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玻纤增强石油发酵尼龙的热稳定性研究 总被引:1,自引:0,他引:1
利用热重动力学方法研究了玻纤增强PF尼龙(即石油发酵尼龙)的热稳定性能。玻纤和偶联剂均对PF尼龙具有热稳定化作用,且硅烷A1100对PF尼龙的热稳定化作用最为显著。 相似文献
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对RE、Tc、Bi、Sb等微量元素以涂料形式对球铁件厚大热节部位进行微合金化,以改善其组织的可能性进行了试验研究,结果表明:多元微量元素涂料可有效地消除碎块状石墨,提高球化率,改善球铁组织,涂料层厚度影响微合金化程度而应严格控制,该工艺具有简便。无炉料污染、可代替冷铁以确保复杂铸件组织均一等优点。 相似文献
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Poly(5‐bromoindole) (PBrI) films were synthesized electrochemically by direct oxidation of 5‐bromoindole in pure boron trifluoride diethyl etherate. The oxidation potential of 5‐bromoindole in this medium was measured to be only 0.97 V vs. saturated calomel electrode, which was lower than that determined in acetonitrile + 0.1 mol L?1 Bu4NBF4 (1.08 V). PBrI films obtained from this medium showed good electrochemical behavior and good thermal stability. Structural studies showed that the polymerization of 5‐bromoindole ring occurred at 2,3 position. As‐formed PBrI films were thoroughly soluble in strong polar solvent dimethylsulfoxide and partly soluble in tetrahydrofuran. Fluorescent spectral studies indicated that PBrI was a good blue‐light emitter. The excitation and emission spectra of PBrI showed a significant shift to longer wavelength compared with that of the monomer, consistent with the greater extent of electron delocalization. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 101: 539–547, 2006 相似文献
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为实现胸鳍摆动推进模式鱼类的游动,模仿牛鼻鲼构建了仿生鱼.首先,基于摆动胸鳍的生物学特征和运动规律,提出了具有主/被动复合柔性变形能力的仿生胸鳍原理模型.然后通过ADAMS运动学仿真验证了设计方案的可行性,并构建仿生样机.自由游动实验表明,仿生鱼游速可达0.46m/s,约1倍身长比,且具有原地转弯能力,最大转弯速度达60?/s.与国内外其他同类机器鱼相比,在游速和机动性方面均表现出明显的优势.基于准稳态叶素理论,提出了仿生胸鳍水动力简化计算模型.构建水动力实验平台,验证了计算模型的有效性,并通过一系列水动力实验研究了仿生胸鳍的水动力特性.实验结果表明,仿生胸鳍能够产生周期性变化的推、升力,且变化趋势与胸鳍运动控制参数密切相关. 相似文献
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The copolymerization of carbazole (CZ) and 3‐methylthiophene (3MeT) was successfully performed electrochemically in freshly distilled boron trifluoride diethyl etherate by direct anodic oxidation of the monomer mixtures, although the oxidation potentials of CZ and 3MeT were quite different. The electrochemical properties of the copolymers were studied with cyclic voltammetry. The influence of the applied polymerization potential on the synthesis of the copolymers was investigated. The higher potential favored the incorporation of 3MeT units into the copolymers. The insertion of 3MeT units into polycarbazole (PCZ) was helpful in improving the conductivity of PCZ. The novel copolymers had the advantages of both PCZ and poly(3‐methylthiophene), that is, good redox activity, good thermal stability, and high conductivity. The structure and morphology of the copolymers were investigated with ultraviolet–visible, infrared spectroscopy, thermal analysis, and scanning electron microscopy. © 2006 Wiley Periodicals, Inc. J Appl Polym Sci 102: 1877–1885, 2006 相似文献
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An experimental study has been performed in order to determine the effect of humidity on the flow field and the flame stability
limit in turbulent non-premixed flame. Two-dimensional Particle Image Velocimetry (PIV) measurements were made to quantify
the velocity field, with and without steam injected. The results indicate the addition of steam decreases the recirculation
flow and reduces the distance between the forward and aft stagnation points. The detailed stabilization regimes show that
the critical fuel-to-air velocity ratios of the central fuel penetration in the humid air case are 16% to 22% lower, and the
partially quenching limits are at least 25% lower. The decreased penetration limit is due to a reduction in momentum of the
humid air. An analysis of flamelet concepts reveals that increased chemical reaction time leads to lower partially quenching
limits in the humid air combustion. 相似文献
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用纯金属作中间层TLP连接颗粒增强铝基复合材料,接头存在增强相偏聚区,是接头力学性能的薄弱区域.控制增强相偏聚区是改善接头力学性能的一种有效途径.文中尝试用Cu,Al金属复合中间层TLP连接Al2O3P/6061Al复合材料,探讨了其接头的显微结构和力学性能特点.结果表明,用Cu,Al金属复合中间层能够控制接头增强相偏聚,改善接头抗剪强度.在连接温度600℃,保温时间60min的工艺条件下,10 μm Al/10 μm Cu/10 μm Al复合中间层接头增强相偏聚明显下降,接头抗剪强度110 MPa;1.5 μm Cu/10 μm Al/1.5 μm Cu复合中间层接头无明显的增强相偏聚,接头抗剪强度123 MPa. 相似文献