Microscopic fatigue processes in a plain-weave glass-fibre composite

This paper focuses on the microscopic damage and progressive failure of a composite reinforced by plain-weave glass cloth under tensile fatigue loading. The fatigue process was divided into three stages like that of multi-directional laminates. It was found that the internal damage at each stage (matrix cracks, debonds in the weft, successive debonds in the warp and ‘metadelaminations’ between warps and wefts) occurred near the cross-over point of the fabric. The modulus decay mechanism was explained by considering the progression of this internal damage. From the end of the first stage to the beginning of the middle stage, a characteristic damage state (CDS) (called a ‘meta-CDS’) was observed. It was found that woven composites have a unit area of damage accumulation (called a ‘unit cell’) and the damage of each unit cell and its distribution control the total fatigue damage of the material.     

Analysis of an Electromagnetic Field Created by Line Current Using Constrained Interpolation Profile Method

Development of accurate schemes is a technical issue related to calculation of electromagnetic fields. This study uses constrained interpolation profile (CIP) method to analyze electromagnetic fields created by line current. This is a novel method proposed by Yabe. Comparison of results obtained using finite difference time domain (FDTD) analysis and CIP analysis indicates that CIP analysis provides higher accuracy using identical discretization. In addition, given the same level of accuracy, CIP analysis requires less memory and less calculation time     

Adsorption of synthetic polyelectrolytes on colloidal spheres

Summary The adsorption of synthetic polyelectrolytes on the surfaces of monodisperse polystyrene spheres and colloidal silica spheres is studied by electrophoretic mobility measurements. Electrolytes used are NaCl, CaCl₂, LaCl₃, Na₂SO₄, sodium poly(ethylenesulfonate) (NaPES), sodium poly(styrenesulfonate) (NaPSS), polybrene^? (PB), poly-4-vinyl-N-ethylpyridinium bromide (C2PVP), poly-4-vinyl-N-benzylpyridinium chloride (BzPVP), and copolymer of 4-vinyl-N-benzylpyridinium chloride (95%) and 4-vinyl-N-n-hexadecylpyridinium bromide (5%) (C16BzPVP). Electrophoretic velocity (u) and the effective charge number (α) of a colloidal sphere increase in the presence of PB, C2PVP, BzPVP, and C16BzPVP, and turn to the positive from the negative values in their absence. Addition of NaPES and NaPSS further decreases u and α values. Adsorption of the polymers on the colloidal spheres are explained by the hydrophobic and/or dipoledipole interactions in addition to the electrostatic forces. Weak adsorption of simple electrolytes on the colloidal spheres is deduced from the electrophoretic measurements.     

High-rate Decoupled Water Electrolysis System Integrated with α-MoO3 as a Redox Mediator with Fast Anhydrous Proton Kinetics

Hydrogen is a promising alternative to fossil fuels that can reduce greenhouse gas emissions. Decoupled water electrolysis system using a reversible proton storage redox mediator, where the oxygen evolution reaction and hydrogen evolution reaction are separated in time and space, is an effective approach to producing hydrogen gas with high purity, high flexibility, and low cost. To realize fast hydrogen production in such a system, a redox mediator capable of releasing protons rapidly is required. Herein, α-MoO₃, with an ultrafast proton transfer property that can be explained by a dense hydrogen bond network in the lattice oxygen arrays of HxMoO₃, is examined as a high-rate redox mediator for fast hydrogen production in acidic electrolytes. The α-MoO₃ redox mediator shows both a large capacity of 204 mAh g⁻¹ and fast hydrogen production at a current rate of 10 A cm⁻²(≈153 A g⁻¹), outperforming most of the previously reported solid-state redox mediators.     

Band 3 protein: physiology, function and structure

Band 3 protein is a typical polytropic membrane protein and mediates the exchange of the cellular HCO3- with CI- in plasma, which has been known as the "Chloride Shift". Owing to the "Chloride Shift", red blood cells can discriminate the metabolically active cells from inactive cells and deliver oxygen particularly to metabolically active tissues that produce carbon dioxide. Thus, band 3 protein is a sensor for metabolically active tissues and no excess oxygen is supplied to tissues as far as oxygen is delivered by red blood cells. In this chapter, we review the physiological role of the anion exchange mediated by band 3 protein and our work concerning the structure and function relationship in band 3 protein, that, is, affinity labeling of the active center for the anion exchange with pyridoxal phosphate, conformational change during the anion exchange process, examination of fidelity of hydropathy prediction on band 3 protein, and phosphoenolpyruvate transport mediated by band 3 protein and its clinical application.     

Application of functionally graded material for solid insulator in gaseous insulation system

Functionally graded materials (FGM) have spatial distribution of a material property in order to achieve efficient stress control. An application of the FGM to a solid insulator (spacer) for a gaseous insulation system, like gas insulated switchgear, is expected to improve electric field (E-field) distribution around the spacer. In this paper, we describe the applicability of the FGM spacer to gas insulated power equipment. In the FGM spacer, we gave spatial distribution of dielectric permittivity to control the E-field distribution inside and outside the spacer. This paper includes following key results for the applications of the FGM. Firstly, E-field simulation results when applying the FGM by a finite element method are presented, in which we show the effective reduction of the maximum field strength by applying the FGM. Next, a fabrication technique of the FGM spacer sample with not only step-by-step but also continuous changes of permittivity is presented by use of centrifugal force. Finally, dielectric breakdown tests using FGM samples which are accurately controlled the spatial distribution of permittivity are carried out under lightning impulse voltage applications. The test result indicates the increase of breakdown voltage (BDV). From these results, we verified the applicability and the fabrication technique of FGM spacer for improvement of the dielectric strength in the gaseous insulation system.     

Real-time and high-speed measurements of charging processes on dielectric surface in vacuum

In order to investigate the charging mechanisms of solid dielectrics in vacuum, we constructed real-time and high-speed measurement systems for charge density, current pulse, light emission and applied voltage. By applying a negative DC ramped voltage to an electrode with a cathode triple-junction (TJ), we measured the temporal variation of surface charge accumulation and current pulse waveforms expressing the electron emission from TJ, by electrostatic probes. From the measurement results, we explain the step like charging process and propose an electron emission model by taking the electric field and its relaxation by charging into account. In addition, we elucidate the relationship between the charging process and the location of electron emission.     

Charge behavior in flowing oil in oil/ pressboard insulation system by electro-optic field measurement

The electrical insulation structure of most power transformers is a combination of insulating oil and solid materials. One of the crucial problems we face in transformer operation is flow electrification, which occurs at a flowing oil/solid material interface. Thus, for the transformer insulation design, we need to clarify the now electrification phenomena. In this paper, we measured the electric field strength in an oil/pressboard composite insulation system using an electro-optic method of the Kerr effect. We obtained the time variation of electric field distribution in both flowing uncharged and charged oil. It is notable that we could quantitatively clarify the electric field distortion in flowing charged oil by flow electrification. Furthermore, we measured the leakage current from divided electrodes and derived a charge density distribution along the flow direction. Finally, we quantitatively discussed the electric field distribution and the charge behavior from the measurement results.