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排序方式: 共有1252条查询结果,搜索用时 562 毫秒
1.
Jinfeng Zeng Zhiting Liu Hanbo Zou Wei Yang Haosen Fan Haijun Yu Shengzhou Chen 《金属学报(英文版)》2021,34(8):1153-1162
A appropriate size with three-dimension(3 D) channels for lithium diffusion plays an important role in constructing highperforming LiNi_(0.5)Mn_(1.5)O_4(LNMO) cathode materials, as it can not only reduce the transport path of lithium ions and electrons, but also reduce the side effects and withstand the structural strain in the process of repetitive Li~+ intercalation/deintercalation. In this work, an e fficient method for designing the hollow LNMO microsphere with 3 D channels structure by using polyethylene oxide(PEO) as soft template agent assisted solvothermal method is proposed. Experimental results indicate that PEO can make the reagents mingle evenly and nucleate slowly in the solvothermal process, thus obtaining a homogeneous distribution of carbonate precursors. In the final LNMO products, the hollow 3 D channels structure obtained by the decomposition of PEO and carbonate precursor in the calcination can provide abundant electroactive zones and electron/ion transport paths during the charge/discharge process, which benefits to improve the cycling performance and rate capability. The LNMO prepared by adding 1 g PEO possesses the most outstanding electrochemical performance, which presented an excellent discharge capacity of 143.1 mAh g~(-1) at 0.1 C and with a capacity retention of 92.2% after 100 cycles at 1 C. The superior performance attributed to the 3 D channels structure of hollow microspheres, which provide uninterrupted conductive systems and therefore achieve the stable transfer for electron/ion. 相似文献
2.
Nd3+:Y0.5Gd0.5VO4晶体生长和基本特性 总被引:5,自引:0,他引:5
Nd^3 :Y0.5Gd0.5VO4晶体作为一种新的激光材料,可以用中频感应加热提拉法生长。X射线粉末衍射分析表明它的结构与Nd^3 :YVO4晶体结构相同,它的晶格常数介于YVO4和NdVO4晶格常数之间。用ICP光谱法测定晶体中Nd^3 含量为0.8at%,分凝系数为0.8,与Nd^3 :GdVO4晶体中Nd^3 的分凝系数0.78相当;用称重法测定其密度为5.00g/cm^3;用稳态纵向热流法测出其室温热导率为12.5W/mK。实验表明Nd^3 :Y0.5Gd0.5VO4晶体有希望作为高功率ID泵浦激光晶体材料。 相似文献
3.
4.
YOSHIHARU KARIYA TADATOMO SUGA 《Fatigue & Fracture of Engineering Materials & Structures》2007,30(5):413-419
This paper details the deformation mechanism and low‐cycle fatigue life of eutectic solder alloys at high temperature (around 0.8Tm). Grain boundary sliding generally nucleates a wedge‐type cavity that reduces the low‐cycle fatigue life of metals. In this study, grain boundary sliding has promoted intergranular failure contributing to the reduction in fatigue life of Sn–Ag–Cu alloy. However, grain boundary sliding has exerted no deleterious effects on fatigue resistance of eutectic Pb–Sn and Bi–Sn alloys. The phase boundary sliding with very fine microstructure induces exceptional ductility in these alloys leading to superior low‐cycle fatigue endurance for theses eutectic Pb–Sn and Bi–Sn alloys. 相似文献
5.
K0.9Li0.1(Ta0.5Nb0.5)O3晶体压电应变系数的测量 总被引:4,自引:2,他引:2
用准静态d_(33)测量仪和干涉法相结合。测量了K_(0.9)Li_(0.1)(Ta_(0.5)Nb_(0.5)Nb_(0.5))O_3晶体的压电应变系数。结果为:d_(33)=86.0,d_(33)=一29.5,d_(15)=112.9×10 ̄(-12)C/N. 相似文献
6.
研究了非晶Sm5Fe74.3Nb1.5Si11.7B4.5C2.5Cu0.5合金经400℃,保温10min预退火后的晶化动力学。结果表明;该合金的晶化相为α-Fe固溶体和Sm2Fe17Cx金属间化合物,两相的晶化表观激活能分别为557KJ/mol和514KJ/mol,当晶化体积分数为60%时,α-Fe相的晶化激活能达极大值;Sm2Fe17Cx相晶化激活能则随其晶化体积分数的增加而逐渐减小。 相似文献
7.
Chaosuan Kanchanomai Yukio Miyashita Yoshiharu Mutoh 《Journal of Electronic Materials》2002,31(5):456-465
Low-cycle fatigue (LCF) tests on as-cast Sn-3.5Ag, Sn-3Ag-0.5Cu, Sn-3Ag-0.5Cu-1Bi, and Sn-3Ag-0.5Cu-3Bi solders was carried
out using a noncontact strain-controlled system at 20°C with a constant frequency of 0.1 Hz. The addition of Cu does not significantly
affect the fatigue life of eutectic Sn-Ag solder. However, the fatigue life was significantly reduced with the addition of
Bi. The LCF behavior of all solders followed the Coffin-Manson relationship. The fatigue life of the present solders is dominated
by the fracture ductility and can be described by the ductility-modified Coffin-Manson’s relationship. Steps at the boundaries
of dendrite phases were the initiation sites for microcracks for Sn-3.5Ag, Sn-3Ag-0.5Cu, and Sn-3Ag-0.5Cu-1Bi solders, while
for Sn-3Ag-0.5Cu-3Bi solder, cracks initiated along both the dendrite boundaries and subgrain boundaries in the dendrite phases.
The linking of these cracks and the propagation of cracks inside the specimen occurred both transgranularly through eutectic
phases and intergranularly along dendrite boundaries or subgrain boundaries. 相似文献
8.
N. Guskos V. Lyvkodimos C. A. Londos A. Kondos S. M. Paraskevas A. Koufoudakis C. Mitros H. Gamari-Seale D. Niarchos I. Kruk 《Journal of Superconductivity》1992,5(5):457-461
EPR, XRD, and magnetic studies are presented for Pr0.5Re0.5Ba2Cu3O7– compounds (Re= La, Nd, Sm, Eu, Gd, Dy, Ho, Y, Er, Tm, Yb, and Lu) in the orthorhombic and tetragonal (large oxygen deficiency) phase. For the samples with Re=Dy, Ho, Y, Er, Tm, Yb, and Lu in the orthorhombic phase, the transition to the superconducting state has been observed in the temperatures rangeT
c
between 18 and 40 K. For the samples with Nd and Yb in the tetragonal phase, EPR spectra coming from trivalent rare earth ions have been recorded. In the nonoxygenated sample Pr0.5La0.5Ba2Cu3O7–
the EPR spectrum arising from the non-Kramers trivalent praseodymium ion has been observed. A broad EPR line appearing in all our samples was attributed to superexchange interaction between copper ions over oxygen (O
2
–
) bridges. Interestingly, for the Pr0.5Re0.5Ba0.5Cu3O7– (Re = Er and Lu) compounds in the tetragonal phase at liquid-nitrogen temperature, a nonresonant microwave absorption in low magnetic fields has been detected. 相似文献
9.
A series of Ce2-xPrxFe16.5Co0.5 alloys were preparedby arc melting under purified argon atmosphere. The structure and magnetic entropy changes in Ce2-xPrxFe16.5Co0.5 alloys were investigated by means of X-ray diffraction pattern and MPMS XL-7 magnetometer. The experimental results show that the crystal structure of Ce2-xPrxFe16.5Co0.5 alloys keeps in TH2Zn17-type rhombohedral, and the Curie temperature of Ce2-xPrxFe16.5Co0.5 alloys can be shifted to room temperature around by a composition adjustment. The magnetic entropy changes (-ΔSM) in Ce2-xPrxFe16.5Co0.5 alloys are relatively large, and a platform of magnetic entropy changes appearsnear the temperature TC. Ce2-xPrxFe16.5Co0.5 alloys are the potential working media for magnetic refrigeration with their stable chemical properties and especially low price. 相似文献
10.
采用高温固相法成功制备了不同Na+掺杂浓度的Li1-xNaxNi1/3Co1/3Mn1/3O2锂离子电池正极材料,探究了Na元素掺杂对层状氧化物正极材料结构以及电化学性能的影响。通过X射线粉末衍射仪和扫描电子显微镜表征了材料的结构和形貌,结果表明,当x≤0.3时,样品不会出现其它杂相;当x>0.3时,样品中会出现NaNi1/3Co1/3Mn1/3O2的杂相。同时随着掺杂浓度的增加,样品的阳离子混排度逐渐增加。电化学性能结果表明,少量Na+的掺入可以提高LiNi1/3Co1/3Mn1/3O2在0.2C,0.5C下的放电比容量并增强其循环稳定性,但会损坏材料的倍率性能。 相似文献