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排序方式: 共有213条查询结果,搜索用时 46 毫秒
1.
Atsushi Narumi Kosei Kawasaki Harumi Kaga Toshifumi Satoh Naoya Sugimoto Toyoji Kakuchi 《Polymer Bulletin》2003,49(6):405-410
Summary
The potato phosphorylase-catalyzed polymerization of α-D-glucose-1-phosphate (G-1-P) onto poly[styrene-block-(4-vinylbenzyl maltohexaoside)] (1) was performed at the molar ratios of [G-l-P]0 and [maltohexaose]0 of 35, 80, and 250. The product was found to be soluble in dimethyl sulfoxide, which was a good solvent for amylose, and
showed the complex-formation with iodine, indicating that the product was assignable to poly[styrene-block-(styrene-graft-amylose)] (2). The quantitative analysis of the liberated phosphoric acid gave the average degree of polymerization o f the glucose unit
(n) as 27, 5 1, and 180 for 2-I, 2-II, and 2-III, respectively.
Received: 29 November 2002/Accepted: 22 December 2002
Correspondence to Toyoji Kakuchi 相似文献
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太钢3#高炉大修改造是集团公司重点外部工程项目之一,工程量大,工期紧,施工场地狭小,而质量要求较高。如何采取科学、经济的设备吊装方案,对整个项目经济指标的实现,意义重大。文章详细介绍了太钢3#高炉重力除尘器大件整体吊装方案。通过实际采用,取得良好的经济效果。 相似文献
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文章根据电机负荷理论对φ3m分级机螺旋轴进行受力分析,避免了复杂的推导计算和疲劳强度校核。根据现场实际,将机械技术与电气技术结合,分析其断裂原因,提出改进措施,具有较好的效果和借鉴价值。 相似文献
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The effects of 8-h annealing at 960 °C on the gaseous phase hydrogen storage and electrochemical properties of partial-Ni substituted Zr8Ni21 alloys were studied. The substituting elements included Mg, Al, Sc, V, Mn, Co, Sn, La, and Hf. Only the main phase of the annealed Sn-substitution remained Zr8Ni21-structured while those of other substitutions turned into Zr7Ni10 or Zr2Ni7. The observed trend in maximum gaseous phase hydrogen storage capacity followed the increasing order of B/A ratio of the main phase as orthogonal Zr7Ni10 > tetragonal Zr7Ni10 > Zr8Ni21 > Zr2Ni7. After annealing, due to the increase in abundance of the main phase, the maximum gaseous phase hydrogen storage capacities of alloys with higher capacities before annealing increased while others decreased. The full discharge capacity also improved in the same increasing order of B/A ratio in the main phase. Hf-substitution showed the highest electrochemical discharge capacity at 200 mAh g−1. After annealing, all alloys with the same main phase as the as-cast alloys showed degradation in full electrochemical capacity due to the reduction in both number and abundance of the catalytic secondary phases. All supplements assisted in improving surface exchange current from the base binary Zr8Ni21 alloy. Except for La- and Hf-substitutions, annealing reduced the surface exchange current density. The bulk hydrogen diffusion coefficient decreased with most of the supplements except for V- and Sn-substitutions. All supplements, except for Sc, showed improvement in the bulk diffusion after annealing. Furthermore, the maximum gaseous phase hydrogen storage capacity showed a strong correlation to the full electrochemical discharge capacity. Among all alloys in this study, the as-cast Hf-substituted Zr8Ni21 alloy demonstrated the best overall gaseous hydrogen storage and electrochemical properties. 相似文献
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Masuda Takahiro Fujimitsu Kazushige Sumikawa Kosei Kajita Takahiro Tang Yongpeng Hirosawa Shoichi Takizawa Yoichi Yumoto Manabu Otagiri Yoshiharu Horita Zenji 《Metallurgical and Materials Transactions A》2021,52(9):3860-3870
Metallurgical and Materials Transactions A - This study examines strain distribution occurring in the high-pressure sliding (HPS) processing for rods of pure Al and an AZ61 alloy. The strain... 相似文献
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Luciane Madureira Almeida Juliana Ferreira Floriano Thuanne Pires Ribeiro Lais Nogueira Magno Lígia Souza Lima Silveira da Mota Nei Peixoto Fátima Mrué Paulo Melo-Reis Ruy de Souza Lino Junior Carlos Frederico de Oliveira Graeff Pablo José Gonçalves 《Journal of materials science. Materials in medicine》2014,25(9):2153-2162
The latex obtained from Hancornia speciosa is used in folk medicine for treatment of several diseases, such as acne, warts, diabetes, gastritis and inflammation. In this work, we describe the biocompatibility assessment and angiogenic properties of H. speciosa latex and its potential application in medicine. The physical–chemical characterization was carried out following different methodologies (CHN elemental analyses; thermogravimetric analyses and Fourier transform infrared spectroscopy). The biocompatibility was evaluated through cytotoxicity and genotoxicity tests in fibroblast mouse cells and the angiogenic properties were evaluated using the chick chorioallantoic membrane (CAM) assay model. The physical–chemical results showed that the structure of Hancornia speciosa latex biomembrane is very similar to that of Hevea brasiliensis (commercially available product). Moreover, the cytotoxicity and genotoxicity assays showed that H. speciosa latex is biocompatible with life systems and can be a good biomaterial for medical applications. The CAM test showed the efficient ability of H. speciosa latex in neovascularization of tissues. The histological analysis was in accordance with the results obtained in the CAM assay. Our data indicate that the latex obtained from H. speciosa and eluted in water showed significant angiogenic activity without any cytotoxic or genotoxic effects on life systems. The same did not occur with H. speciosa latex stabilized with ammonia. Addition of ammonia does not have significant effects on the structure of biomembranes, but showed a smaller cell survival and a significant genotoxicity effect. This study contributes to the understanding of the potentialities of H. speciosa latex as a source of new phytomedicines. 相似文献