosslinking agent for acid functional acrylic copolymer resin

N,N-bis (2-hydroxyethyl) fatty amide (HAFA) derived from dehydrated castor oil (DCO) has been employed as a curing agent for a carboxylic acid functional acrylic resin (AAR). Coating compositions with a varying AAR/HAFA ratio have been prepared and their various film properties have been studied and compared with the conventional butylated melamine formaldehyde (MF) based systems. The study reveals that HAFA can be used successfully as a crosslinking agent for AAR in baking systems. In addition to other technical advantages, the use of HAFA is environmentally friendly as no toxic volatiles are evolved during curing reaction, unlike in MF-cured systems. Department of Industrial Chemistry, Vallabh Vidyanagar, Gujarat 388 120 India. Hyderabad, India.     

Flow simulation in Electro-Static-Precipitator (ESP) ducts with turning vanes

Flow simulation in inlet ducts along with several turning vanes used in electrostatic precipitator (ESP) are analysed to understand the flow pattern at its exit locations. The geometry of inlet duct has been extracted from the Plant Design Manufacturing System (PDMS) and refined with turning vanes placed at several locations. The domain of duct geometry around turning vanes are decomposed with several volumes and filled with hexahedral elements with the help of stat-of-art mesh generator - Hypermesh. The resulting computational grid has been used in TASCflow solver to predict its flow pattern in the duct. Simulation for the specified conditions predicts uneven flow distribution in the ESP inlet duct. Due to large flow recirculation and turbulent losses in the duct, non-uniform averaged mass flow rates are noticed at duct exit locations. Simulation results suggest that the improvement of flow distribution in the duct through optimization can be tried by placing more turning/splitter vanes in the inlet duct. In order to ensure that the results obtained from TASCflow are meaningful and in right direction, in the absence of measurement data, simulation was benchmarked with other industry standard commercial flow solvers. The observations made from these popular solvers confirm the findings obtained using the TASCflow solver. The analysis with multiple solvers indicates that Fluent provides quick results, while better visualization can be made using CFX solver. The Star-CD solver, which captures the turbulent losses accurately takes more time for convergence provides alternatives.