用二甲基二氯硅烷水解物代替混合环体生产107甲基室温硫化硅橡胶

分析了１０７甲基室温硫化硅橡胶生产中造成粘度波动和收率较低的因素，通过改变原料，用二甲基二氯硅烷水解物代替甲基混合环体，提高了产品收率、降低了成本，粘度也易于控制     

21世纪的绿色基础化学原料--碳酸二甲脂

综述碳酸二甲酯(DMC)的生产开发和应用.     

新型疏水沉淀二氧化硅的制备

以沉淀二氧化硅的半成品为原料,用DMC(二甲基聚环硅氧烷)进行表面改性,得到疏水度为29.9%的疏水二氧化硅产品。实验研究了DMC用量、改性时间、体系酸度、异丙醇的加入量及表面活性剂的添加等因素对改性效果的影响。结果表明,异丙醇和表面活性剂(Tween-20)的加入及酸性介质对提高产品改性效果影响显著;改性后样品的DBP、比表面积以及孔隙度均下降,说明改性后产品结构排布更加紧密,部分微孔被堵塞封闭。该方法具有工艺简单、成本较低、无有害腐蚀气体产生等优点。     

Poly(pyridine-2,5-diyl)–CuCl2 catalyst for synthesis of dimethyl carbonate by oxidative carbonylation of methanol: catalytic activity and corrosion influence

A -conjugated polymer, poly(pyridine-2,5-diyl) (PPy) was investigated as a support for CuCl₂ in the synthesis of dimethyl carbonate by oxidative carbonylation of methanol. The PPy–CuCl₂ adduct had high catalytic activity which was comparable to that of the homogeneous CuCl₂ catalyst. The adduct caused corrosion of stainless-steel vessels only to minor extent, compared with the homogeneous CuCl₂ catalyst. This PPy–CuCl₂ catalyst was easily recycled by filtration and showed a similar catalytic activity in the third time use. The presence of the -conjugated system in PPy, through which electrons can move, may bring about the high catalytic activity for the oxidative carbonylation of methanol, which involves Cu(II)/Cu(I) redox processes.     

Ionic liquids as electrolytes

Salts having a low melting point are liquid at room temperature, or even below, and form a new class of liquids usually called room temperature ionic liquids (RTIL). Information about RTILs can be found in the literature with such key words as: room temperature molten salt, low-temperature molten salt, ambient-temperature molten salt, liquid organic salt or simply ionic liquid. Their physicochemical properties are the same as high temperature ionic liquids, but the practical aspects of their maintenance or handling are different enough to merit a distinction. The class of ionic liquids, based on tetraalkylammonium cation and chloroaluminate anion, has been extensively studied since late 1970s of the XX century, following the works of Osteryoung. Systematic research on the application of chloroaluminate ionic liquids as solvents was performed in 1980s. However, ionic liquids based on aluminium halides are moisture sensitive. During the last decade an increasing number of new ionic liquids have been prepared and used as solvents. The general aim of this paper was to review the physical and chemical properties of RTILs from the point of view of their possible application as electrolytes in electrochemical processes and devices. The following points are discussed: melting and freezing, conductivity, viscosity, temperature dependence of conductivity, transport and transference numbers, electrochemical stability, possible application in aluminium electroplating, lithium batteries and in electrochemical capacitors.     

苯氨基甲酸酯催化合成研究进展

综述了国内外苯氨基甲酸酯合成方法和催化剂的研究进展,重点阐述了近年来以苯胺和碳酸二甲酯(DMC)为原料,合成苯氨基甲酸甲酯(MPC)催化剂的研究进展.同时对今后催化合成路线的研究和发展进行了讨论和分析,由苯胺和DMC合成MPC,副产物甲醇回收合成DMC,是零排放绿色工艺,其研究方向是开发出活性和选择性高的负载型催化剂.     

Repair approach for DMC images based on hierarchical location using edge curve

The color composite digital mapping camera (DMC) images are produced by the post-processing software of Z/I imaging. But the failure of radiometric correction in post-processing leads to residual radiometric differences between CCD images, which then affect the quality of the images in further applications. This paper, via analyzing the characters and causes of such a phenomenon, proposes a repair approach based on hierarchical location using edge curve. The approach employs a hierarchical strategy to locate the transition area and seam-line automatically and then repair the image through the global reconstruction between CCD images and the local reconstruction in the transition area. Experiments indicate that the approach proposed by this paper is feasible and can improve the quality of images effectively. Supported by the National Basic Research Program of China (Grant No. 2006CB701302) and the Youth Fundation Plan of Wuhan (Grant No. 200750731253)     

单级倒立摆的LQR控制和DMC控制Matlab仿真比较

建立了单级直线倒立摆的状态空间模型,分别从线性最优二次型（LQR）控制和模型预测控制的原理出发,在MAT-LAB/SIMULINK环境下,设计了LQR控制器和动态矩阵控制（DMC）控制器,对所建立的倒立摆模型对象进行系统控制仿真。仿真结果表明,作为先进控制的DMC控制的效果比作为最优控制的LQR控制效果更好,鲁棒性更强。     

基于神经网络非线性模型的多级工作点阶跃响应扩展DMC预测控制

利用前馈神经网络建立对象的非线性预测模型,在不同工作点做阶跃响应,建立其局部线性模型,用隶属函数将局部线性模型加权得到全局线性模型,全局线性模型用于滚动优化,非线性模型用于预测系统输出和校正线性模型,实现非线性预测控制,仿真结果表明该方法控制效果良好,可满足实时要求。     

一种多变量系统分散优化DMC算法

提出一种多变量系统的分散优化动态矩阵控制（ＤＭＣ）算法,该处冯动 经的特点,将多变量系统ＤＭＣ算法分散为若干单变量系统的ＤＭＣ算法,使多变量ＤＭＣ算法参数设计和算法求解计算人为简化。