Relationships of tensile strength with crosslink density for the high-carbon black-filled EPDM compounds with various softeners

Equilibrium swelling and rheological tests were adopted to systematically investigate the effects of softener type and dosage on the crosslink densities. The results turned out that the chemical crosslink density could be distinguished from the physical crosslink density by comparing the results of equilibrium swelling and rheological tests. The liquid butadiene (LB) as a softener leads to the greatest reduction in crosslink density, followed by polyethylene wax (PW) and paraffinic oil (PO). The tensile strength decreases with increasing PO content while shows peak values with increase of LB and PW contents. The dependencies of chemical crosslink density on the aging time under 150°C are quite different for the three softeners, which can be expected from the double crosslinking networks consisting of small softener and large main crosslinking networks. Further investigation has been performed to correlate the tensile strength with chemical crosslink density of ethylene propylene diene monomer elastomer vulcanizates. Three different linear relationships can be obtained for the softeners independent of the aging time. It can now be expected from this study that the role of some new softeners in rubber compounds is not only confined to plasticization but also forms crosslinking networks in the peroxide-cured rubbers.     

Core–shell NTC materials with low thermal constant and high resistivity for wide-temperature thermistor ceramics

Core–shell structures have been proposed to improve the electrical properties of negative-temperature coefficient (NTC) thermistor ceramics. In this work, Al₂O₃-modified Co_1.5Mn_1.2Ni_0.3O₄ NTC thermistor ceramics with adjustable electrical properties were prepared through citrate-chelation followed by conventional sintering. Co_1.5Mn_1.2Ni_0.3O₄ powder was coated with a thin Al₂O₃ shell layer to form a core–shell structure. Resistivity (ρ) increased rapidly with increasing thickness of the Al₂O₃ layer, and the thermal constant (B) varied moderately between 3706 and 3846 K. In particular, Co_1.5Mn_1.2Ni_0.3O₄@Al₂O₃ ceramic with 0.08 wt% Al₂O₃ showed the increase of ρ double, and the change in its B was less than 140 K. The Co_1.5Mn_1.2Ni_0.3O₄@Al₂O₃ NTC ceramics showed high stability, and their grain size was relatively uniform due to the protection offered by the shell. The aging coefficient of the ceramic was less than 0.2% after aging for 500 hours at 125°C. Taken together, the results indicate that as-prepared Co_1.5Mn_1.2Ni_0.3O₄@Al₂O₃ NTC ceramics with a core–shell structure may be promising candidates for application as wide-temperature NTC thermistor ceramics.     

Se doped nickel-molybdenum bimetal sulfide with enhanced electrochemical activity for hydrogen evolution reaction

In this work, we synthesized Se doped MoS₂@Ni₃S₂ with nanosheets coated nanorods structure supported on Ni foam (MoNiSeS). Firstly, MoS₂@Ni₃S₂ (MoNiS) nanorods was synthesized by hydrothermal method. After selenization treatment, MoSe₂ successfully formed on the edge of MoS₂ nanosheets and particle Ni₃S₂ transformed into NiSe, in which MoSe₂ and NiSe acted as new phase in MoNiSeS. The obtained MoNiSeS only needs a low overpotential of 68 mV to reach the current density of 10 mA cm^?2, and has a low Tafel plots of 72.77 mV dec^?1 and good electrochemical durability, whose electrochemical activity is much better than that of MoNiS and NiSeS, implying the introduction of Mo and Se is beneficial to improve the electrocatalytic performance of NiS for HER. In addition, the proper amount of Mo source, which has an effect on the morphology of product, has also been investigated. For MoNiSeS, the typical nanosheets coated nanarods expose more active sites and the synergic effects is good to the improvement of the catalytic activity. Meanwhile, WNiSeS has also been prepared using the same method and the corresponding results show that the electrochemical activity of WNiSeS is much better than that of NiSeS, proving the universality of this strategy.     

风管摩擦阻力的直接计算方法

提出用高精度的反映密度、黏度和温度关系的经验公式和Colebrook公式计算风管摩擦阻力系数的方法。分析和算例表明，用该方法计算，计算结果比采用常用工程设计方法更为准确，为应用计算机进行风道设计提供了直接、简便的方法。     

关于沥青针入度指数

介绍了沥青针入度指数(PI)的由来和计算、使用意义、局限性和分析。     

大港油田关家堡地区不同含油层系气测解释方法探讨

大港油田关家堡地区油气藏特征复杂，不同含油层系油气显示特征不同，气测录井解释符合率相对较低。针对这一情况，通过分析关家堡地区明化镇组、馆陶组和沙河街组的地质和气测显示特征，结合试油结论，提出不同含油层系相应的气测录井解释方法——TR与Wh（湿度比）气测解释法和三角形图板法，归纳总结了全烃及组分在不同层系的变化规律。应用实例表明，效果较好，对于复杂油气藏多层系油气层的解释评价具有一定的借鉴作用。     

MPEG-4流媒体技术及其实现方法

详细地介绍了一种基于MPEG-4压缩的嵌入式网络流媒体采集、传输和控制应用系统的设计与实现技术。该嵌入式平台采用203 MHz的ARM920T内核处理器S3C2410B,嵌入式操作系统采用Linux操作系统,用户可在这个系统平台上进行自主软件开发。视频采集模块采用TI公司的TVP5145,视频压缩芯片采用硬压缩W IS GO7007B进行处理,将Y:Cb:Cr格式的视频流转换为MPEG-4编码。     

Abstract Implementation of Algebraic Specifications in a Temporal Logic Language

A formal technique for incorporating two specification paradigms is presented,in which an algebraic specification is implemented by a set of abstract procedures specified in pre and post-condition style.The link between the two level specifications is provided via a translation from terms of algebraic specifications into temporal logic formulae representing abstract programs.In terms of translation,a criterion for an abstract implementation satisfying its specification is given,which allows one to check the consistency between the two levels of specifications.The abstract implementations can be refined into executable code by refining each abstract procedure in it.It is proved that the satisfication relation between a specification and its implementations is preserved by such refinement steps.     

Deformation analysis of skew ruled surface shells by moiré interference

The use of thin film grids coated on surfaces is described in relation to the determination of deformations in doubly curved shells. The technique is called the coating film moiré interference method and employs a laser holographic approach.