Toluene oxidation on Pd catalysts supported by CeO2–Y2O3 washcoated cordierite honeycomb

A novel CeO₂–Y₂O₃ (CY) washcoat on cordierite honeycomb was prepared by an impregnation method, which was used as a support to prepare a Pd catalyst. A model reaction of the complete combustion of toluene was conducted to evaluate the performance of the developed Pd/CY catalyst. The CY washcoat support and the Pd/CY catalyst were characterized by XRD, Raman spectroscopy, H₂-TPR and SEM techniques. The results show that compared with conventional washcoat the CY washcoat has better adhesion and higher vibration- and heat-resistance. The CY washcoat can anchor well Pd onto the cordierite honeycomb substrate. The formation of a CeO₂–Y₂O₃ solid solution and the steady present of PdO occur at high calcination temperatures, resulting in a better thermal stability. On a Pd/CY catalyst calcined at 500 °C, a 99% of toluene conversion was obtained at 210 °C, and it was stable for reaction time up to 30 h.     

基于卷积神经网络的指针式仪表识别

目前大部分研究指针式仪表识别的方法中提取指针是完全基于传统的图像处理技术,提取过程较为复杂且步骤繁多.为了有效解决指针式仪表读数识别中指针中轴线所在直线提取困难及识别精度不高等问题,本文提出了一种基于深度学习的指针式仪表的识别方法.首先用Faster R-CNN算法检测仪表圆盘,再采用基于深度学习的方法Faster R-CNN算法检测指针,根据得到的指针目标框的位置信息裁剪得到指针图像,在指针图像的基础上进行二值化、细化、霍夫变换检测直线、最小二乘法拟合直线等步骤识别仪表最终读数.和直接在仪表表盘目标框图像或原始图像上进行传统图像处理相比很大程度上减少了定位指针中轴线所在直线过程中的干扰.实验结果表明本文所提出的基于深度学习的指针检测的平均准确率高达96.55％.对于复杂背景下指针式仪表的指针区域的检测具有良好的准确性与稳定性.     

质量管理信息系统(QMS)的开发及应用探讨

介绍了火电建设质量管理信息系统 ,其基本功能模块为质检计划、质量记录、质量签证、质量验评、缺陷统计和调试记录。采用作业码 (由 6位 BSI码和 4位序列码组成 )及应用情况。     

Capacitated facility location problem with general setup cost

This paper presents an extension of the capacitated facility location problem (CFLP), in which the general setup cost functions and multiple facilities in one site are considered. The setup costs consist of a fixed term (site setup cost) plus a second term (facility setup costs). The facility setup cost functions are generally non-linear functions of the size of the facility in the same site. Two equivalent mixed integer linear programming (MIP) models are formulated for the problem and solved by general MIP solver. A Lagrangian heuristic algorithm (LHA) is also developed to find approximate solutions for this NP-hard problem. Extensive computational experiments are taken on randomly generated data and also well-known existing data (with some necessary modifications). The detailed results are provided and the heuristic algorithm is shown to be efficient.     

基于MapReduce 的大规模在线社交网络蠕虫仿真

利用云计算中的核心技术MapReduce,提出了一种在线社交网络(online social network,简称OSN)蠕虫的仿真方法.为了提高仿真精度,首先提出利用节点属性可调节的OSN 有向图来描述蠕虫传播的各个过程.其次,利用运行在云环境中的多个Map 函数和Reduce 函数来实现对OSN 蠕虫传播各个过程的仿真.在真实的大规模数据集上的仿真实验结果表明,提出的仿真方法不仅具有较强的可扩展性,同时也为相关领域的研究提供了一定的帮助.     

基于混合蛙跳和遗传规划的跨单元调度方法

针对运输能力受限条件下的跨单元问题,提出了一种基于混合蛙跳与遗传规划的超启发式算法.将改进的混合蛙跳算法作为超启发式算法的高层框架,为跨单元调度问题搜索启发式规则,同时利用遗传规划产生可以兼顾多因素的优质规则,用于扩充超启发式算法的规则集.实验表明,提出的算法可以有效地搜索出优异的规则组合,并且通过遗传规划产生的规则可以在很大程度上改善候选规则集,提升算法性能.     

不同形式壳聚糖基水凝胶的微观结构与控释性能对比

本文采用离子交联和巯基化两种不同方式改性壳聚糖,制备载有活性蛋白的壳聚糖水凝胶。通过红外光谱、粒径/zeta电位分析、透射电镜、扫描电镜、模拟消化实验等手段,探讨了其微观结构和控释性能。实验结果发现,由于分子间氢键作用,p H值、CS:TPP质量比以及BSA浓度等对交联壳聚糖水凝胶的蛋白包载率影响明显,而由于巯基的引入,使得巯基化壳聚糖水凝胶在酸性环境下具有较小的粒径(平均409.61 nm)和较低的表面电势(平均-0.67 mV)。壳聚糖基材料微观结构的变化进而影响其水凝胶的控释性能。模拟消化实验显示,交联壳聚糖水凝胶在模拟胃液中出现突释现象,在运送至结肠前,已有44.76%的活性蛋白释放,而巯基化壳聚糖水凝胶在模拟上消化道环境中释放缓慢,仅有8.42%的活性蛋白释放,运转至模拟结肠,活性蛋白释放速度逐渐增加,呈现持续释放的效果,约有34.53%的BSA逐渐释放在结肠中。因此,巯基化壳聚糖基水凝胶具有更好的控释性能,这对活性蛋白的生物利用改善具有重要作用。     

Resveratrol Attenuates Acute Inflammatory Injury in Experimental Subarachnoid Hemorrhage in Rats via Inhibition of TLR4 Pathway

Toll-like receptor 4 (TLR4) has been proven to play a critical role in neuroinflammation and to represent an important therapeutic target following subarachnoid hemorrhage (SAH). Resveratrol (RSV), a natural occurring polyphenolic compound, has a powerful anti-inflammatory property. However, the underlying molecular mechanisms of RSV in protecting against early brain injury (EBI) after SAH remain obscure. The purpose of this study was to investigate the effects of RSV on the TLR4-related inflammatory signaling pathway and EBI in rats after SAH. A prechiasmatic cistern SAH model was used in our experiment. The expressions of TLR4, high-mobility group box 1 (HMGB1), myeloid differentiation factor 88 (MyD88), and nuclear factor-κB (NF-κB) were evaluated by Western blot and immunohistochemistry. The expressions of Iba-1 and pro-inflammatory cytokines in brain cortex were determined by Western blot, immunofluorescence staining, or enzyme-linked immunosorbent assay. Neural apoptosis, brain edema, and neurological function were further evaluated to investigate the development of EBI. We found that post-SAH treatment with RSV could markedly inhibit the expressions of TLR4, HMGB1, MyD88, and NF-κB. Meanwhile, RSV significantly reduced microglia activation, as well as inflammatory cytokines leading to the amelioration of neural apoptosis, brain edema, and neurological behavior impairment at 24 h after SAH. However, RSV treatment failed to alleviate brain edema and neurological deficits at 72 h after SAH. These results indicated that RSV treatment could alleviate EBI after SAH, at least in part, via inhibition of TLR4-mediated inflammatory signaling pathway.     

通过廉价硅源制备二氧化硅微球及其粒径控制

将廉价的硅酸钠作为硅源生产二氧化硅微球有着重要的意义。以硅酸钠为硅源,聚乙二醇（PEG）为结构导向剂,在超声波辅助下,成功合成出高分散的二氧化硅微球。探索了PEG及超声波对产物形貌的影响,讨论了反应温度、pH、PEG相对分子质量与产物粒径的关系。结果表明,PEG能够引导产物成球,超声波可以提高产物的分散性,升高温度及pH会降低产物粒径,增加PEG的相对分子质量会提升产物粒径。当控制温度为40 ℃、pH为3.5、聚乙二醇相对分子质量为2 000时,所得的产品分散性较好,粒径为6.34 μm。     

非水滴定法测定凉味剂琥珀酸单薄荷酯含量的研究

建立了测定琥珀酸单薄荷酯含量的非水滴定方法。采用电位法和指示剂法指示滴定终点,对测定条件进行了研究,并用气相色谱法验证了方法的准确性。实验结果表明,以乙醇为溶剂,用甲醇钠标准滴定溶液对琥珀酸单薄荷酯进行非水滴定,采用电位法和指示剂法的测定结果与气相色谱法的测定结果无显著差异(置信度95%);体系中水分含量≤1%时,对测定结果没有显著影响。该方法简单快速,准确度高,重复性好,非常适用于琥珀酸单薄荷酯含量的测定和质量控制。