Theoretical study on a kind of cyclization mechanism of boron trichloride and hexamethyldisilazane to form the borazine ring for SiBCN ceramics precursor

Borazine rings act as a pivotal part in siliconboroncarbonitride ceramics (SiBCN) for high-temperature stability and great resistance to crystallization. A detailed investigation of the ring formation mechanism will guide the design and synthesis of SiBCN to meet application requirements under extreme conditions. Boron trichloride (BCl₃) and hexamethyldisilazane (HN(SiMe₃)₂) are common raw materials for the synthesis of precursors for SiBCN. In this paper, quantum chemical calculation was used to study the cyclization reaction mechanism between BCl₃ and HN(SiMe₃)₂ to form trichloroborazine (TCBZ) at the MP2/6-31G (d,p) level of theory. We discussed the structure properties, reaction pathways, energy barriers, reaction rates, and other aspects in detail. The results show that BCl₃ and HN(SiMe₃)₂ alternately participate in the reaction process, accompanied by the release of trimethylchlorosilane (TMCS), and that the entire reaction shows an absolute advantage in terms of energy. In the Step by step reaction, lower reaction barriers are formed due to the introduction of BCl₃ with more heat released compared to that for the introduction of HN(SiMe₃)₂. The final single-molecule cyclization and TMCS elimination steps are found to be faster compared to all previous bimolecular reactions.     

高可靠镀Ni／Au工艺及其在微波PTFE电路上的应用

介绍了高可靠电镀Ｎｉ／Ａｕ工艺在ＰＴＦＥ微波印制电路上的应用，并分析了氨基磺酸盐镀软镍和亚硫酸盐镀软金工艺的影响因素及提高Ｎｉ／Ａｕ镀层之间附着力的措施。通过实验及应用证明了与直接镀金工艺相比，在软基材ＰＴＦＥ敷铜箔板上镀Ｎｉ／Ａｕ工艺能大大提高微波电路的可焊性，高温稳定性和长期可靠性，并且用其所制作的微波器件的高频性能也优于直接镀金工业。     

基于LonWorks和DSPs的智能节点

本文提出了一种基于LonWorks和DSPs的智能节点设计方案，并给出了具体的实现方法。该方案简单、可靠，充分利用了LonWorks强大的网络性、可靠性和DSPs强大的数据处理能力，大大提升了节点的智能化程度。     

基于ARToolkit Plus的增强现实系统实现及框架研究

文章首先对基于ARToolkit Plus和WPF的增强现实系统实现的关键技术问题进行了描述,具体讨论了在MVC框架下如何将数据采集层与呈现层进行分划,在保证可用性的同时提供较强的扩展能力,并基于上述框架实现了一个应用于住房装修的实例。     

超重力对燃烧合成Ti（C，N）-TiB2复合粉体的影响

以Ti和B4C为起始反应物，分别在常规和超重力条件下通过燃烧合成技术制备出Ti（C,N）-TiB2复合粉体，利用XRD和SEM对燃烧产物进行了表征，研究了起始组成和超重力条件对燃烧产物相组成和微观形貌的影响。结果表明，燃烧产物主要由Ti（C，N）和TiB2组成，通过改变起始配方中Ti／B4C的摩尔比，可以调节产物中Ti（C，N）和TiB2的相对含量。超重力条件下，反应物颗粒接触更加充分，碰撞更加频繁，因而晶粒形态发育更加完整，生成规则的多面体。     

立体传质塔板CTST技术及其在炼油装置中的应用

介绍了新型高效喷射型塔板--立体传质塔板CTST的安装结构与工作原理,并对基本的水力学性能进行了研究,包括物沫夹带、塔板压降、消泡和抗堵等性能.CTST成功应用到炼油装置的常压蒸馏、催化裂化、脱硫再生、污水汽提等装置的塔器中,应用结果表明CTST塔板的处理能力比F1浮阀塔板高一倍,具有很好的消泡和抗堵性能,而且扩产后的塔板效率高于以前的塔板.     

受端电网区域无功自动控制调控策略研究

要确保受端电压的稳定性,就要保证有足够的无功补偿。静态无功补偿可以有效降低网损,并提供稳定的无功功率。但在电网系统变得越来越复杂的情况下,静态无功补偿已经很难满足需求,这时,动态无功补偿作为一种更为有效的无功补偿方式应运而生了。     

Modeling the Value-Based Software Process with Object-Petri-Nets

Commercial organizations increasingly need software processes sensitive to busi- ness value, quick to apply, supportive of multi-stakeholder collaboration, and capable of early analysis for subprocess consistency and compatibility. This paper and a companion paper \Applying Value-Based Software Process: An ERP Example" present our experience in ap- plying a lightweight synthesis of a Value-Based Software Quality Achievement (VBSQA) process and an Object-Petri-Net (OPN) based process model to achieve a stakeholder win- win outcome for software quality achievement in an ERP software project in China. We attempt to answer such questions as (1) whether it is possible to model various project stakeholder perspectives using formal process modeling languages in a real-world project? (2) how to make stakeholders synchronize and stabilize their value propositions, activities and commitments as needed. The companion paper presents the VBSQA process and its application to the ERP project; this paper presents the OPN-based process modeling and its application. The application results of OPN process modeling conˉrmed that (1) the OPN- based process model provided project managers with a synchronization and stabilization framework for process activities, success-critical stakeholders and their value propositions; (2) process visualization and simulation tools signiˉcantly increased management visibility and controllability for the success of the software project.     

浅埋地下结构抗震设计的反应位移法关键问题

为了解决采用反应位移法进行地下结构抗震设计时工程师所面临的不同计算公式和模型的选取及土体是否需要分层等问题,通过具体算例分析,探讨了影响反应位移法计算精度的几个主要因素,具体包括不同规范中推荐的土体相对位移及剪应力的计算公式、土弹簧刚度的确定方法、分层土体与等效单层土体的差异、荷载-结构模型的选择等。研究结果表明：不同方法确定的土体相对位移、剪应力及土弹簧刚度值相差很大,由此造成的结构内力和变形差异显著,推荐公式应谨慎采用;对存在中柱体系的地下结构,荷载-结构模型应优先采用等代框架模型;采用反应位移法计算时,应严格按照实际分层土体完成土层地震响应分析,避免进行等效均一化处理。