Influence of Different Additives on the Interaction of Quinolone Antibiotic Drug with Surfactant: Conductivity and Cloud Point Measurement Study

Conductometric and cloud point (CP) measurement studies have been performed to investigate the interaction of tetradecyltrimethylammonium bromide (TTAB) and Triton® X-100 (TX-100) with ciprofloxacin hydrochloride (CFH) in different solvents over the temperature range of 295.15–315.15 K. CFH is used for the treatment of various bacterial infections. The observed critical micelle concentration (CMC) values of TTAB were found to be reduced in the presence of electrolytes (Na₂SO₄/Na₃PO₄), and this reduction proceeds with the elevation of salt concentration. The order of the CMC of TTAB follows the trend: > >. The observed CMC values of TTAB were found to increase with increasing temperature and decrease with increasing concentration of CFH in aqueous medium. The values of Gibbs free energy of micellization () for the TTAB/TTAB + CFH mixture were found to be negative, implying spontaneous micellization. The estimated CP of TX-100 decreases with increasing concentration of TX-100 in aqueous medium. The CP values first decrease with increasing concentration of CFH and then increase at higher concentration of CFH almost in all cases investigated. The values of free energy of clouding were found to be positive in all cases studied implying that phase separation of TX-100 was nonspontaneous. The other thermodynamic parameters associated with the micellization of TTAB and the phase separation of TX-100 were estimated and explained.     

Interaction of triton X-100 on silica: A relationship between surface characteristics and adsorption isotherms

Adsorption of Triton X-100 on various silica substrates has been investigated. A number of solids, including a natural quartz, this quartz washed with HCl acid and subsequently heated at 1273 K; two aerosils and one Kieselgel silicas were studied. These solids exhibit surface areas in the range of 5 to 430 m² g^?1. All the Triton adsorption isotherms display an S-shape at the adsorption temperatures studied (298 and 308 K). It has been found that the pretreatments of natural quartz (by water washing, impurities removed by acid and/or high temperature calcination) affect considerably the amounts of TX-100 adsorbed. Measurements of surface composition have been made by X-ray photoelectron spectroscopy (XPS) with particular emphasis on the presence of impurities and on the number of OH groups at the surface of the samples. The nature of the surface hydroxyl has also been studied by infrared spectroscopy. Furthermore, the specific number of hydroxyl groups on the surface of the silica samples has been determined by thermogravimetric analysis. Finally an attempt to correlate solid surface characteristics with adsorption isotherms has been developed.     

φ100mm定径机轧辊孔型设计改进

针对定径机换辊后定径钢管所出现的质量问题,提出了成品机架的轧辊孔型不分配变形量和适当增大孔型直径的改进措施。     

等离子体横向刻蚀硅的特性研究

研究了用SiO2 +Al作掩模 ,SF6 +O2 混合气体等离子体对Si的横向刻蚀 ,其结果表明 ,在SF6 +O2 等离子体气氛中 ,Al是很好的保护膜 ,可以在待悬浮器件下形成大的开孔。因此 ,预计用这种技术 ,可以在Si片上集成横向尺寸为数百微米 ,具有优良高频性能的MEMSRF/MW无源器件 ,如开关、传输线、电感和电容等。     

高纯氯化锂中微量铜、锌、铁、锰的测定-Tritonx-100增感原子吸收光谱法

采用Tritonx-100为铜、锌、铁、锰的增感剂,对高纯氯化锂中的铜、锌、铁、锰进行了原子吸收光谱分析,结果令人满意。其特征浓度铜为0．018μg．ml-1／1％吸收、锌为0．004μg．ml-1／1％吸收、铁为0．021μg．ml-1／1％吸收,锰为0．011μg．ml-1／1％吸收。     

外高桥900MW超临界汽轮机的合作制造概况

简述了上海汽轮机有限公司(STC)与西门子公司首次合作制造的目前国内最大容量的外高桥900MW超临界机组的一些基本情况，介绍了在合作制造中为保证生产进度和质量而采取的工艺改进、技术攻关等措施，以及通过合作制造提升了我公司的制造能力和管理水平。     

火电仿真技术研究

在电力行业中，计算机仿真一直是不可缺少的工具，它在减少损失、节约经费、提高效率、确保安全经济运行等方面发挥了巨大作用。主要介绍了计算机仿真技术在660MW火电站中的具体应用情况。以邯峰发电厂^#1机为对象，采用STAR-90仿真支撑系统，建立起660MW火电机组1：1仿真机，并在机组投产前建成，取得了良好的培训效果。论述了火电站仿真机未来的发展趋势，包括开发高精度机理性仿真数学模型以及真实的DCS仿真模型、进行性能计算与故障诊断、应用于热工人员培训及机组调试等。     

pH传感器温度补偿模型研究

水质pH值在线监测对提高水产品健康养殖至关重要,本文将无线传感器网络与pH值传感器相集成,设计了pH值监测的无线传感器网络系统。为克服pH值测量过程中温度对测量结果的影响,提出了一种pH传感器温度补偿模型,该模型通过pH传感器和PT100铂电阻温度传感器分别测量溶液的pH值和温度,利用最小二乘法对pH值和电压进行线性分析,建立pH传感器的温度补偿模型。实验结果表明,该补偿模型测量精度高,能够实现较精确的pH值在线监测。     

台塑公司高密度聚乙烯专用树脂的开发策略

介绍了台湾塑胶工业股份有限公司高密度聚乙烯(HDPE)树脂的生产装置、工艺技术、生产能力、树脂牌号及新产品开发现状,同时阐述了HDPE专用树脂的开发策略。目前,台塑公司HDPE商品牌号台塑烯的产品包括薄膜专用树脂、中空吹塑专用树脂、挤出专用树脂和注塑等用树脂等,并且产品具有单峰、双峰甚至宽峰相对分子质量分布的特性。2006年,台塑公司将调整台塑烯专用树脂的生产比例,强化产品结构而维持一定的营利水平。