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排序方式: 共有154条查询结果,搜索用时 15 毫秒
1.
EA Lock Y Sani RB Moore MB Finkelstein MW Anders AA Seawright 《Canadian Metallurgical Quarterly》1996,70(10):607-619
Almost 40 years ago, it was reported that cattle-feed which had been extracted with hot trichloroethylene and then fed to calves produced renal injury and a fatal aplastic anaemia. The toxic factor was subsequently identified as S-(1,2-dichlorovinyl)-L-cysteine (DCVC). These original findings have been confirmed, a single intravenous dose of DCVC at 4 mg/kg, or 0.4 mg/kg intravenously per day administered for 10 days to calves produced aplastic anaemia, and renal injury after a single dose of 4 mg/kg. The toxicity to calves of a number of other haloalkene cysteine conjugates has been examined to ascertain whether, like DCVC, they produce bone marrow and renal injury. Intravenous administration of the N-acetyl cysteine conjugate of DCVC produced renal but not bone marrow injury at a molar equivalent dose to DCVC, indicating that the calf can deacetylate the mercapturic acid and further that sufficient chemical had reached the kidney to be a substrate for the enzyme cysteine conjugate beta-lyase. However, intravenous administration of the alpha-methyl analogue of DCVC, which cannot undergo metabolism via the enzyme cysteine conjugate beta-lyase, was without toxicity at doses about five-fold higher than DCVC. These latter findings provide strong evidence that metabolism of DCVC via the enzyme beta-lyase is necessary for bone marrow and renal injury to occur. The cysteine conjugates of perchloroethylene and hexachloro-1,3-butadiene(HCBD) when given intravenously to calves at molar equivalent doses to DCVC, or above, did not produce either bone marrow or renal injury. In contrast, intravenous administration of the cysteine conjugate of tetrafluoroethylene (TFEC) produced severe renal tubular injury in calves without affecting the bone marrow. In vitro studies with these haloalkene cysteine conjugates showed, like DCVC, that they were good substrates for calf renal cysteine conjugate beta-lyase and toxic to renal cells as judged by their ability to reduce organic anion and cation transport by slices of calf renal cortex and inhibit the renal enzyme glutathione reductase. Calves were also dosed either orally or intravenously with HCBD to assess its toxicity. HCBD at higher molar equivalent doses than DCVC produced mid-zonal necrosis in the liver, renal tubular necrosis but no bone marrow injury in calves. The key findings emerging from these studies are (1) that none of the other cysteine conjugates, at molar equivalent doses to DCVC and above, produce bone marrow injury in calves, (2) TFEC produced only renal injury, suggesting that sufficient of the other conjugates had not reached the kidney for metabolism by beta-lyase to produce cytotoxicity and (3) that HCBD itself is more toxic than its cysteine or mercapturic acid conjugate, suggesting that pharmaco-kinetics and disposition are important factors in determining the toxicity of these conjugates to calves. Further studies are needed to understand the basis for the selective toxicity of DCVC to the bone marrow of calves. 相似文献
2.
Anna Grazia Mignani Peter R. Smith Leonardo Ciaccheri Antonio Cimato Graziano Sani 《Sensors and actuators. B, Chemical》2003,90(1-3):157-162
In spectral nephelometry, absorption spectroscopy and nephelometry are innovatively combined to provide simultaneous online monitoring of color and turbidity of edible oils. Spectral nephelometry instrumentation consists of an optoelectronic device that measures the absorption spectrum of the oil sample at different angles. Data processing, carried out by principal component analysis (PCA), allows identification of the oil sample and creates a two-dimensional map as a fingerprint of oil types. 相似文献
3.
Mohammad‐Reza Alirezaee Mohammad‐Reza Rafiee Sani 《International Transactions in Operational Research》2011,18(6):729-740
Data envelopment analysis (DEA) models assume real‐valued inputs and outputs, but on many occasions, some inputs and/or outputs can only take integer values. In these cases, using DEA models can result in misleading efficiency assessments and inaccurate performance targets. In this paper, we propose an enumeration algorithm for computing efficiency scores and performance targets of decision‐making units with integer value inputs/outputs. In the presented algorithm, we do not use any of the mixed integer linear programming (MILP) models that are used in previous studies. We show that the result of our algorithm and that of the MILP model presented in this context is the same. We also generalize our algorithm for different types of returns to scale as well as for the hybrid setting with real‐valued data. 相似文献
4.
An electromechanical switch based on bent carbon nanotubes was fabricated. The shape and structure of the bent carbon nanotubes allows one to produce a low cost and low working voltage switch. The fabrication process is free of any nanolithography. The electrical characteristics of the fabricated device were investigated, both experimentally and theoretically. Actuation of the fabricated device shows hysteresis behavior in the measured I–V curves depending on the structural parameters of the bent nanotubes. The relationship between the pull-in voltage and the morphology of the bent nanotubes was studied by the obtained hysteresis curves. A scanning electron microscope was used for structural analysis. This study introduced an easy way to fabricate electromechanical switches with controllable on/off states. 相似文献
5.
Ali Hemmatifar Mohammad Said Saidi Arman Sadeghi Mahdi Sani 《Microfluidics and nanofluidics》2013,14(1-2):265-276
Dielectrophoresis (DEP) is an electrokinetic phenomenon which is used for manipulating micro- and nanoparticles in micron-sized devices with high sensitivity. In recent years, electrode-based DEP by patterning narrow oblique electrodes in microchannels has been used for particle manipulation. In this theoretic study, a microchannel with triangular electrodes is presented and a detailed comparison with oblique electrodes is made. For each shape, the behavior of particles is compared for three different configurations of applied voltages. Electric field, resultant DEP force, and particle trajectories for configurations are computed by means of Rayan native code. The separation efficiency of the two systems is assessed and compared afterward. The results demonstrate higher lateral DEP force, responsible for particle separation, distributed wider across the channel width for triangular shape electrodes in comparison with the oblique ones. The proposed electrode shape also shows the ability of particle separation by attracting negative DEP particles to or propelling them from the flow centerline, according to the configuration of applied voltages. A major deficiency of the oblique electrodes, which is the streamwise variation of the lateral DEP force direction near the electrodes, is also eliminated in the proposed electrode shape. In addition, with a proper voltages configuration, the triangular electrodes require lower voltages for particle focusing in comparison with the oblique ones. 相似文献
6.
Sanaz Naghibi Hamid Reza Madaah Hosseini Mohammad Ali Faghihi Sani Mohammad Ali Shokrgozar Morteza Mehrjoo 《Ceramics International》2014
TiO2 nanoparticles (NPs) were synthesized by hydrothermal assisted sol–gel technique. In the next step, as-synthesized NPs were modified by poly ethylene glycol (PEG). Then, folic acid (FA) was conjugated to TiO2–PEG. Finally, Doxorubicin (Dox) as an anticancer drug was loaded on as-prepared TiO2–PEG–FA nanocarrier. The optimization of TiO2 and FA concentration and the influence of ultraviolet (UV) irradiation on photocatalytic activity of nanocarrier and Dox loaded carrier were assessed by utilizing the 3-(4,5-dimethylthiazol-2yl)-2,5-diphenyltetrazolium bromide (MTT)-assay method. 相似文献
7.
P. Sansoni D. Fontani F. Francini A. Giannuzzi E. Sani L. Mercatelli D. Jafrancesco 《Renewable Energy》2011,36(9):2341-2347
Parabolic trough collectors were investigated, applying the study results to a plant prototype installed in Florence (Italy) for residential supply. Ray tracing simulations examined optical characteristics and collection performance on the base of prototype geometry and functionality. The purpose was to control the realisation errors and overcome the difficulties arising in the development of the solar trough plant. The paper summarises the results of several studies analysing the interactions between collection efficiency, angular misalignments, mirror deformations, sun tracking and trough placement. The mirror deformations are reproduced introducing an original procedure. The unusual subject of imprecision in trough axis placement is discussed. 相似文献
8.
9.
Well-formed carbon nanocones at the ends of micrometer-diameter carbon fibers (CFs) were fashioned into functional tips for scanning tunneling microscopy (STM) and miniaturized voltammetric sensors. Sharpening of single graphite filaments was achieved by simple DC electrochemical etching in 0.1 N NaOH. Operated as STM tips, pointed CFs resolved in air the contour and surface morphology of a nanoscopic Au line pattern and imaged in vacuum a Si (1 1 1) surface with clear atomic resolution. Subjecting already etched CFs to tip-sparing insulation with electrodeposited paint produced conical carbon ultramicroelectrodes (UMEs) with effective radii down to about 900 nm. Comparative cyclic voltammetry trials in alkaline, neutral and acidic solutions showed that the conical carbon UME’s had a wider practical potential window for electroanalytic applications than, for instance, Pt disk UMEs. The CF-based conical sensors described here are exceptionally easy to make with simple laboratory equipment and perform well in STM topography imaging and voltammetry. The inherent simplicity of sensor production widens the field of potential users, and offers clear advantages over existing types of UMEs, in particular those based on carbon nanotubes, which are especially hard to handle in an optical microscope setting. 相似文献
10.
E. Sani L. Mercatelli S. Barison C. Pagura F. Agresti L. Colla P. Sansoni 《Solar Energy Materials & Solar Cells》2011,95(11):2994-3000
The optical characterization is reported of a new fluid consisting of single-wall carbon nanohorns and ethylene glycol for solar energy applications. Carbon nanohorns play a significant role in enhancing sunlight absorption with respect to the pure base fluid. The obtained results are compared with those obtained for fluids suspending more conventional carbon forms, i.e. carbon-black particles. We found that nanohorn spectral features are far more favorable than those of amorphous carbon for the specific application. This result shows that carbon nanohorn-based nanofluids can be useful for increasing the efficiency and compactness of thermal solar devices, reducing both environmental impact and costs. 相似文献