盒厚不均对STN-LCD显示"黑斑"形成的影响

在制造STN-LCD产品中,STN—LCD显示“黑斑”缺陷是显示不匀缺陷的一种．用CG-100液晶显示器延迟量与扭曲角测试系结合EO-100电光测试系统,将“黑斑”缺陷区与正常显示区的盒厚、电光性质作了比较,并用偏光显微镜观察了“黑斑”,分析了“黑斑”缺陷的形成实质．基于实验,给出了有可能造成“黑斑”缺陷的相关工艺过程,并对有可能导致产生该缺陷的工艺条件作了分析．     

Influence of heating source position and dilution rate in achieving overmatched dissimilar welded joints

Abstract

The investigation addresses the overall performance of black and white joints (BWJ) of low carbon steel (LCS) and stainless steel thin sheets achieved by laser hybrid welding. Assuming that the structural integrity is directly influenced by the processing temperature, a thermal simulation of BWJ of thin sheets was developed. Afterwards, the base metals apportionment at joint formation, namely their distinct dilution rate, was originally estimated from the top surface temperature variation. Defect-free laser hybrid dissimilar welds were experimentally obtained using the selected filler metal and the energetic input from the process simulation, even for a critical analysed case of heat source displacement from the weld gap centreline towards LCS. Detailed macro and microstructural examination of the BWJ and related microhardness analysis results are presented. The tensile tests results indicate that in the case of transversally loaded BWJ, the positive difference in yield between the weld metal and the base materials protects the weld metal from being plastically deformed; the flat transverse tensile specimens loading up to failure reveals large strains in LCS, far away from the weld.     

黑米色素的性质及光稳定化剂的研究

研究了黑米色素的性质和光降解动力学方程 ,以及黑米色素的光稳定化剂对色素的辅助成色和护色的影响。结果表明 ,黑米色素光降解服从零级反应动力学方程 ,添加黄酮化合物及改性黄酮化合物可使黑米色素对光稳定性有较大提高     

Minimisation of toxicity in nickel ferrite black pigment

Abstract

Black ceramic pigments are usually prepared from a mixture of transition metal oxides, including toxic and hazardous elements such as Ni, Co, Cr, and Mn. Spinel type black ceramic pigments based on Ni(Fe,Cr)₂O₄ prepared by a ceramic method have been optimised to reduce toxic and hazardous components. Ni (an A1 carcinogen as classified by ACGIH)has been partially substituted by inert elements such as Mg and Zn and the content of Cr (an A1 carcinogen in hexavalent form) has been minimised, to obtain a black ceramic pigment in which the important properties (colour and stability) are maintained. The black pigments obtained have been glazed and compared with commercial pigments. While maintaining adequate colouring properties, the concentration of toxic elements in the composition has been reduced.     

Elastomeric and electrically conductive materials on basis of thermoplastic elastomers and their controlled manufacturing

Abstract

The present work presents a possibility to produce a rubber elastic and electrically conductive polymer material on the basis of dynamic vulcanisates. Thanks to the specific morphology of dynamic vulcanisates and the non-uniform carbon black distribution, carbon black filled dynamic vulcanisates can exhibit a very low percolation threshold of ～4 wt-%. Keeping the carbon black content low, a broad spectrum of resistivity properties can be achieved by variation of material factors like type and content of rubber phase and filler, concentration of cross-linking agent and compatibiliser and technological factors like mixing time respectively. In comparison with thermoplastic elastomers on the basis of block copolymers dynamic vulcanisates show a distinct lower percolation threshold. Up to a carbon black content of ～10 wt-% the mechanical properties of carbon black filled dynamic vulcanisates are not negative influenced essentially. To characterise the development of the carbon black dispersion and distribution processes and the conductivity properties in an internal mixer, the method of online measured electrical conductivity is suited very well for carbon black containing rubber mixtures. It could be shown in pre-investigations that this method promises to be a very useful tool for monitoring the mixing processes of carbon black filled dynamic vulcanisates in continuous mixing processes by means of extruders too.     

Effects of moisture and temperature ageing on reliability of interfacial adhesion with black copper oxide substrate

The reliability of adhesion performance of bare Cu, as-deposited and surface-hardened black oxide coatings on Cu substrates was studied. The interfacial adhesion with a polyimide adhesive tape and an epoxy moulding compound was measured using the button shear and tape peel tests after hygrothermal ageing in an autoclave, high temperature ageing and thermal cycles. Moisture adsorption and desorption studies at different aging times suggested that the black oxide coating was effective in reducing the moisture adsorption. The bond strengths for all substrates remained almost unchanged after thermal ageing at 150°C for 8 h. Thermal cycling between ?50°C and 150°C for 500 cycles reduced by about 20% the button shear strength of the as-deposited black oxide substrate, but it did change much the bonding performance of the bare Cu substrate. Hygrothermal ageing at 121°C/100% RH in an autoclave was most detrimental to adhesion performance because of the combined effect of elevated temperature and high humidity. The reduction in button shear strength after the initial ageing for 48 h was 50–67%, depending on the type of coating. In all accelerated ageing tests, the residual interfacial bond strengths were consistently much higher for the black-oxide-coated substrates than the bare Cu surface, confirming a higher reliability of black oxide coating. Fracture surfaces analysis of tape-peeled bare copper substrates after 500 cycles of thermal loading revealed a transition in failure mechanism from interfacial to cohesive failure. In contrast, the failure mechanism remained unchanged for black-oxide-coated substrates. The observations made from the button shear and tape peel tests were generally different because of the different fracture modes involved.     

Tensile Strength of Joints Bonded With a Nano-particle-Reinforced Adhesive

In order to improve the tensile lap shear strength of adhesively bonded joints, nano-particles were dispersed in the adhesive using a 3-roll mill. The dispersion states of nano-particles in the epoxy adhesive were observed with TEM (Transmission Electron Microscopy) with respect to the mixing conditions, and the effect of nano-particles on the mechanical properties of the adhesive was measured with respect to dispersion state and weight content of nano-particles. Also the static tensile load capability of the adhesively bonded double lap joints composed of uni-directional glass/epoxy composite and nano-particle-reinforced epoxy adhesive was investigated to assess the effect of nano-particles on the lap shear strength of the joint. From the experimental and FE analysis results, it was found that the nano-particles in the adhesive improved the mechanical properties of the adhesive. Also the increased failure strain and the reduced CTE (coefficient of thermal expansion) of the nano-particle-reinforced adhesive improved the lap shear strength of adhesively bonded joints.     

Surface characteristics and adhesion performance of black oxide coated copper substrates with epoxy resins

Black oxide is a conversion coating applied onto the copper substrate to improve its interfacial adhesion with polymeric adhesives. A comprehensive study is made to characterize the black oxide coating using various characterization techniques, including SEM, XPS, AFM, XRD, Auger electron spectroscopy, TEM, D-SIMS, RBS and contact angle measurements. It was found that the oxide coating consisted of cupric and cuprous oxide layers from the top surface to inside. The cuprous oxide layer was formed on the copper crystal surface, on which densely-packed fibrillar cupric oxide grew continuously until saturation. The cupric oxide had a fibrillar structure with high roughness at the nanoscopic scale, whereas the cuprous oxide was rather flat and granular. There was a continuous change in oxide composition with no distinct boundary between the two oxide layers. The bond strength between the epoxy resin and the oxide coated copper substrate increased rapidly at a low level of oxide thickness, and became saturated at thicknesses greater than about 800 nm. There were similar dependences of bond strength on surface roughness, oxide thickness especially of cupric oxide and surface energy, reflecting the importance of these surface characteristics in controlling the interfacial adhesion.     

Adhesion Characteristics of Carbon Black Embedded Glass/Epoxy Composite

The surface of glass/epoxy composite material was embedded with carbon black which was dispersed in methyl ethyl ketone (MEK) during the curing process to enhance the adhesion strength of the glass/epoxy composite structure. The morphological effect of the carbon black on the surface of composite was observed using scanning electron microscopy (SEM) and atomic force microscopy (AFM). Quantitative chemical bonding analysis with X-ray photoelectron spectroscopy (XPS) was also performed to observe chemical bonding states on the surface. The lap shear strength of the glass/epoxy composite adhesive joints where composite adherends were embedded with carbon black was investigated with respect to the type and amount of embedment. Also, the tensile properties of the carbon black embedded glass/epoxy composites were measured to observe the mechanical degradation of the composite due to the MEK. The surface free energies of carbon black embedded composites were determined from the van Oss–Chaudhury–Good equation to correlate the lap shear strength of the adhesive joints with the surface free energies of composite adherends. From the experimental results, it was found that the carbon black embedment of the composite adherend improved much the bond strength due to the increased surface roughness on nano-scale as well as increased surface free energy.     

Macro- and microdispersion of carbon black in liquid silicone rubbers

Abstract

A correlation between the online during mixing measured conductance of carbon black (CB) filled silicone rubber and macrodispersion of CB determined by optical microscopy and microdispersion analysed by AFM has been established. The online conductance is a suitable tool to characterise the effect of technological parameters (e.g. rotor type, speed, mixing temperature) and material parameters (matrix viscosity, CB type and content) on the macro- and microdispersion directly during the mixing process. Thus, a modified method of the online conductance measurement can be used as the in-process method for monitoring the production process of electrical conductive polymer materials with low viscosity, e.g. liquid silicone rubbers.