CSP流程和传统流程生产无取向硅钢50W1300析出物分析

采用配备了X射线能谱分析仪的Tecnai F20场发射透射电子显微镜对CSP流程和传统流程生产的50W1300无取向硅钢析出物类型、形貌和尺寸进行了对比分析.结果表明:不同流程生产的50W1300无取向硅钢的析出物主要为AlN、CuXS/MnS以及Ti(CN)的单相或复合析出物,但CSP流程中Ti(CN)的含量明显高于传统流程;采用CSP流程生产的50W1300无取向硅钢中析出物平均尺寸仅69 nm,比传统流程生产的208 nm明显细小,对最终产品晶粒长大具有更强的抑制效应.     

冷轧硅钢横向同板差优化方案研究

对冷轧硅钢横向同板差的影响因素进行了研究。利用6 Sigma的研究方法,开展DOE实验方案设计,得到同板差与4个变量的回归模型。通过对模型中各变量进行优化,得到同板差最优值。在满足客户对同板差要求的前提下,可根据热轧平均凸度,对中间辊窜辊、辊型进行优化,以减少冷轧切边量、避免切边浪费、提高硅钢综合成材率。     

铂铑包覆钼合金搅拌器的研制

介绍了铂铑包覆钼合金搅拌器的结构与技术要求,以及搅拌器的制作与使用效果。研制结果表明,国产搅拌器达到了日本同类产品的水平。     

渣油胶体稳定性与热反应生焦性能关系的研究

利用混合物粘度法对辽河减压渣油(LHVR)、俄罗斯M100(M100)的胶体稳定性进行研究,其胶体稳定性参数分别为0.802和0.287。对两种渣油的生焦性能进行研究,在相同的反应温度(380℃),反应时间达到90min时,LHVR和M100的生焦率分别为28.40%和11.05%。将质量分数为0.5%的碱性添加剂注入到M100中,反应时间为90 min时,生焦率为3.07%。结果表明,生焦诱导期后,渣油胶体稳定性与其生焦性能之间不存在对应关系,其生焦率的大小主要取决于原料的康氏残炭值,碱性添加剂能够改变渣油中分散体系的稳定性,从而降低生焦率,改善产品分布。     

基于核函数的多极化HRRP识别

针对多极化雷达高分辨距离像(HRRP)识别中数据量大、分布复杂和识别算法复杂的问题,提出了基于核函数的识别方法.该方法首先定义了两种基于多极化HRRP的核函数,然后将其分别应用到核主分量分析(KPCA)中降维和提取特征,最后采用最近邻(1NN)分类器和支持矢量机(SVM)分类器对目标进行分类.该方法可以在不丢失极化信息的情况下,将多极化HRRP作为一个整体进行识别,降低了识别算法的复杂度.多极化HRRP数据的仿真实验结果显示,该方法的识别率比单极化HRRP提高7%～10%;与其他多极化HRRP识别方法相比,该方法不仅降低了提取特征的维数,而且还提高了识别性能.     

表面活性剂辅助水热法中TiO2的形状控制

By hydrolysing titanium isopropoxide in a long hydrocarbon chain surfactant-containing solution, TiO2 fine particles with a diversity of well-defined morphologies was synthesized in this study by a hydrothermal route. The structural change during the formation process was monitored by scanning electron microscopy, transmission electron microscopy and X-ray diffraction analysis. TiO2 with various morphologies such as particle, sheet, rod, tube and flower-like shape was obtained by carefully controlling the preparation conditions. The experimental results show that the pH value is crucial for shape control of the produced TiO2 because it can change the charge state of the surfactant in the solution and the adsorption potential of the surfactant on the TiO2 surface. The shape evolvement of anatase TiO2 was elucidated by quenching the reaction at different stage and the formation mechanism of different shaped TiO2 was suggested.     

面向铣削任务的工业机器人刚度位姿优化

为提高机器人刚度性能,减小铣削加工误差,对搭载铣削执行器的6自由度机器人进行刚度优化.首先,运用虚功原理建立机器人刚度映射模型;其次,设计辨识实验获取关节刚度;再次,以铣削力椭圆平面的各向同性度为优化指标,运用遗传算法对机器人优化位姿进行求解;最后,对比分析机器人位姿优化前后的整体刚度,并进行机器人铣削试验验证位姿优化的有效性,铣削平面度可提升45％.该优化方法可指导串联型工业机器人对大型航天器舱体的铣削加工任务,提高加工质量.     

Mo-Modified ZnIn2S4@NiTiO3 S-Scheme Heterojunction with Enhanced Interfacial Electric Field for Efficient Visible-Light-Driven Hydrogen Evolution

Designing and developing visible-light-responsive materials for solar to chemical energy is an efficient and promising approach to green and sustainable carbon-neutral energy systems. Herein, a facile in situ growth hydrothermal strategy using Mo-modified ZnIn₂S₄ (Mo-ZIS) nanosheets coupled with NiTiO₃ (NTO) microrods to synthesize multifunctional Mo-modified ZIS wrapped NTO microrods (Mo-ZIS@NTO) photocatalyst with enhanced interfacial electric field (IEF) effect and typical S-scheme heterojunction is reported. Mo-ZIS@NTO catalyst possesses wide-spectrum light absorption properties, excellent visible light-to-thermal energy effect, electron mobility, charges transfer, and strong IEF and exhibits excellent solar-to-chemical energy conversion for efficient visible-light-driven photocatalytic hydrogen evolution. Notably, the engineered Mo_1.4-ZIS@NTO catalyst exhibits superior performance with H₂ evolution rate of up to 14.06 mmol g⁻¹ h^{− 1} and the apparent quantum efficiency of 44.1% at 420 nm. The scientific explorations provide an in-depth understanding of microstructure, S-scheme heterojunction, enhanced IEF, Mo-dopant facilitation effect. Moreover, the theoretical simulations verify the critical role of Mo element in promoting the adsorption and activation of H₂O molecules, modulating the H adsorption behavior on active S sites, and thus accelerating the overall catalytic efficiency. The photocatalytic hydrogen evolution mechanism via S-scheme heterojunction with adjustable IEF regulation over Mo_1.4-ZIS@NTO is also demonstrated.     

基于CTI技术实现小型呼叫中心

CTI技术已成为建设第三代客户服务中心的核心技术。本文介绍了一种小型客服中心新的构建方案，并设计了相应的软硬件结构，并和其它模型相比较探讨其经济性和实用性。