Rare earth oxides as carbon oxidation catalysts

The behavior of a number of rare earth oxides as catalysts for the oxidation of graphite in air has been investigated by the methods of thermal analysis. Of the oxides studied, only CeO₂ showed significant activity in accelerating the gasification of graphite by oxygen between 500 and 1000°C. Cerium salts, which decompose to a finely dispersed oxide phase at low temperatures, e.g. Ce (III) nitrate and ammonium Ce (IV) nitrate, were found to be very active catalysts. The catalytic effect may be due to a redox process involving the cyclic conversion of the oxide from the Ce (IV) to the Ce (III) oxidation state, or the oxide particles may provide sites for the dissociative chemisorption of oxygen.     

Measuring hospital performance: are we asking the right questions?

The aim of this randomized cross-over trial was to evaluate the dose effect and systemic absorption of epinephrine nebulized at 2 and 5 mg in comparison with salbutamol (5 mg). Thirteen asthmatic patients (29 +/- 15 years, 4 men and 9 women) were randomly assigned to receive one nebulization of each of the three treatment regimens at 24 h interval. The evaluation concerned forced expiratory volume in 1 second (FEV1), heart rate, respiratory rate and arterial pressure. All measurements were done at baseline, every 15 minutes during the first hour, and hourly thereafter until return to baseline FEV1. Serum potassium was measured at baseline (T0) and sixty minutes after (T60). Plasma levels of epinephrine were measured at T0, T20, T60. Fifteen minutes after the beginning of nebulization FEV1 improved significantly over baseline in the three groups. These changes were similar in the three groups until T45, while FEV1 improvement was significantly greater in A5 and S groups than A2 group (+640 +/- 470 ml, +721 +/- 349 ml, +406 +/- 306 ml in A5, S and A2 groups respectively, p < 0.01). Bronchodilation lasted significantly longer with salbutamol than with epinephrine (p < 0.05). No side effects were recorded in spite of substantial and dose-dependent systemic absorption of epinephrine. CONCLUSION: Increasing epinephrine doses produces greater bronchodilation without additional side effects. However this bronchodilation lasts shorter than with salbutamol.     

Insanity and adultery: forensic implications of a divorce case

Legal responsibility for acts presumes that a person's behavior is rationally intentional and under voluntary control. Automatism, a type of insanity defense, contends that the person's conscious, voluntary control of behavior has been impaired by a mental disorder. In a recent case in South Carolina, automatism was offered as a defense to adultery, an at-fault grounds to divorce. On appeal, the State Supreme Court recognized the novel application of mental impairment defenses in domestic litigation and remanded the case for rehearing. Implications of the ruling for clinical and forensic practice in family court are discussed.     

Fabrication of electroabsorption optical modulators using laserdisordered GaInAs/GaInAsP multiquantum well structures

Electroabsorption optical modulators have been fabricated on GaInAs/GaInAsP multiquantum well structures whose bandgap had been increased by laser photoabsorption-induced disordering. Modulation depths of 20 dB have been obtained in material which has been bandgap blue shifted by as much as 120 nm, while samples shifted by 80 nm gave depths as high as 27 dB     

An orphan nuclear receptor activated by pregnanes defines a novel steroid signaling pathway

PURPOSE: To determine the effects of 28 d of creatine supplementation during training on body composition, strength, sprint performance, and hematological profiles. METHODS: In a double-blind and randomized manner, 25 NCAA division IA football players were matched-paired and assigned to supplement their diet for 28 d during resistance/agility training (8 h x wk[-1]) with a Phosphagen HP (Experimental and Applied Sciences, Golden, CO) placebo (P) containing 99 g x d(-1) of glucose, 3 g x d(-1) of taurine, 1.1 g x d(-1) of disodium phosphate, and 1.2 g x d(-1) of potassium phosphate (P) or Phosphagen HP containing the P with 15.75 g x d(-1) of HPCE pure creatine monohydrate (HP). Before and after supplementation, fasting blood samples were obtained; total body weight, total body water, and body composition were determined; subjects performed a maximal repetition test on the isotonic bench press, squat, and power clean; and subjects performed a cycle ergometer sprint test (12 x 6-s sprints with 30-s rest recovery). RESULTS: Hematological parameters remained within normal clinical limits for active individuals with no side effects reported. Total body weight significantly increased (P < 0.05) in the HP group (P 0.85 +/- 2.2; HP 2.42 +/- 1.4 kg) while no differences were observed in the percentage of total body water. DEXA scanned body mass (P 0.77 +/- 1.8; HP 2.22 +/- 1.5 kg) and fat/bone-free mass (P 1.33 +/- 1.1; HP 2.43 +/- 1.4 kg) were significantly increased in the HP group. Gains in bench press lifting volume (P -5 +/- 134; HP 225 +/- 246 kg), the sum of bench press, squat, and power clean lifting volume (P 1,105 +/- 429; HP 1,558 +/- 645 kg), and total work performed during the first five 6-s sprints was significantly greater in the HP group. CONCLUSION: The addition of creatine to the glucose/taurine/electrolyte supplement promoted greater gains in fat/bone-free mass, isotonic lifting volume, and sprint performance during intense resistance/agility training.     

Compton scattering in a large-aperture positron imaging system

Compton scattering of gamma rays within the image volume has been assessed for a large-aperture positron-emission-tomography imaging system. The Compton scattered attenuation and the Compton scattered background were both modeled and measured for point sources centered in scattering spheres up to 10 cm in diameter. Good agreement was obtained between simulations and measurements. The attenuation problem is independent of the detector system, but its correction is more difficult in a large-aperture system. The scattered coincidence background is large in this system (43% for a 10-cm-diameter scattering sphere), but the background overlap is reduced with 3D imaging.     

Correlations between electrical resistance-hydrogen pressure relationships of the Pd/Pt/H system and alterations of structure with changes of hydrogen content in the Pd/H system

For higher Pt content alloys of the Pd/Pt series of alloys, relationships at 25 °C between hydrogen content, n, and incremental changes of specific electrical resistance, Δρ, seem representable to a good approximation by a common curve, with a maximum of Δρ near n = 0.5 of similar form to ‘Nordheim’ types of relationship between resistivity and composition appropriate to substitutional alloys. An attempt has been made to assess whether phase-transition-related deviations from this symmetrical form of Δρ-n relationship in the cases of palladium itself and Pd/Pt alloys with lower Pt contents may provide useful guidance concerning the sequence of hydrogen occupation of interstitial sites in and β(′) phases (domains) of these systems.     

Adapting Memory Hierarchies for Emerging Datacenter Interconnects

E?cient resource utilization requires that emerging datacenter interconnects support both high performance communication and e?cient remote resource sharing. These goals require that the network be mor...     

The MAC method

In this article recent advances in the Marker and Cell (MAC) method will be reviewed. The MAC technique dates back to the early 1960s at the Los Alamos Laboratories and this article starts with a historical review, and then a brief discussion of related techniques. Improvements since the early days of MAC (and the Simplified MAC - SMAC) include automatic time-stepping, the use of the conjugate gradient method to solve the Poisson equation for the corrected velocity potential, greater efficiency through stripping out the virtual particles (markers) other than those near the free surface, and more accurate approximations of the free surface boundary conditions, the addition of bounded high accuracy upwinding for the convected terms (thereby being able to solve higher Reynolds number flows), and a (dynamics) flow visualization facility. More recently, effective techniques for surface and interfacial flows and, in particular, for accurately tracking the associated surface(s)/interface(s) including moving contact angles have been developed. This article will concentrate principally on a three-dimensional version of the SMAC method. It will eschew both code verification and model validation; instead it will emphasize the applications that the MAC method can solve, from multiphase flows to rheology.