Estimation of Small Reservoir Storage Capacities with Remote Sensing in the Brazilian Savannah Region

Small reservoirs play an important role in supporting the local economy in the savannah areas of Brazil and are primarily used for the provision of water for irrigation and watering livestock. Hundreds of small reservoirs have been built in the last few decades in the Preto River Basin, but efficient water management and sound planning are hindered by inadequate knowledge of the number, storage capacity and spatial distribution of reservoirs in the basin. The main reason for the lack of this information is that current methodologies for quantifying the physical parameters of reservoirs are laborious, time consuming and costly. To address this lack of data, a simple method to estimate reservoir storage volumes based on remotely sensed reservoir surface area measured with LANDSAT was developed. The method was validated with a subset of reservoirs in the Preto River Basin for which surface areas, shapes and depths were determined with ground-based survey measurements. The agreement between measured and the remotely sensed reservoir volumes was satisfactory, indicating that remotely-sensed images can be used for improved management of water in the Brazilian Savannah region. With the newly developed methods we found that the Preto River Basin’s 147 small reservoirs can store 19 × 10⁶ m³ of water at full capacity.     

Impact of dissolved organic matter on colloid transport in the vadose zone: deterministic approximation of transport deposition coefficients from polymeric coating characteristics

Although numerous studies have been conducted to discern colloid transport and stability processes, the mechanistic understanding of how dissolved organic matter (DOM) affects colloid fate in unsaturated soils (i.e., the vadose zone) remains unclear. This study aims to bridge the gap between the physicochemical responses of colloid complexes and porous media interfaces to solution chemistry, and the effect these changes have on colloid transport and fate. Measurements of adsorbed layer thickness, density, and charge of DOM-colloid complexes and transport experiments with tandem internal process visualization were conducted for key constituents of DOM, humic (HA) and fulvic acids (FA), at acidic, neutral and basic pH and two CaCl₂ concentrations. Polymeric characteristics reveal that, of the two tested DOM constituents, only HA electrosterically stabilizes colloids. This stabilization is highly dependent on solution pH which controls DOM polymer adsorption affinity, and on the presence of Ca⁺² which promotes charge neutralization and inter-particle bridging. Transport experiments indicate that HA improved colloid transport significantly, while FA only marginally affected transport despite having a large effect on particle charge. A transport model with deposition and pore-exclusion parameters fit experimental breakthrough curves well. Trends in deposition coefficients are correlated to the changes in colloid surface potential for bare colloids, but must include adsorbed layer thickness and density for sterically stabilized colloids. Additionally, internal process observations with bright field microscopy reveal that, under optimal conditions for retention, experiments with FA or no DOM promoted colloid retention at solid-water interfaces, while experiments with HA enhanced colloid retention at air-water interfaces, presumably due to partitioning of HA at the air-water interface and/or increased hydrophobic characteristics of HA-colloid complexes.     

Visualization of unstable water flow in a fuel cell gas diffusion layer

Modeling two-phase flow in proton exchange membrane (PEM) fuel cells is hampered by a lack of conceptual understanding of flow patterns in the gas diffusion layer (GDL). In this paper, pore-scale visualizations of water in different types of GDLs were used to improve current understanding of flow and transport phenomena in PEM fuel cells. Confocal microscopy was used to capture the real-time transport of water, and pressure micro-transducers were installed to measure water breakthrough pressures. Three types of fuel cell GDLs were examined: TO series (Toray Corp., Tokyo, Japan), SGL series (SGL Carbon Group, Wiesbaden, Germany), and MRC series (Mitsubishi Rayon Corp., Otake City, Japan). The visualizations and pressure measurements revealed that despite difference in “pore” structures in the three types of GDLs, water followed distinct flow paths spanning several pores with characteristics similar to the “column flow” phenomena observed previously in hydrophobic or coarse-grained hydrophilic soils. The results obtained from this study can aid in the construction of theories and models for optimizing water management in fuel cells.     

Mapping and interpreting soil textural layers to assess agri-chemical movement at several scales along the eastern seaboard (USA)

Despite numerous cases of groundwater contamination with agricultural chemicals on layered sandy soils, monitoring and prediction of the fate of these chemicals in the vadose zone has eluded researchers and bureaucrats alike so far. To aid in a better understanding of this phenomena, the movement and fate of agricultural chemicals were assessed at different scales for the (sandy and layered) floodplain soil occurring along the Eastern Seaboard. At the point and field scale ground penetrating radar was used to locate the coarse sand lenses and tracer experiments were initiated to study the flow pattern of the chemicals. Results show that water and solutes moved over the coarse layers and were funneled into fingers bypassing most of the soil matrix and reaching the groundwater much faster than when the solute would move evenly through the vadose zone. At field scale a computer simulation indicated that the exact location of the layers does not have to be known for calculating travel times, indicating that pedo-transfer functions could be developed for calculating groundwater pollution potential for different combinations of soil and chemicals. In the future, groundwater pollution on a regional scale can be predicted by using these pedo-transfer functions in a Geographic Information System.     

Correlation equation for predicting attachment efficiency (α) of organic matter-colloid complexes in unsaturated porous media

Naturally occurring polymers such as organic matter have been known to inhibit aggregation and promote mobility of suspensions in soil environments by imparting steric stability. This increase in mobility can significantly reduce the water filtering capacity of soils, thus jeopardizing a primary function of the vadose zone. Improvements to classic filtration theory have been made to account for the known decrease in attachment efficiency of electrostatically stabilized particles, and more recently, of sterically stabilized particles traveling through simple and saturated porous media. In the absence of an established unsaturated transport expression, and in the absence of applicable theoretical approaches for suspensions with asymmetric and nonindifferent electrolytes, this study presents an empirical correlation to predict attachment efficiency (α) for electrosterically stabilized suspensions in unsaturated systems in the presence of nonideal electrolytes. We show that existing models fall short in estimating polymer-coated colloid deposition in unsaturated media. This deficiency is expected given that the models were developed for saturated conditions where the mechanisms controlling colloid deposition are significantly different. A new correlation is derived from unsaturated transport data and direct characterization of microspheres coated with natural organic matter over a range of pH and CaCl(2) concentrations. The improvements to existing transport models include the following: adjustment for a restricted liquid-phase in the medium, development of a quantitative term to account for unsaturated transport phenomena, and adjustments in the relative contribution of steric stability parameters based on direct measurements of the adsorbed polymer layer characteristics. Differences in model formulation for correlations designed for saturated systems and the newly proposed correlation for unsaturated systems are discussed, and the performance of the new model against a comprehensive set of experimental observations is evaluated.     

Distribution of colloid particles onto interfaces in partially saturated sand

Colloids have long been known to facilitate the transport of contaminants in soils, but few direct observations have been made of transport and retention in unsaturated porous media. Studies have typically been limited to evaluation of column breakthrough curves, resulting in differing and sometimes conflicting proposed retention mechanisms. We carried out pore scale visualization studies of colloid transport in unsaturated quartz sand to directly observe and characterize colloid retention phenomena. Synthetic hydrophilic (0.8, 2.6, and 4.8 microm carboxylated polystyrene latex) and relatively hydrophobic (5.2 microm polystyrene latex) colloidal microspheres were added to steady-state water flow (0.15 mm min(-1)) applied to an inclined infiltration chamber. Bright field microscopy was used to determine the positions and movement of water and colloids. Confocal laser scanning microscopy was used to determine water film geometry in an unsaturated horizontal chamber. We determined mechanisms of hydrophilic colloid retention at what is generally termed the air/water/solid (AWS) interface. Based on our observations, the AWS interface is here more accuratelytermed the air/water meniscus/solid (AWmS) interface, denoting the region where between-grain water meniscii diminish to thin water films on the grain surfaces. Colloids were retained at the AWmS interface where the film thickness approximately equaled colloid diameters. The greater retention for hydrophilic colloids at this interface (compared to elsewhere in the solid/water interface) can be explained by the additional surface tension capillary potentials exerted on colloids at the AWmS interface. While some 0.8-microm colloids were observed in thin water films, film straining played no significant role in the retention of larger colloids. Mechanisms for slightly hydrophobic colloids differed slightly. In addition to primary retention at the AWmS interface, hydrophobic colloids attached to others already present atthat interface resulting in apparent retention at the air/water (AW) interface. Attachment of hydrophobic colloids was also observed at water-solid interfaces, as hydrophobicity impelled the colloids to avoid water. Factors contributing to retention of slightly hydrophobic colloids were sand grain roughness and possibly a tendency for these colloids to flow near surfaces and interfaces, consonant with the enhanced retention of hydrophobic colloids (relative to hydrophilic colloids) observed in the literature.     

Prüfung von Vakuumpumpen zur Verwendung in explosionsgefährdeten Bereichen nach der Richtlinie 94/9/EG (ATEX 95).

In the following article are described the fundamentals of the EC Type Examinations of vacuum pumps. The essential components of the test are mentioned and explained. Proceeding on the present experiences at the test of vacuum pumps, references for the preparations of EC Type Examinations and for the design of the test samples are given. References for the suitable design of vacuum equipment are mentioned.     

Including Source-Specific Phosphorus Mobility in a Nonpoint Source Pollution Model for Agricultural Watersheds

Most widely used nonpoint source models associate pollutant loads almost exclusively with land use via pollutant export coefficients and some kind of runoff coefficient. Not surprisingly, the range of management options suggested by such models’ simulations are largely linked to changes in land use. This problem is addressed by developing models of dissolved phosphorus (DP) mobility for specific agricultural sources: manure, fertilizers, soil/plant complexes, and impervious surfaces and those associated with baseflow P loads. These models are coupled with a spatially distributed hydrologic model, the variable source loading function model. The model was applied to a small (164?ha), upstate New York watershed and tested against 1996–2000 stream flow and DP data. The source-specific model required no direct calibration of parameters compared to eight parameters needed in a similar export coefficient type model. Both models predicted stream DP loads well but the source-specific model provided additional insights into, for example, how much DP in the stream was derived from accumulated soil P as opposed to direct leaching from manure. This type of information is necessary to develop and assess a full range of options for best management practices, especially those that involve nonstatic activities such as manure spreading.     

Second law analysis of momentum and heat transfer in unit operations

Momentum and heat transfer in complex systems always is the sum of single and simple transfer elements here called unit operations. They are usually characterised by head loss coefficients and Nusselt numbers as far as the flow and the heat transfer aspect is concerned. In our study we show that this is insufficient for a complete assessment and that additional parameters should be introduced. They take into account that energy, its use and conversion always is subject to the constraints set by the second law of thermodynamics.     

1.3 ?m/1.5 ?m bidirectional WDM optical-fibre transmission system experiment at 144 Mbit/s

Results are reported of a 1.3 ?m/1.5 ?m bidirectional WDM transmission system experiment operating at 144 Mbit/s over 58 km of cabled single-mode fibre. Regenerators used Bell Laboratories-developed 1.3 and 1.5 ?m InGaAsP semiconductor lasers, InGaAs PIN diodes, microwave monolithic amplifiers and optical bidirectional couplers.